PMID- 28793555 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20201001 IS - 1996-1944 (Print) IS - 1996-1944 (Electronic) IS - 1996-1944 (Linking) VI - 8 IP - 9 DP - 2015 Sep 14 TI - The Photoluminescent Properties of New Cationic Iridium(III) Complexes Using Different Anions and Their Applications in White Light-Emitting Diodes. PG - 6105-6116 LID - 10.3390/ma8095296 [doi] AB - Three cationic iridium(III) complexes [Ir(ppy)(2)(phen)][PF(6)] (C1), [Ir(ppy)(2)(phen)](2)SiF(6) (C2) and [Ir(ppy)(2)(phen)](2)TiF(6) (C3) (ppy: 2-phenylpyridine, phen: 1, 10-phenanthroline) using different anions were synthesized and characterized by (1)H Nuclear magnetic resonance ((1)HNMR), mass spectra (MS), Fourier transform infrared (FTIR) spectra and element analysis (EA). After the ultraviolet visible (UV-vis) absorption spectra, photoluminescent (PL) properties and thermal properties of the complexes were investigated, complex C1 and C3 with good optical properties and high thermal stability were used in white light-emitting diodes (WLEDs) as luminescence conversion materials by incorporation with 460 nm-emitting blue GaN chips. The integrative performances of the WLEDs fabricated with complex C1 and C3 are better than those fabricated with the widely used yellow phosphor Y(3)Al(5)O(12):Ce(3+) (YAG). The color rendering indexes of the WLEDs with C1 and C3 are 82.0 and 82.6, the color temperatures of them are 5912 K and 3717 K, and the maximum power efficiencies of them are 10.61 Lm.W(-1) and 11.41 Lm.W(-1), respectively. FAU - Yang, Hui AU - Yang H AD - Key Laboratory of Comprehensive Utilization of Mineral Resources in Ethnic Regions, Joint Research Centre for International Cross-border Ethnic Regions Biomass Clean Utilization in Yunnan, School of Chemistry & Environment, Yunnan Minzu University, Kunming 650500, China. yanghui0304@foxmail.com. FAU - Meng, Guoyun AU - Meng G AD - Key Laboratory of Comprehensive Utilization of Mineral Resources in Ethnic Regions, Joint Research Centre for International Cross-border Ethnic Regions Biomass Clean Utilization in Yunnan, School of Chemistry & Environment, Yunnan Minzu University, Kunming 650500, China. mengguoyun@sina.com. FAU - Zhou, Yayun AU - Zhou Y AD - Key Laboratory of Comprehensive Utilization of Mineral Resources in Ethnic Regions, Joint Research Centre for International Cross-border Ethnic Regions Biomass Clean Utilization in Yunnan, School of Chemistry & Environment, Yunnan Minzu University, Kunming 650500, China. zhou-yayun@foxmail.com. FAU - Tang, Huaijun AU - Tang H AD - Key Laboratory of Comprehensive Utilization of Mineral Resources in Ethnic Regions, Joint Research Centre for International Cross-border Ethnic Regions Biomass Clean Utilization in Yunnan, School of Chemistry & Environment, Yunnan Minzu University, Kunming 650500, China. tanghuaijun@sohu.com. FAU - Zhao, Jishou AU - Zhao J AD - Key Laboratory of Comprehensive Utilization of Mineral Resources in Ethnic Regions, Joint Research Centre for International Cross-border Ethnic Regions Biomass Clean Utilization in Yunnan, School of Chemistry & Environment, Yunnan Minzu University, Kunming 650500, China. zhaojishou@163.com. FAU - Wang, Zhengliang AU - Wang Z AD - Key Laboratory of Comprehensive Utilization of Mineral Resources in Ethnic Regions, Joint Research Centre for International Cross-border Ethnic Regions Biomass Clean Utilization in Yunnan, School of Chemistry & Environment, Yunnan Minzu University, Kunming 650500, China. wzhl629@163.com. LA - eng PT - Journal Article DEP - 20150914 PL - Switzerland TA - Materials (Basel) JT - Materials (Basel, Switzerland) JID - 101555929 PMC - PMC5512903 OTO - NOTNLM OT - blue GaN chip OT - cationic iridium(III) complex OT - photoluminescence OT - white light-emitting diode COIS- The authors declare no conflict of interest. EDAT- 2015/09/14 00:00 MHDA- 2015/09/14 00:01 PMCR- 2015/09/14 CRDT- 2017/08/11 06:00 PHST- 2015/07/19 00:00 [received] PHST- 2015/08/29 00:00 [revised] PHST- 2015/09/06 00:00 [accepted] PHST- 2017/08/11 06:00 [entrez] PHST- 2015/09/14 00:00 [pubmed] PHST- 2015/09/14 00:01 [medline] PHST- 2015/09/14 00:00 [pmc-release] AID - ma8095296 [pii] AID - materials-08-05296 [pii] AID - 10.3390/ma8095296 [doi] PST - epublish SO - Materials (Basel). 2015 Sep 14;8(9):6105-6116. doi: 10.3390/ma8095296.