PMID- 28746997 OWN - NLM STAT- MEDLINE DCOM- 20171011 LR - 20181202 IS - 1879-1298 (Electronic) IS - 0045-6535 (Linking) VI - 185 DP - 2017 Oct TI - Removal of bisphenol A by electrochemical carbon-nanotube filter: Influential factors and degradation pathway. PG - 879-887 LID - S0045-6535(17)31134-7 [pii] LID - 10.1016/j.chemosphere.2017.07.082 [doi] AB - Bisphenol A is a chemical with hazardous health effects that is largely used in the manufacture of extensively used products including adhesives, plastics, powder paints, thermal paper and paper coatings, and epoxy resin, and is reported to exist in nature in an accumulative manner. In this study, both pristine and boron-doped multiwalled carbon nanotubes (MWNTs) were employed as filtration and electrochemical filtration materials, resulting in a significant removal of bisphenol A with identical performance for both MWNTs types. It was shown that the presence of salt is not critical for the greatest contaminant removal efficiency, likely due to the vital role of other electroactive species (e.g. reactive oxygen species). Near complete removal of 1 mg L(-1) bisphenol A at 2 and 3 V of applied DC potentials was achieved, indicating that the electrochemical filtration process is voltage dependent at both 2 and 3 V. Increasing the residence time by 7.4 fold (from 2.0 to 14.9 s) resulted in a significant removal of bisphenol A and its toxic byproducts, up to 424 min of electrochemical filtration time at 3 V of applied potential. Based on these results, electrochemical filtration using MWNTs is considered a promising technology for the removal of the accumulative bisphenol A and the reduction of its hazardous effects in waters. CI - Copyright (c) 2017. Published by Elsevier Ltd. FAU - Bakr, Ahmed Refaat AU - Bakr AR AD - Department of Building, Civil and Environmental Engineering, Concordia University, Montreal, Quebec, H3G 1M8, Canada. FAU - Rahaman, Md Saifur AU - Rahaman MS AD - Department of Building, Civil and Environmental Engineering, Concordia University, Montreal, Quebec, H3G 1M8, Canada. Electronic address: saifur.rahaman@concordia.ca. LA - eng PT - Journal Article DEP - 20170717 PL - England TA - Chemosphere JT - Chemosphere JID - 0320657 RN - 0 (Benzhydryl Compounds) RN - 0 (Nanotubes, Carbon) RN - 0 (Phenols) RN - 0 (Water Pollutants, Chemical) RN - MLT3645I99 (bisphenol A) RN - N9E3X5056Q (Boron) SB - IM MH - Benzhydryl Compounds/analysis/*chemistry MH - Boron MH - Filtration/*methods MH - Nanotubes, Carbon/*chemistry MH - Phenols/analysis/*chemistry MH - Water Pollutants, Chemical/analysis/*chemistry MH - Water Purification/*methods OTO - NOTNLM OT - Bisphenol A OT - Doping OT - Electrochemical filtration OT - Multiwalled carbon nanotubes OT - Oxidation EDAT- 2017/07/28 06:00 MHDA- 2017/10/12 06:00 CRDT- 2017/07/28 06:00 PHST- 2017/02/26 00:00 [received] PHST- 2017/07/14 00:00 [revised] PHST- 2017/07/15 00:00 [accepted] PHST- 2017/07/28 06:00 [pubmed] PHST- 2017/10/12 06:00 [medline] PHST- 2017/07/28 06:00 [entrez] AID - S0045-6535(17)31134-7 [pii] AID - 10.1016/j.chemosphere.2017.07.082 [doi] PST - ppublish SO - Chemosphere. 2017 Oct;185:879-887. doi: 10.1016/j.chemosphere.2017.07.082. Epub 2017 Jul 17.