PMID- 28773297 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20230412 IS - 1996-1944 (Print) IS - 1996-1944 (Electronic) IS - 1996-1944 (Linking) VI - 9 IP - 3 DP - 2016 Mar 5 TI - Integrated Effects of Two Additives on the Enhanced Performance of PTB7:PC(71)BM Polymer Solar Cells. LID - 10.3390/ma9030171 [doi] LID - 171 AB - Organic photovoltaics (OPVs) are fabricated with blended active layers of poly [[4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b']dithiophene-2,6-diyl][3-fluoro-2-[(2-ethylhexyl)carbonyl] thieno[3,4-b]thiophenediyl]]: [6,6]-phenylC71-butyric acid methyl ester (PTB7:PC(71)BM). The active layers are prepared in chlorobenzene (CB) added different additives of 1, 8-Diiodooctane (DIO) and polystyrene (PS) with different concentrations by spin coating. A small addition, 0.5%-5% by weight relative to the BHJ components, of inert high molecular weight PS is used to increase the solution viscosity and film thickness without sacrificing desirable phase separation and structural order. The effects of the PS are studied with respect of photovoltaic parameters such as fill factor, short circuit current density, and power conversion efficiency. Together with DIO, the device with 3.0 v% DIO and 1 wt % PS shows a high power conversion efficiency (PCE) of 8.92% along with an open-circuit voltage (V(oc)) of 0.76 V, a short-circuit current (J(sc)) of 16.37 mA/cm(2), and a fill factor (FF) of 71.68%. The absorption and surface morphology of the active layers are investigated by UV-visible spectroscopy, atomic force microscopy (AFM) respectively. The positive effect of DIO and PS additives on the performance of the OPVs is attributed to the increased absorption and the charge carrier transport and collection. FAU - Wang, Lin AU - Wang L AD - Key Laboratory of Luminescence and Optical Information, Beijing Jiaotong University, Ministry of Education, Beijing 100044, China. 13121569@bjtu.edu.cn. AD - Institute of Optoelectronic Technology, Beijing Jiaotong University, Beijing 100044, China. 13121569@bjtu.edu.cn. FAU - Zhao, Suling AU - Zhao S AD - Key Laboratory of Luminescence and Optical Information, Beijing Jiaotong University, Ministry of Education, Beijing 100044, China. slzhao@bjtu.edu.cn. AD - Institute of Optoelectronic Technology, Beijing Jiaotong University, Beijing 100044, China. slzhao@bjtu.edu.cn. FAU - Xu, Zheng AU - Xu Z AD - Key Laboratory of Luminescence and Optical Information, Beijing Jiaotong University, Ministry of Education, Beijing 100044, China. zhengxu@bjtu.edu.cn. AD - Institute of Optoelectronic Technology, Beijing Jiaotong University, Beijing 100044, China. zhengxu@bjtu.edu.cn. FAU - Zhao, Jiao AU - Zhao J AD - Key Laboratory of Luminescence and Optical Information, Beijing Jiaotong University, Ministry of Education, Beijing 100044, China. 14118436@bjtu.edu.cn. AD - Institute of Optoelectronic Technology, Beijing Jiaotong University, Beijing 100044, China. 14118436@bjtu.edu.cn. FAU - Huang, Di AU - Huang D AD - Key Laboratory of Luminescence and Optical Information, Beijing Jiaotong University, Ministry of Education, Beijing 100044, China. 2008-hd@163.com. AD - Institute of Optoelectronic Technology, Beijing Jiaotong University, Beijing 100044, China. 2008-hd@163.com. FAU - Zhao, Ling AU - Zhao L AD - Key Laboratory of Luminescence and Optical Information, Beijing Jiaotong University, Ministry of Education, Beijing 100044, China. 13118413@bjtu.edu.cn. AD - Institute of Optoelectronic Technology, Beijing Jiaotong University, Beijing 100044, China. 13118413@bjtu.edu.cn. LA - eng PT - Journal Article DEP - 20160305 PL - Switzerland TA - Materials (Basel) JT - Materials (Basel, Switzerland) JID - 101555929 PMC - PMC5456692 OTO - NOTNLM OT - absorption OT - hole mobility OT - mixed additives OT - organic solar cells COIS- The authors declare no conflict of interest. EDAT- 2016/03/05 00:00 MHDA- 2016/03/05 00:01 PMCR- 2016/03/05 CRDT- 2017/08/05 06:00 PHST- 2016/01/19 00:00 [received] PHST- 2016/02/20 00:00 [revised] PHST- 2016/02/24 00:00 [accepted] PHST- 2017/08/05 06:00 [entrez] PHST- 2016/03/05 00:00 [pubmed] PHST- 2016/03/05 00:01 [medline] PHST- 2016/03/05 00:00 [pmc-release] AID - ma9030171 [pii] AID - materials-09-00171 [pii] AID - 10.3390/ma9030171 [doi] PST - epublish SO - Materials (Basel). 2016 Mar 5;9(3):171. doi: 10.3390/ma9030171.