PMID- 28853276
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20180730
LR  - 20180730
IS  - 1944-8252 (Electronic)
IS  - 1944-8244 (Linking)
VI  - 9
IP  - 36
DP  - 2017 Sep 13
TI  - Light-Converting Polymer/Si Nanocrystal Composites with Stable 60-70% Quantum 
      Efficiency and Their Glass Laminates.
PG  - 30267-30272
LID - 10.1021/acsami.7b09265 [doi]
AB  - Thiol-ene polymer/Si nanocrystal bulk hybrids were synthesized from 
      alkyl-passivated Si nanocrystal (Si NC) toluene solutions. Radicals in the 
      polymer provided a copassivation of "dark" Si NCs, making them optically active 
      and leading to a substantial ensemble quantum yield increase. Optical stability 
      over several months was confirmed. The presented materials exhibit the highest 
      photoluminescence quantum yield ( approximately 65%) of any solid-state Si NC hybrid reported 
      to date. The broad tunability of thiol-ene polymer reactivity provides facile 
      glass integration, as demonstrated by a laminated structure. This, together with 
      extremely fast polymerization, makes the demonstrated hybrid material a promising 
      candidate for light converting applications.
FAU - Marinins, Aleksandrs
AU  - Marinins A
AUID- ORCID: 0000-0002-0728-6684
AD  - Department of Applied Physics, KTH - Royal Institute of Technology , 16440 
      Stockholm, Sweden.
FAU - Zandi Shafagh, Reza
AU  - Zandi Shafagh R
AD  - Department of Micro and Nanosystems, KTH - Royal Institute of Technology , 10044 
      Stockholm, Sweden.
FAU - van der Wijngaart, Wouter
AU  - van der Wijngaart W
AUID- ORCID: 0000-0001-8248-6670
AD  - Department of Micro and Nanosystems, KTH - Royal Institute of Technology , 10044 
      Stockholm, Sweden.
FAU - Haraldsson, Tommy
AU  - Haraldsson T
AD  - Department of Micro and Nanosystems, KTH - Royal Institute of Technology , 10044 
      Stockholm, Sweden.
FAU - Linnros, Jan
AU  - Linnros J
AD  - Department of Applied Physics, KTH - Royal Institute of Technology , 16440 
      Stockholm, Sweden.
FAU - Veinot, Jonathan G C
AU  - Veinot JGC
AUID- ORCID: 0000-0001-7511-510X
AD  - Department of Chemistry, University of Alberta , Edmonton, Alberta T6G 2G2, 
      Canada.
FAU - Popov, Sergei
AU  - Popov S
AD  - Department of Applied Physics, KTH - Royal Institute of Technology , 16440 
      Stockholm, Sweden.
FAU - Sychugov, Ilya
AU  - Sychugov I
AUID- ORCID: 0000-0003-2562-0540
AD  - Department of Applied Physics, KTH - Royal Institute of Technology , 16440 
      Stockholm, Sweden.
LA  - eng
PT  - Journal Article
DEP - 20170831
PL  - United States
TA  - ACS Appl Mater Interfaces
JT  - ACS applied materials & interfaces
JID - 101504991
OTO - NOTNLM
OT  - Si nanocrystals
OT  - hybrids
OT  - laminates
OT  - photoluminescence
OT  - photovoltaics
OT  - polymers
EDAT- 2017/08/31 06:00
MHDA- 2017/08/31 06:01
CRDT- 2017/08/31 06:00
PHST- 2017/08/31 06:00 [pubmed]
PHST- 2017/08/31 06:01 [medline]
PHST- 2017/08/31 06:00 [entrez]
AID - 10.1021/acsami.7b09265 [doi]
PST - ppublish
SO  - ACS Appl Mater Interfaces. 2017 Sep 13;9(36):30267-30272. doi: 
      10.1021/acsami.7b09265. Epub 2017 Aug 31.