PMID- 28772734 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20200930 IS - 1996-1944 (Print) IS - 1996-1944 (Electronic) IS - 1996-1944 (Linking) VI - 10 IP - 4 DP - 2017 Mar 31 TI - One-Pot Route towards Active TiO(2) Doped Hierarchically Porous Cellulose: Highly Efficient Photocatalysts for Methylene Blue Degradation. LID - 10.3390/ma10040373 [doi] LID - 373 AB - In this study, novel photocatalyst monolith materials were successfully fabricated by a non-solvent induced phase separation (NIPS) technique. By adding a certain amount of ethyl acetate (as non-solvent) into a cellulose/LiCl/N,N-dimethylacetamide (DMAc) solution, and successively adding titanium dioxide (TiO(2)) nanoparticles (NPs), cellulose/TiO(2) composite monoliths with hierarchically porous structures were easily formed. The obtained composite monoliths possessed mesopores, and two kinds of macropores. Scanning Electron Microscope (SEM), Energy Dispersive Spectroscopy (EDS), Fourier Transform Infrared Spectroscopy (FT-IR), X-ray Diffraction (XRD), Brunauer-Emmett-Teller (BET), and Ultraviolet-visible Spectroscopy (UV-Vis) measurements were adopted to characterize the cellulose/TiO(2) composite monolith. The cellulose/TiO(2) composite monoliths showed high efficiency of photocatalytic activity in the decomposition of methylene blue dye, which was decomposed up to 99% within 60 min under UV light. Moreover, the composite monoliths could retain 90% of the photodegradation efficiency after 10 cycles. The novel NIPS technique has great potential for fabricating recyclable photocatalysts with highly efficiency. FAU - Sun, Xiaoxia AU - Sun X AD - College of Textiles, Donghua University, Shanghai 201620, China. xxsun@dhu.edu.cn. AD - Key Laboratory of Textile Science & Technology of Eco-Textile, Ministry of Education, Donghua University, Shanghai 201620, China. xxsun@dhu.edu.cn. AD - Key Laboratory of Textile Science & Technology, Ministry of Education, Donghua University, Shanghai 201620, China. xxsun@dhu.edu.cn. FAU - Wang, Kunpeng AU - Wang K AD - College of Textiles, Donghua University, Shanghai 201620, China. wang.k.peng@foxmail.com. FAU - Shu, Yu AU - Shu Y AD - Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Osaka 565-0871, Japan. y_shu@chem.eng.osaka-u.ac.jp. FAU - Zou, Fangdong AU - Zou F AD - College of Textiles, Donghua University, Shanghai 201620, China. gool228@163.com. FAU - Zhang, Boxing AU - Zhang B AD - South China Advanced Institute for Soft Matter Science and Technology, South China University of Technology, Guangzhou 510641, China. bxzhang@scut.edu.cn. FAU - Sun, Guangwu AU - Sun G AD - School of Fashion Technology, Shanghai University of Engineering Science, Shanghai 201620, China. sunguangwu77@163.com. FAU - Uyama, Hiroshi AU - Uyama H AD - Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Osaka 565-0871, Japan. uyama@chem.eng.osaka-u.ac.jp. FAU - Wang, Xinhou AU - Wang X AD - College of Textiles, Donghua University, Shanghai 201620, China. xhwang@dhu.edu.cn. AD - Key Laboratory of Textile Science & Technology of Eco-Textile, Ministry of Education, Donghua University, Shanghai 201620, China. xhwang@dhu.edu.cn. LA - eng PT - Journal Article DEP - 20170331 PL - Switzerland TA - Materials (Basel) JT - Materials (Basel, Switzerland) JID - 101555929 PMC - PMC5506969 OTO - NOTNLM OT - TiO2 OT - cellulose OT - monolith OT - non-solvent induced phase separation OT - photocatalyst COIS- The authors declare no conflict of interest. The founding sponsors had no role in the design of the study; in the collection, analyses, or interpretation of data; in the writing of the manuscript, and in the decision to publish the results. EDAT- 2017/08/05 06:00 MHDA- 2017/08/05 06:01 PMCR- 2017/03/31 CRDT- 2017/08/05 06:00 PHST- 2017/02/19 00:00 [received] PHST- 2017/03/25 00:00 [revised] PHST- 2017/03/28 00:00 [accepted] PHST- 2017/08/05 06:00 [entrez] PHST- 2017/08/05 06:00 [pubmed] PHST- 2017/08/05 06:01 [medline] PHST- 2017/03/31 00:00 [pmc-release] AID - ma10040373 [pii] AID - materials-10-00373 [pii] AID - 10.3390/ma10040373 [doi] PST - epublish SO - Materials (Basel). 2017 Mar 31;10(4):373. doi: 10.3390/ma10040373.