PMID- 28843602
OWN - NLM
STAT- MEDLINE
DCOM- 20171207
LR  - 20181202
IS  - 1873-3778 (Electronic)
IS  - 0021-9673 (Linking)
VI  - 1517
DP  - 2017 Sep 29
TI  - An organically modified silica aerogel for online in-tube solid-phase 
      microextraction.
PG  - 203-208
LID - S0021-9673(17)31096-8 [pii]
LID - 10.1016/j.chroma.2017.07.075 [doi]
AB  - Aerogels have received considerable attentions because of its porous, high 
      specific surface, unique properties and environmental friendliness. In this work, 
      an organically modified silica aerogel was functionalized on the basalt fibers 
      (BFs) and filled into a poly(ether ether ketone) (PEEK) tube, which was coupled 
      with high performance liquid chromatography (HPLC) for in-tube solid-phase 
      microextraction (IT-SPME). The aerogel was characterized by scanning electron 
      microscopy (SEM) and fourier transform infrared spectrometry (FT-IR). The 
      extraction efficiency of the tube was systematically investigated and shown 
      enrichment factors from 2346 to 3132. An automated, sensitive and selective 
      method was developed for the determination of five estrogens. The linear range 
      was from 0.03 to 100mugL(-1) with correlation coefficients (r) higher than 0.9989, 
      and low detection limits (LODs) were 0.01-0.05mugL(-1). The relative standard 
      deviations (RSDs) for intra-day and inter-day were less than 4.5% and 6.7% (n=6), 
      respectively. Finally, the analysis method was successfully applied to detect 
      estrogens in sewage and emollient water samples.
CI  - Copyright (c) 2017 Elsevier B.V. All rights reserved.
FAU - Bu, Yanan
AU  - Bu Y
AD  - Key Laboratory of Interfacial Reaction & Sensing Analysis in Universities of 
      Shandong, School of Chemistry and Chemical Engineering, University of Jinan, 
      Jinan 250022, PR China.
FAU - Feng, Juanjuan
AU  - Feng J
AD  - Key Laboratory of Interfacial Reaction & Sensing Analysis in Universities of 
      Shandong, School of Chemistry and Chemical Engineering, University of Jinan, 
      Jinan 250022, PR China.
FAU - Tian, Yu
AU  - Tian Y
AD  - Key Laboratory of Interfacial Reaction & Sensing Analysis in Universities of 
      Shandong, School of Chemistry and Chemical Engineering, University of Jinan, 
      Jinan 250022, PR China.
FAU - Wang, Xiuqin
AU  - Wang X
AD  - Key Laboratory of Interfacial Reaction & Sensing Analysis in Universities of 
      Shandong, School of Chemistry and Chemical Engineering, University of Jinan, 
      Jinan 250022, PR China.
FAU - Sun, Min
AU  - Sun M
AD  - Key Laboratory of Interfacial Reaction & Sensing Analysis in Universities of 
      Shandong, School of Chemistry and Chemical Engineering, University of Jinan, 
      Jinan 250022, PR China. Electronic address: chm_sunm@ujn.edu.cn.
FAU - Luo, Chuannan
AU  - Luo C
AD  - Key Laboratory of Interfacial Reaction & Sensing Analysis in Universities of 
      Shandong, School of Chemistry and Chemical Engineering, University of Jinan, 
      Jinan 250022, PR China. Electronic address: chm_luocn@ujn.edu.cn.
LA  - eng
PT  - Journal Article
DEP - 20170724
PL  - Netherlands
TA  - J Chromatogr A
JT  - Journal of chromatography. A
JID - 9318488
RN  - 0 (Estrogens)
RN  - 0 (Gels)
RN  - 0 (Ketones)
RN  - 0 (Sewage)
RN  - 0 (Silicates)
RN  - 0 (Water Pollutants, Chemical)
RN  - 0 (basalt)
RN  - 7631-86-9 (Silicon Dioxide)
SB  - IM
MH  - Chromatography, High Pressure Liquid
MH  - Environmental Monitoring/*methods
MH  - Estrogens/analysis
MH  - Fresh Water/chemistry
MH  - Gels/chemistry
MH  - Ketones/chemistry
MH  - Limit of Detection
MH  - Microscopy, Electron, Scanning
MH  - Sewage/chemistry
MH  - Silicates/chemistry
MH  - Silicon Dioxide/*chemistry
MH  - Solid Phase Microextraction/instrumentation/*methods
MH  - Spectroscopy, Fourier Transform Infrared
MH  - Water Pollutants, Chemical/analysis
OTO - NOTNLM
OT  - Basalt fibers
OT  - Estrogens
OT  - High performance liquid chromatography
OT  - In-tube solid-phase microextraction
OT  - Online analysis
OT  - Silica aerogel
EDAT- 2017/08/28 06:00
MHDA- 2017/12/08 06:00
CRDT- 2017/08/28 06:00
PHST- 2017/05/25 00:00 [received]
PHST- 2017/07/18 00:00 [revised]
PHST- 2017/07/23 00:00 [accepted]
PHST- 2017/08/28 06:00 [pubmed]
PHST- 2017/12/08 06:00 [medline]
PHST- 2017/08/28 06:00 [entrez]
AID - S0021-9673(17)31096-8 [pii]
AID - 10.1016/j.chroma.2017.07.075 [doi]
PST - ppublish
SO  - J Chromatogr A. 2017 Sep 29;1517:203-208. doi: 10.1016/j.chroma.2017.07.075. Epub 
      2017 Jul 24.