PMID- 28905184
OWN - NLM
STAT- MEDLINE
DCOM- 20180911
LR  - 20181202
IS  - 1614-7499 (Electronic)
IS  - 0944-1344 (Linking)
VI  - 24
IP  - 31
DP  - 2017 Nov
TI  - Energy transfer and kinetics in mechanochemistry.
PG  - 24562-24571
LID - 10.1007/s11356-017-0028-9 [doi]
AB  - Mechanochemistry (MC) exerts extraordinary degradation and decomposition effects 
      on many chlorinated, brominated, and even fluorinated persistent organic 
      pollutants (POPs). However, its application is still limited by inadequate study 
      of its reaction kinetic aspects. In the present work, the ball motion and energy 
      transfer in planetary ball mill are investigated in some detail. Almost all 
      milling parameters are summarised in a single factor-total effective impact 
      energy. Furthermore, the MC kinetic between calcium oxide/Al and 
      hexachlorobenzene is well established and modelled. The results indicate that 
      total effective impact energy and reagent ratio are the two factors sufficient 
      for describing the MC degradation degree of POPs. The reaction rate constant only 
      depends on the chemical properties of reactants, so it could be used as an 
      important index to appraise the quality of MC additives. This model successfully 
      predicts the reaction rate for different operating conditions, indicating that it 
      could be suitably applied for conducting MC reactions in other reactors.
FAU - Chen, Zhiliang
AU  - Chen Z
AD  - State Key Laboratory for Clean Energy Utilization, Institute for Thermal Power 
      Engineering, Zhejiang University, Hangzhou, 310027, China.
FAU - Lu, Shengyong
AU  - Lu S
AD  - State Key Laboratory for Clean Energy Utilization, Institute for Thermal Power 
      Engineering, Zhejiang University, Hangzhou, 310027, China. lushy@zju.edu.cn.
FAU - Mao, Qiongjing
AU  - Mao Q
AD  - Zhejiang University of Water Resources and Electric Power, College of 
      Architecture Engineering, Hangzhou, 310018, China.
FAU - Buekens, Alfons
AU  - Buekens A
AD  - State Key Laboratory for Clean Energy Utilization, Institute for Thermal Power 
      Engineering, Zhejiang University, Hangzhou, 310027, China.
FAU - Wang, Yuting
AU  - Wang Y
AD  - State Key Laboratory for Clean Energy Utilization, Institute for Thermal Power 
      Engineering, Zhejiang University, Hangzhou, 310027, China.
FAU - Yan, Jianhua
AU  - Yan J
AD  - State Key Laboratory for Clean Energy Utilization, Institute for Thermal Power 
      Engineering, Zhejiang University, Hangzhou, 310027, China.
LA  - eng
PT  - Journal Article
DEP - 20170913
PL  - Germany
TA  - Environ Sci Pollut Res Int
JT  - Environmental science and pollution research international
JID - 9441769
RN  - 0 (Calcium Compounds)
RN  - 0 (Oxides)
RN  - 4Z87H0LKUY (Hexachlorobenzene)
RN  - C7X2M0VVNH (lime)
SB  - IM
MH  - Calcium Compounds/chemistry
MH  - *Energy Transfer
MH  - Environmental Restoration and Remediation/methods
MH  - Hexachlorobenzene/chemistry
MH  - Kinetics
MH  - *Mechanical Phenomena
MH  - Models, Chemical
MH  - Motion
MH  - Oxides/chemistry
OTO - NOTNLM
OT  - Additives
OT  - Energy transfer
OT  - Hexachlorobenzene (HCBz)
OT  - Kinetic model
OT  - Mechanochemical degradation
OT  - Persistent organic pollutants (POPs)
EDAT- 2017/09/15 06:00
MHDA- 2018/09/12 06:00
CRDT- 2017/09/15 06:00
PHST- 2017/07/17 00:00 [received]
PHST- 2017/08/23 00:00 [accepted]
PHST- 2017/09/15 06:00 [pubmed]
PHST- 2018/09/12 06:00 [medline]
PHST- 2017/09/15 06:00 [entrez]
AID - 10.1007/s11356-017-0028-9 [pii]
AID - 10.1007/s11356-017-0028-9 [doi]
PST - ppublish
SO  - Environ Sci Pollut Res Int. 2017 Nov;24(31):24562-24571. doi: 
      10.1007/s11356-017-0028-9. Epub 2017 Sep 13.