PMID- 28914059 OWN - NLM STAT- MEDLINE DCOM- 20171222 LR - 20171222 IS - 1520-5118 (Electronic) IS - 0021-8561 (Linking) VI - 65 IP - 41 DP - 2017 Oct 18 TI - Physiochemical Characteristics and Molecular Structures for Digestible Carbohydrates of Silages. PG - 8979-8991 LID - 10.1021/acs.jafc.7b01032 [doi] AB - The main objectives of this study were (1) to assess the magnitude of differences among new barley silage varieties (BS) selected for varying rates of in vitro neutral detergent fiber (NDF) digestibility (ivNDFD; Cowboy BS with higher ivNDFD, Copeland BS with intermediate ivNDFD, and Xena BS with lower ivNDFD) with regard to their carbohydrate (CHO) molecular makeup, CHO chemical fractions, and rumen degradability in dairy cows in comparison with a new corn silage hybrid (Pioneer 7213R) and (2) to quantify the strength and pattern of association between the molecular structures and digestibility of carbohydrates. The carbohydrate-related molecular structure spectral data was measured using advanced vibrational molecular spectroscopy (FT/IR). In comparison to BS, corn silage showed a significantly (P < 0.05) higher level of starch and energy content and higher degradation of dry matter (DM). Cowboy BS had lower feeding value (higher indigestible fiber content and lower starch content) and lower DM degradation in the rumen compared to other BS varieties (P < 0.05). The spectral intensities of carbohydrates were significantly (P < 0.05) correlated with digestible carbohydrate content of the silages. In conclusion, the univariate approach with only one-factor consideration (ivNDFD) might not be a satisfactory method for evaluating and ranking BS quality. FT/IR molecular spectroscopy can be used to evaluate silage quality rapidly, particularly the digestible fiber content. FAU - Refat, Basim AU - Refat B AUID- ORCID: 0000-0002-2902-153X AD - Department of Animal and Poultry Science, College of Agriculture and Bioresources, University of Saskatchewan , Saskatoon, S7N 5A8 SK, Canada. FAU - Prates, Luciana L AU - Prates LL AUID- ORCID: 0000-0001-8398-6749 AD - Department of Animal and Poultry Science, College of Agriculture and Bioresources, University of Saskatchewan , Saskatoon, S7N 5A8 SK, Canada. FAU - Khan, Nazir A AU - Khan NA AD - Department of Animal and Poultry Science, College of Agriculture and Bioresources, University of Saskatchewan , Saskatoon, S7N 5A8 SK, Canada. AD - Department of Animal Nutrition, The University of Agriculture Peshawar , Peshawar, 25130 KP, Pakistan. FAU - Lei, Yaogeng AU - Lei Y AD - Department of Animal and Poultry Science, College of Agriculture and Bioresources, University of Saskatchewan , Saskatoon, S7N 5A8 SK, Canada. FAU - Christensen, David A AU - Christensen DA AD - Department of Animal and Poultry Science, College of Agriculture and Bioresources, University of Saskatchewan , Saskatoon, S7N 5A8 SK, Canada. FAU - McKinnon, John J AU - McKinnon JJ AD - Department of Animal and Poultry Science, College of Agriculture and Bioresources, University of Saskatchewan , Saskatoon, S7N 5A8 SK, Canada. FAU - Yu, Peiqiang AU - Yu P AD - Department of Animal and Poultry Science, College of Agriculture and Bioresources, University of Saskatchewan , Saskatoon, S7N 5A8 SK, Canada. AD - College of Life Science and Engineering, Foshan University , Guangdong, China. LA - eng PT - Journal Article DEP - 20171005 PL - United States TA - J Agric Food Chem JT - Journal of agricultural and food chemistry JID - 0374755 RN - 0 (Carbohydrates) RN - 9005-25-8 (Starch) SB - IM MH - Animal Feed/*analysis MH - Animals MH - Carbohydrates/*chemistry MH - Cattle/*metabolism MH - Digestion MH - Hordeum/*chemistry/metabolism MH - Rumen/metabolism MH - Silage/*analysis MH - Starch/chemistry/metabolism MH - Zea mays/*chemistry/metabolism OTO - NOTNLM OT - barley silage OT - carbohydrate structure OT - corn silage OT - molecular spectroscopy EDAT- 2017/09/16 06:00 MHDA- 2017/12/23 06:00 CRDT- 2017/09/16 06:00 PHST- 2017/09/16 06:00 [pubmed] PHST- 2017/12/23 06:00 [medline] PHST- 2017/09/16 06:00 [entrez] AID - 10.1021/acs.jafc.7b01032 [doi] PST - ppublish SO - J Agric Food Chem. 2017 Oct 18;65(41):8979-8991. doi: 10.1021/acs.jafc.7b01032. Epub 2017 Oct 5.