PMID- 28759851
OWN - NLM
STAT- MEDLINE
DCOM- 20180813
LR  - 20180813
IS  - 1873-3557 (Electronic)
IS  - 1386-1425 (Linking)
VI  - 188
DP  - 2018 Jan 5
TI  - Relationship of carbohydrates and lignin molecular structure spectral profiles to 
      nutrient profile in newly developed oats cultivars and barley grain.
PG  - 495-506
LID - S1386-1425(17)30590-5 [pii]
LID - 10.1016/j.saa.2017.07.042 [doi]
AB  - The objectives of this study were to quantify the chemical profile and the 
      magnitude of differences in the oat and barley grain varieties developed by Crop 
      Development Centre (CDC) in terms of Cornell Net Carbohydrate Protein System 
      (CNCPS) carbohydrate sub-fractions: CA4 (sugars), CB1 (starch), CB2 (soluble 
      fibre), CB3 (available neutral detergent fibre - NDF), and CC (unavailable 
      carbohydrate); to estimate the energy values; to detect the lignin and 
      carbohydrate (CHO) molecular structure profiles in CDC Nasser and CDC Seabiscuit 
      oat and CDC Meredith barley grains by using Fourier transform infrared attenuated 
      total reflectance (FTIR-ATR); to develop a model to predict nutrient supply based 
      on CHO molecular profile. Results showed that NDF, ADF and CHO were greater 
      (P<0.05) in oat than in barley. The starch content was greater (P<0.05) in barley 
      than in oat. The CDC Meredith showed greater total rumen degradable carbohydrate 
      (RDC), intestinal digestible fraction carbohydrate (FC) and lower total rumen 
      undegradable carbohydrate (RUC). However, the estimated milk production did not 
      differ for CDC Nasser oat and CDC Meredith barley. Lignin peak area and peak 
      height did not differ (P>0.05) for oat and barley grains as well as 
      non-structural CHO. However, cellulosic compounds peak area and height were 
      greater (P<0.05) in oat than barley grains. Multiple regressions were determined 
      to predict nutrient supply by using lignin and CHO molecular profiles. It was 
      concluded that although there were some differences between oat and barley 
      grains, CDC Nasser and CDC Meredith presented similarities related to chemical 
      and molecular profiles, indicating that CDC Meredith barley could be replaced for 
      CDC Nasser as ruminant feed. The FTIR was able to identify functional groups 
      related to CHO molecular spectral in oat and barley grains and FTIR-ATR results 
      could be used to predict nutrient supply in ruminant livestock systems.
CI  - Copyright (c) 2017. Published by Elsevier B.V.
FAU - Prates, Luciana Louzada
AU  - Prates LL
AD  - College of Agriculture and Bioresources, Department of Animal and Poultry 
      Science, University of Saskatchewan, 51 Campus Drive, Saskatoon, SK S7N 5A8, 
      Canada. Electronic address: peqiang.yu@usask.ca.
FAU - Refat, Basim
AU  - Refat B
AD  - College of Agriculture and Bioresources, Department of Animal and Poultry 
      Science, University of Saskatchewan, 51 Campus Drive, Saskatoon, SK S7N 5A8, 
      Canada.
FAU - Lei, Yaogeng
AU  - Lei Y
AD  - College of Agriculture and Bioresources, Department of Animal and Poultry 
      Science, University of Saskatchewan, 51 Campus Drive, Saskatoon, SK S7N 5A8, 
      Canada.
FAU - Louzada-Prates, Mariana
AU  - Louzada-Prates M
AD  - Department of Nutrition, Universidade Federal de Vicosa, Campus Universitario, 
      Vicosa, MG 365700-000, Brazil.
FAU - Yu, Peiqiang
AU  - Yu P
AD  - College of Agriculture and Bioresources, Department of Animal and Poultry 
      Science, University of Saskatchewan, 51 Campus Drive, Saskatoon, SK S7N 5A8, 
      Canada.
LA  - eng
PT  - Journal Article
DEP - 20170724
PL  - England
TA  - Spectrochim Acta A Mol Biomol Spectrosc
JT  - Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy
JID - 9602533
RN  - 0 (Carbohydrates)
RN  - 9005-53-2 (Lignin)
SB  - IM
MH  - Avena/*chemistry
MH  - Carbohydrates/*chemistry
MH  - Edible Grain/*chemistry
MH  - Hordeum/*chemistry
MH  - Lignin/*chemistry
MH  - Multivariate Analysis
OTO - NOTNLM
OT  - CNCPS
OT  - Digestibility
OT  - Fourier-transform infrared spectroscopy
OT  - Molecular chemistry
EDAT- 2017/08/02 06:00
MHDA- 2018/08/14 06:00
CRDT- 2017/08/01 06:00
PHST- 2016/10/14 00:00 [received]
PHST- 2017/07/18 00:00 [revised]
PHST- 2017/07/20 00:00 [accepted]
PHST- 2017/08/02 06:00 [pubmed]
PHST- 2018/08/14 06:00 [medline]
PHST- 2017/08/01 06:00 [entrez]
AID - S1386-1425(17)30590-5 [pii]
AID - 10.1016/j.saa.2017.07.042 [doi]
PST - ppublish
SO  - Spectrochim Acta A Mol Biomol Spectrosc. 2018 Jan 5;188:495-506. doi: 
      10.1016/j.saa.2017.07.042. Epub 2017 Jul 24.