PMID- 28802526
OWN - NLM
STAT- MEDLINE
DCOM- 20171012
LR  - 20181202
IS  - 1873-3778 (Electronic)
IS  - 0021-9673 (Linking)
VI  - 1515
DP  - 2017 Sep 15
TI  - Sodium hyaluronate-functionalized urea-formaldehyde monolithic column for 
      hydrophilic in-tube solid-phase microextraction of melamine.
PG  - 54-61
LID - S0021-9673(17)31145-7 [pii]
LID - 10.1016/j.chroma.2017.08.005 [doi]
AB  - A novel sodium hyaluronate-functionalized urea-formaldehyde (UF) monolithic 
      column has been developed by in-situ polycondensation of urea, formaldehyde and 
      sodium hyaluronate (HA). HA plays both the roles of crosslinking and hydrophilic 
      functionalization. The preparation factors including different molecular weights 
      of HA and different amounts of HA were optimized, and then a uniform monolith 
      with satisfactory permeability and hydrophilic binding capacity was obtained. Due 
      to the excellent hydrophilicity of HA, HA-functionalized UF monolith showed 
      higher hydrophilic extraction efficiency than UF monolith, and was applied for 
      hydrophilic in-tube solid-phase microextraction (SPME) of melamine (MEL). Several 
      factors for hydrophilic in-tube SPME, such as ACN percentage in the sampling 
      solution, salt concentration and pH value of the sampling solution, elution 
      volume, sampling and elution flow rate, were investigated with respect to the 
      extraction efficiency of MEL. Under the optimized SPME conditions, the limit of 
      detection (LOD) of MEL was found to be 0.2ng/mL in the milk formula samples, the 
      recoveries of MEL spiked in milk formula samples ranged from 87.3% to 96.7% with 
      relative standard deviations (RSDs) less than 5.1%. Owing to the excellent 
      hydrophilic extraction ability, the novel HA-functionalized UF monolith could 
      provide a promising tool for the sensitive analysis of polar analytes in 
      complicated samples.
CI  - Copyright (c) 2017 Elsevier B.V. All rights reserved.
FAU - Wang, Jiabin
AU  - Wang J
AD  - Institute of Biomedical and Pharmaceutical Technology, Fuzhou University, Fuzhou, 
      350002, China. Electronic address: jbwang@fzu.edu.cn.
FAU - Jiang, Nan
AU  - Jiang N
AD  - Institute of Biomedical and Pharmaceutical Technology, Fuzhou University, Fuzhou, 
      350002, China.
FAU - Cai, Zhengmiao
AU  - Cai Z
AD  - Institute of Food Safety and Environment Monitoring, Fuzhou University, Fuzhou, 
      350108, China.
FAU - Li, Wenbang
AU  - Li W
AD  - Institute of Biomedical and Pharmaceutical Technology, Fuzhou University, Fuzhou, 
      350002, China.
FAU - Li, Jianhua
AU  - Li J
AD  - Institute of Biomedical and Pharmaceutical Technology, Fuzhou University, Fuzhou, 
      350002, China.
FAU - Lin, Xucong
AU  - Lin X
AD  - Institute of Food Safety and Environment Monitoring, Fuzhou University, Fuzhou, 
      350108, China.
FAU - Xie, Zenghong
AU  - Xie Z
AD  - Institute of Food Safety and Environment Monitoring, Fuzhou University, Fuzhou, 
      350108, China.
FAU - You, Lijun
AU  - You L
AD  - Institute of Biomedical and Pharmaceutical Technology, Fuzhou University, Fuzhou, 
      350002, China.
FAU - Zhang, Qiqing
AU  - Zhang Q
AD  - Institute of Biomedical and Pharmaceutical Technology, Fuzhou University, Fuzhou, 
      350002, China; Key Laboratory of Biomedical Material of Tianjin, Institute of 
      Biomedical Engineering, Chinese Academy of Medical Science & Peking Union Medical 
      College, Tianjin, 300192, China. Electronic address: zhangqiq@126.com.
LA  - eng
PT  - Journal Article
DEP - 20170803
PL  - Netherlands
TA  - J Chromatogr A
JT  - Journal of chromatography. A
JID - 9318488
RN  - 0 (Triazines)
RN  - 1HG84L3525 (Formaldehyde)
RN  - 8W8T17847W (Urea)
RN  - 9004-61-9 (Hyaluronic Acid)
RN  - 9NEZ333N27 (Sodium)
RN  - N3GP2YSD88 (melamine)
SB  - IM
MH  - Formaldehyde/*chemistry
MH  - Hyaluronic Acid/*chemistry
MH  - Hydrophobic and Hydrophilic Interactions
MH  - Limit of Detection
MH  - Sodium/chemistry
MH  - Solid Phase Microextraction/*instrumentation/*methods
MH  - Triazines/analysis/*isolation & purification
MH  - Urea/*chemistry
OTO - NOTNLM
OT  - Hydrophilic interaction
OT  - In-tube solid-phase microextraction
OT  - Melamine
OT  - Sodium hyaluronate
OT  - Urea-formaldehyde monolithic column
EDAT- 2017/08/15 06:00
MHDA- 2017/10/13 06:00
CRDT- 2017/08/14 06:00
PHST- 2017/06/13 00:00 [received]
PHST- 2017/07/31 00:00 [revised]
PHST- 2017/08/01 00:00 [accepted]
PHST- 2017/08/15 06:00 [pubmed]
PHST- 2017/10/13 06:00 [medline]
PHST- 2017/08/14 06:00 [entrez]
AID - S0021-9673(17)31145-7 [pii]
AID - 10.1016/j.chroma.2017.08.005 [doi]
PST - ppublish
SO  - J Chromatogr A. 2017 Sep 15;1515:54-61. doi: 10.1016/j.chroma.2017.08.005. Epub 
      2017 Aug 3.