PMID- 28773169 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20201001 IS - 1996-1944 (Print) IS - 1996-1944 (Electronic) IS - 1996-1944 (Linking) VI - 10 IP - 7 DP - 2017 Jul 16 TI - Preparation and Properties of a Novel Microcrystalline Cellulose-Filled Composites Based on Polyamide 6/High-Density Polyethylene. LID - 10.3390/ma10070808 [doi] LID - 808 AB - In the present study, lithium chloride (LiCl) was utilized as a modifier to reduce the melting point of polyamide 6 (PA6), and then 15 wt % microcrystalline cellulose (MCC) was compounded with low melting point PA6/high-density polyethylene (HDPE) by hot pressing. Crystallization analysis revealed that as little as 3 wt % LiCl transformed the crystallographic forms of PA6 from semi-crystalline to an amorphous state (melting point: 220 degrees C to none), which sharply reduced the processing temperature of the composites. LiCl improved the mechanical properties of the composites, as evidenced by the fact that the impact strength of the composites was increased by 90%. HDPE increased the impact strength of PA6/MCC composites. In addition, morphological analysis revealed that incorporation of LiCl and maleic anhydride grafted high-density polyethylene (MAPE) improved the interfacial adhesion. LiCl increased the glass transition temperature of the composites (the maximum is 72.6 degrees C). FAU - Xu, Shihua AU - Xu S AD - Key Laboratory of Bio-based Material Science and Technology (Ministry of Education), Northeast Forestry University, Harbin 150040, China. xush@nefu.edu.cn. FAU - Yi, Shunmin AU - Yi S AD - Key Laboratory of Bio-based Material Science and Technology (Ministry of Education), Northeast Forestry University, Harbin 150040, China. binshanmu@nefu.edu.cn. FAU - He, Jun AU - He J AD - Nanjing Xuhua Sundi New Building Materials Co., Ltd., Nanjing 211224, China. xush@nefu.edu.cn. FAU - Wang, Haigang AU - Wang H AD - Key Laboratory of Bio-based Material Science and Technology (Ministry of Education), Northeast Forestry University, Harbin 150040, China. hgwang@nefu.edu.cn. FAU - Fang, Yiqun AU - Fang Y AD - Key Laboratory of Bio-based Material Science and Technology (Ministry of Education), Northeast Forestry University, Harbin 150040, China. yqfang@nefu.edu.cn. FAU - Wang, Qingwen AU - Wang Q AD - Key Laboratory of Bio-based Material Science and Technology (Ministry of Education), Northeast Forestry University, Harbin 150040, China. qwwang@scau.edu.cn. AD - College of Materials and Energy, South China Agricultural University, Guangzhou 510642, China. qwwang@scau.edu.cn. LA - eng PT - Journal Article DEP - 20170716 PL - Switzerland TA - Materials (Basel) JT - Materials (Basel, Switzerland) JID - 101555929 PMC - PMC5551851 OTO - NOTNLM OT - lithium chloride OT - melting point OT - microcrystalline cellulose OT - polyamide 6/high-density polyethylene COIS- The authors declare no conflict of interest. EDAT- 2017/08/05 06:00 MHDA- 2017/08/05 06:01 PMCR- 2017/07/16 CRDT- 2017/08/05 06:00 PHST- 2017/05/13 00:00 [received] PHST- 2017/07/02 00:00 [revised] PHST- 2017/07/10 00:00 [accepted] PHST- 2017/08/05 06:00 [entrez] PHST- 2017/08/05 06:00 [pubmed] PHST- 2017/08/05 06:01 [medline] PHST- 2017/07/16 00:00 [pmc-release] AID - ma10070808 [pii] AID - materials-10-00808 [pii] AID - 10.3390/ma10070808 [doi] PST - epublish SO - Materials (Basel). 2017 Jul 16;10(7):808. doi: 10.3390/ma10070808.