PMID- 28948578 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20201001 IS - 1931-7573 (Print) IS - 1556-276X (Electronic) IS - 1556-276X (Linking) VI - 12 IP - 1 DP - 2017 Sep 25 TI - Monodisperse Carbon Nanospheres with Hierarchical Porous Structure as Electrode Material for Supercapacitor. PG - 550 LID - 10.1186/s11671-017-2318-z [doi] LID - 550 AB - Carbon nanospheres with distinguishable microstructure were prepared by carbonization and subsequent KOH activation of F108/resorcinol-formaldehyde composites. The dosage of triblock copolymer Pluronic F108 is crucial to the microstructure differences. With the adding of F108, the polydisperse carbon nanospheres (PCNS) with microporous structure, monodisperse carbon nanospheres (MCNS) with hierarchical porous structure, and agglomerated carbon nanospheres (ACNS) were obtained. Their microstructure and capacitance properties were carefully compared. As a result of the synergetic effect of mono-dispersion spheres and hierarchical porous structures, the MCNS sample shows improved electrochemical performance, i.e., the highest specific capacitance of 224 F g(-1) (0.2 A g(-1)), the best rate capability (73% retention at 20 A g(-1)), and the most excellent capacitance retention of 93% over 10,000 cycles, making it to be the promising electrode material for high-performance supercapacitors. FAU - Yang, Xiutao AU - Yang X AD - School of Physics and Electronics, Central South University, Changsha, 410083, China. AD - Key Laboratory of Wetland Ecology and Environment, Northeast Institute of Geography and Agroecology, Chinese Academy of Sciences, Changchun, 130102, China. FAU - Xia, Hui AU - Xia H AD - School of Physics and Electronics, Central South University, Changsha, 410083, China. xhui73@csu.edu.cn. FAU - Liang, Zhongguan AU - Liang Z AD - School of Physics and Electronics, Central South University, Changsha, 410083, China. FAU - Li, Haiyan AU - Li H AD - Key Laboratory of Wetland Ecology and Environment, Northeast Institute of Geography and Agroecology, Chinese Academy of Sciences, Changchun, 130102, China. FAU - Yu, Hongwen AU - Yu H AD - Key Laboratory of Wetland Ecology and Environment, Northeast Institute of Geography and Agroecology, Chinese Academy of Sciences, Changchun, 130102, China. yuhw@neigae.ac.cn. LA - eng PT - Journal Article DEP - 20170925 PL - United States TA - Nanoscale Res Lett JT - Nanoscale research letters JID - 101279750 PMC - PMC5612903 OTO - NOTNLM OT - Carbon nanosphere OT - Energy storage and conversion OT - Monodisperse OT - Porous materials OT - Supercapacitor COIS- COMPETING INTERESTS: The authors declare that they have no competing interests. PUBLISHER'S NOTE: Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations. EDAT- 2017/09/28 06:00 MHDA- 2017/09/28 06:01 PMCR- 2017/09/25 CRDT- 2017/09/27 06:00 PHST- 2017/05/26 00:00 [received] PHST- 2017/09/19 00:00 [accepted] PHST- 2017/09/27 06:00 [entrez] PHST- 2017/09/28 06:00 [pubmed] PHST- 2017/09/28 06:01 [medline] PHST- 2017/09/25 00:00 [pmc-release] AID - 10.1186/s11671-017-2318-z [pii] AID - 2318 [pii] AID - 10.1186/s11671-017-2318-z [doi] PST - epublish SO - Nanoscale Res Lett. 2017 Sep 25;12(1):550. doi: 10.1186/s11671-017-2318-z.