PMID- 28939840
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20240327
IS  - 2045-2322 (Electronic)
IS  - 2045-2322 (Linking)
VI  - 7
IP  - 1
DP  - 2017 Sep 22
TI  - Tuneable pressure effects in graphene oxide layers.
PG  - 12159
LID - 10.1038/s41598-017-12444-x [doi]
LID - 12159
AB  - Tuneable pressure effects associated with changing interlayer distances in 
      two-dimensional graphene oxide (GO)/reduced GO (rGO) layers are demonstrated 
      through monitoring the changes in the spin-crossover (SCO) temperature (T (1/2)) 
      of [Fe(Htrz)(2)(trz)](BF(4)) nanoparticles (NPs) incorporated in the interlayer 
      spaces of the GO/rGO layers. The interlayer separation along the GO to GO/rGO-NP 
      composites to rGO series decreases smoothly from 9.00 A (for GO) to 3.50 A (for 
      rGO) as the temperature employed for the thermal reduction treatments of the 
      GO-NP composites is increased. At the same time, T (1/2) increases from 351 K to 
      362 K along the series. This T (1/2) increment of 11 K corresponds to that 
      observed for pristine [Fe(Htrz)(2)(trz)](BF(4)) NPs under a hydrostatic pressure 
      of 38 MPa. The influence of the stacked layer structures on the pseudo-pressure 
      effects has been further probed by investigating the differences in T (1/2) for 
      [Fe(Htrz)(2)(trz)](BF(4)) that is present in the composite as larger bulk 
      particles rather than as NPs.
FAU - Sekimoto, Yusuke
AU  - Sekimoto Y
AD  - Department of Chemistry, Graduate School of Science and Technology, Kumamoto 
      University, 2-39-1 Kurokami, Chuo-ku, Kumamoto, 860-8555, Japan.
FAU - Ohtani, Ryo
AU  - Ohtani R
AD  - Department of Chemistry, Graduate School of Science and Technology, Kumamoto 
      University, 2-39-1 Kurokami, Chuo-ku, Kumamoto, 860-8555, Japan.
FAU - Nakamura, Masaaki
AU  - Nakamura M
AD  - Department of Chemistry, Graduate School of Science and Technology, Kumamoto 
      University, 2-39-1 Kurokami, Chuo-ku, Kumamoto, 860-8555, Japan.
FAU - Koinuma, Michio
AU  - Koinuma M
AD  - Department of Chemistry, Graduate School of Science and Technology, Kumamoto 
      University, 2-39-1 Kurokami, Chuo-ku, Kumamoto, 860-8555, Japan.
FAU - Lindoy, Leonard F
AU  - Lindoy LF
AD  - School of Chemistry, The University of Sydney, Sydney, NSW, 2006, Australia.
FAU - Hayami, Shinya
AU  - Hayami S
AUID- ORCID: 0000-0001-8392-2382
AD  - Department of Chemistry, Graduate School of Science and Technology, Kumamoto 
      University, 2-39-1 Kurokami, Chuo-ku, Kumamoto, 860-8555, Japan. 
      hayami@kumamoto-u.ac.jp.
AD  - Institute of Pulsed Power Science (IPPS), Kumamoto University, 2-39-1 Kurokami, 
      Chuo-ku, Kumamoto, 860-8555, Japan. hayami@kumamoto-u.ac.jp.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20170922
PL  - England
TA  - Sci Rep
JT  - Scientific reports
JID - 101563288
PMC - PMC5610342
COIS- The authors declare that they have no competing interests.
EDAT- 2017/09/25 06:00
MHDA- 2017/09/25 06:01
PMCR- 2017/09/22
CRDT- 2017/09/24 06:00
PHST- 2017/07/18 00:00 [received]
PHST- 2017/09/05 00:00 [accepted]
PHST- 2017/09/24 06:00 [entrez]
PHST- 2017/09/25 06:00 [pubmed]
PHST- 2017/09/25 06:01 [medline]
PHST- 2017/09/22 00:00 [pmc-release]
AID - 10.1038/s41598-017-12444-x [pii]
AID - 12444 [pii]
AID - 10.1038/s41598-017-12444-x [doi]
PST - epublish
SO  - Sci Rep. 2017 Sep 22;7(1):12159. doi: 10.1038/s41598-017-12444-x.