PMID- 28848973
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20180220
LR  - 20180220
IS  - 1477-9234 (Electronic)
IS  - 1477-9226 (Linking)
VI  - 46
IP  - 35
DP  - 2017 Sep 12
TI  - Diverse dissolution-recrystallization structural transformations and sequential 
      Forster resonance energy transfer behavior of a luminescent porous Cd-MOF.
PG  - 11656-11663
LID - 10.1039/c7dt02697h [doi]
AB  - Metal-organic frameworks (MOFs) with light-harvesting building blocks provide an 
      excellent platform to study energy transfer in networks with well-defined 
      structures. Here, we report the synthesis, dissolution-recrystallization 
      structural transformation (DRST) and the Forster resonance energy transfer (FRET) 
      properties of a 2D microporous MOF [Cd(2)(L(1))(3)(Hdabco)(2)].5DMAc.6H(2)O(n) 
      (Cd-MOF, 1). Complex 1 can be dissolved in water and three other products with 
      different dimensions recrystallized from the aqueous solution under diverse 
      reaction conditions were obtained. Due to the porosity and excellent blue 
      luminescence properties of complex 1, we also studied the FRET process between 1 
      and guest dyes. Two distinct organic dye molecules viz., acridine orange (AO) and 
      rhodamine B (RhB), are encapsulated in 1 which has honeycomb-type nanochannels, 
      and their influence on fluorescence emission has also been studied. The 
      microporous complex 1 in (AO + RhB)@1 serves as an energy funnel that harvests 
      high energy excitation and channels it onto AO and then onto RhB. The 
      steady-state fluorescence and fluorescence dynamics of emission reveal 
      successfully the process of stepwise vectorial energy transfer. Therefore, MOFs 
      could be a class of promising host materials to be further explored in the field 
      of energy transfer between MOF-host and organic guests.
FAU - Cao, Li-Hui
AU  - Cao LH
AD  - College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 
      450001, China. zangsqzg@zzu.edu.cn weiyongli@zzu.edu.cn.
FAU - Li, Hai-Yang
AU  - Li HY
FAU - Xu, Hong
AU  - Xu H
FAU - Wei, Yong-Li
AU  - Wei YL
FAU - Zang, Shuang-Quan
AU  - Zang SQ
LA  - eng
PT  - Journal Article
PL  - England
TA  - Dalton Trans
JT  - Dalton transactions (Cambridge, England : 2003)
JID - 101176026
EDAT- 2017/08/30 06:00
MHDA- 2017/08/30 06:01
CRDT- 2017/08/30 06:00
PHST- 2017/08/30 06:00 [pubmed]
PHST- 2017/08/30 06:01 [medline]
PHST- 2017/08/30 06:00 [entrez]
AID - 10.1039/c7dt02697h [doi]
PST - ppublish
SO  - Dalton Trans. 2017 Sep 12;46(35):11656-11663. doi: 10.1039/c7dt02697h.