PMID- 28942347
OWN - NLM
STAT- MEDLINE
DCOM- 20180625
LR  - 20191210
IS  - 1873-4235 (Electronic)
IS  - 0956-5663 (Linking)
VI  - 100
DP  - 2018 Feb 15
TI  - A novel molecularly imprinted electrochemical sensor based on graphene quantum 
      dots coated on hollow nickel nanospheres with high sensitivity and selectivity 
      for the rapid determination of bisphenol S.
PG  - 341-347
LID - S0956-5663(17)30622-X [pii]
LID - 10.1016/j.bios.2017.09.016 [doi]
AB  - In this paper, a novel molecularly imprinted electrochemical sensor (MIECS) based 
      on a glassy carbon electrode (GCE) modified with graphene quantum dots (GQDs) 
      coated on hollow nickel nanospheres (hNiNS) for the rapid determination of 
      bisphenol S (BPS) was proposed for the first time. HNiNS and GQDs as electrode 
      modifications were used to enlarge the active area and electron-transport ability 
      for amplifying the sensor signal, while molecularly imprinted polymer (MIP) film 
      was electropolymerized by using pyrrole as monomer and BPS as template to detect 
      BPS via cyclic voltammetry (CV). Scanning electron microscope (SEM), 
      energy-dispersive spectrometry (EDS), CV and differential pulse voltammetry (DPV) 
      were employed to characterize the fabricated sensor. Experimental conditions, 
      such as molar ratio of monomer to template, electropolymerization cycles, pH, 
      incubation time and elution time were optimized. The DPV response of the MIECS to 
      BPS was obtained in the linear range from 0.1 to 50muM with a low limit of 
      detection (LOD) of 0.03muM (S/N = 3) under the optimized conditions. The MIECS 
      exhibited excellent response towards BPS with high sensitivity, selectivity, good 
      reproducibility, and stability. In addition, the proposed MIECS was also 
      successfully applied for the determination of BPS in the plastic samples with 
      simple sample pretreatment.
CI  - Copyright (c) 2017 Elsevier B.V. All rights reserved.
FAU - Rao, Hanbing
AU  - Rao H
AD  - College of Science, Sichuan Agricultural University, Ya'an 625014, China.
FAU - Zhao, Xun
AU  - Zhao X
AD  - College of Science, Sichuan Agricultural University, Ya'an 625014, China.
FAU - Liu, Xin
AU  - Liu X
AD  - College of Science, Sichuan Agricultural University, Ya'an 625014, China.
FAU - Zhong, Ji
AU  - Zhong J
AD  - College of Science, Sichuan Agricultural University, Ya'an 625014, China.
FAU - Zhang, Zhaoyi
AU  - Zhang Z
AD  - College of Science, Sichuan Agricultural University, Ya'an 625014, China.
FAU - Zou, Ping
AU  - Zou P
AD  - College of Science, Sichuan Agricultural University, Ya'an 625014, China.
FAU - Jiang, Yuanyuan
AU  - Jiang Y
AD  - College of Science, Sichuan Agricultural University, Ya'an 625014, China.
FAU - Wang, Xianxiang
AU  - Wang X
AD  - College of Science, Sichuan Agricultural University, Ya'an 625014, China.
FAU - Wang, Yanying
AU  - Wang Y
AD  - College of Science, Sichuan Agricultural University, Ya'an 625014, China. 
      Electronic address: wangyy@sicau.edu.cn.
LA  - eng
PT  - Evaluation Study
PT  - Journal Article
DEP - 20170915
PL  - England
TA  - Biosens Bioelectron
JT  - Biosensors & bioelectronics
JID - 9001289
RN  - 0 (Phenols)
RN  - 0 (Plastics)
RN  - 0 (Sulfones)
RN  - 0 (Water Pollutants, Chemical)
RN  - 7782-42-5 (Graphite)
RN  - 7OV03QG267 (Nickel)
RN  - 80-09-1 (bis(4-hydroxyphenyl)sulfone)
SB  - IM
MH  - Biosensing Techniques/economics/methods
MH  - Electrochemical Techniques/economics/*methods
MH  - Graphite/chemistry
MH  - Limit of Detection
MH  - Molecular Imprinting/economics/*methods
MH  - Nanospheres/*chemistry/ultrastructure
MH  - Nickel/*chemistry
MH  - Phenols/*analysis
MH  - Plastics/chemistry
MH  - Quantum Dots/*chemistry/ultrastructure
MH  - Sulfones/*analysis
MH  - Time Factors
MH  - Water Pollutants, Chemical/analysis
OTO - NOTNLM
OT  - Bisphenol S
OT  - Electrochemical determination
OT  - Electrochemical sensor
OT  - Graphene quantum dots
OT  - Hollow nickel nanospheres
OT  - Molecularly imprinted polymers
EDAT- 2017/09/25 06:00
MHDA- 2018/06/26 06:00
CRDT- 2017/09/25 06:00
PHST- 2017/07/17 00:00 [received]
PHST- 2017/09/02 00:00 [revised]
PHST- 2017/09/12 00:00 [accepted]
PHST- 2017/09/25 06:00 [pubmed]
PHST- 2018/06/26 06:00 [medline]
PHST- 2017/09/25 06:00 [entrez]
AID - S0956-5663(17)30622-X [pii]
AID - 10.1016/j.bios.2017.09.016 [doi]
PST - ppublish
SO  - Biosens Bioelectron. 2018 Feb 15;100:341-347. doi: 10.1016/j.bios.2017.09.016. 
      Epub 2017 Sep 15.