PMID- 28818653 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20180606 LR - 20180606 IS - 1095-7103 (Electronic) IS - 0021-9797 (Linking) VI - 508 DP - 2017 Dec 15 TI - Robust and thermal-healing superhydrophobic surfaces by spin-coating of polydimethylsiloxane. PG - 18-27 LID - S0021-9797(17)30932-3 [pii] LID - 10.1016/j.jcis.2017.08.027 [doi] AB - HYPOTHESIS: Superhydrophobic surfaces easily lose their excellent water-repellency after damages, which limit their broad applications in practice. Thus, the fabrication of superhydrophobic surfaces with excellent durability and thermal healing should be taken into consideration. EXPERIMENTS: In this work, robust superhydrophobic surfaces with thermal healing were successfully fabricated by spin-coating method. To achieve superhydrophobicity, cost-less and fluoride-free polydimethylsiloxane (PDMS) was spin-coated on rough aluminum substrates. FINDINGS: After being spin-coated for one cycle, the superhydrophobic PDMS coated hierarchical aluminum (PDMS-H-Al) surfaces showed excellent tolerance to various chemical and mechanical damages in lab, and outdoor damages for 90days. When the PDMS-H-Al surfaces underwent severe damages such as oil contamination (peanut oil with high boiling point) or sandpaper abrasion (500g of force for 60cm), their superhydrophobicity would lose. Interestingly, through a heating process, cyclic oligomers generating from the partially decomposed PDMS acted as low-surface-energy substance on the damaged rough surfaces, leading to the recovery of superhydrophobicity. The relationship between the spin-coating cycles and surface wettability was also investigated. This paper provides a facile, fluoride-free and efficient method to fabricate superhydrophobic surfaces with thermal healing. CI - Copyright (c) 2017. Published by Elsevier Inc. FAU - Long, Mengying AU - Long M AD - College of Materials Science and Engineering, South China University of Technology, Wushan Road, Tianhe District, Guangzhou 510640, PR China. FAU - Peng, Shan AU - Peng S AD - College of Materials Science and Engineering, South China University of Technology, Wushan Road, Tianhe District, Guangzhou 510640, PR China. Electronic address: pengshan5213@163.com. FAU - Deng, Wanshun AU - Deng W AD - College of Materials Science and Engineering, South China University of Technology, Wushan Road, Tianhe District, Guangzhou 510640, PR China. FAU - Yang, Xiaojun AU - Yang X AD - College of Materials Science and Engineering, South China University of Technology, Wushan Road, Tianhe District, Guangzhou 510640, PR China. FAU - Miao, Kai AU - Miao K AD - College of Materials Science and Engineering, South China University of Technology, Wushan Road, Tianhe District, Guangzhou 510640, PR China. FAU - Wen, Ni AU - Wen N AD - College of Materials Science and Engineering, South China University of Technology, Wushan Road, Tianhe District, Guangzhou 510640, PR China. FAU - Miao, Xinrui AU - Miao X AD - College of Materials Science and Engineering, South China University of Technology, Wushan Road, Tianhe District, Guangzhou 510640, PR China. FAU - Deng, Wenli AU - Deng W AD - College of Materials Science and Engineering, South China University of Technology, Wushan Road, Tianhe District, Guangzhou 510640, PR China. Electronic address: wldeng@scut.edu.cn. LA - eng PT - Journal Article DEP - 20170810 PL - United States TA - J Colloid Interface Sci JT - Journal of colloid and interface science JID - 0043125 OTO - NOTNLM OT - Healing OT - Hierarchical OT - PDMS OT - Robust OT - Superhydrophobic OT - Thermal EDAT- 2017/08/19 06:00 MHDA- 2017/08/19 06:01 CRDT- 2017/08/19 06:00 PHST- 2017/05/31 00:00 [received] PHST- 2017/08/09 00:00 [revised] PHST- 2017/08/09 00:00 [accepted] PHST- 2017/08/19 06:00 [pubmed] PHST- 2017/08/19 06:01 [medline] PHST- 2017/08/19 06:00 [entrez] AID - S0021-9797(17)30932-3 [pii] AID - 10.1016/j.jcis.2017.08.027 [doi] PST - ppublish SO - J Colloid Interface Sci. 2017 Dec 15;508:18-27. doi: 10.1016/j.jcis.2017.08.027. Epub 2017 Aug 10.