PMID- 28962763
OWN - NLM
STAT- MEDLINE
DCOM- 20180725
LR  - 20181202
IS  - 1879-1344 (Electronic)
IS  - 0144-8617 (Linking)
VI  - 177
DP  - 2017 Dec 1
TI  - A crosslinked beta-cyclodextrin polymer used for rapid removal of a broad-spectrum 
      of organic micropollutants from water.
PG  - 224-231
LID - S0144-8617(17)30920-7 [pii]
LID - 10.1016/j.carbpol.2017.08.059 [doi]
AB  - Organic micropollutants in aquatic environment such as plasticizer, pesticide and 
      pharmaceuticals, have posed a serious threat to human health and are emerging as 
      a great challenge to humanity. Traditional water treatment techniques fail to 
      achieve high removal efficiency for low concentration of organic micropollutants. 
      Here we demonstrate a water-insoluble crosslinked beta-cyclodextrin (beta-CD) polymer 
      able to remove a broad-spectrum of organic micropollutants from water by rapid 
      adsorption. A family of beta-CD polymers (beta-CDPs) were synthesized by nucleophilic 
      aromatic substitution of beta-CD hydroxyl groups and 4,4'-difluorodiphenylsulfone. 
      The beta-CDPs were used to adsorb various organic micropollutants in water by static 
      or dynamic adsorption process. It was found that more than 99% micropollutants in 
      water were removed by flowing the feed water through the column of beta-CDPs. The 
      results of static adsorption experiments indicated the adsorption process was 
      fast and the adsorption capacity was very high (the maximal value was 113.0mg of 
      bisphenol A per gram of beta-CDP). The adsorption process was fitted well with the 
      quasi-second-order kinetics and the Langmuir isothermal adsorption model, 
      suggesting that it is mainly a chemical adsorption of monolayer. The 
      water-insoluble characteristic of the beta-CDPs is convenient for their separation 
      from the treated solution after adsorption saturation for regeneration and reuse. 
      The adsorption ability of beta-CDPs was kept nearly unchanged after five 
      filtration-regeneration cycles.
CI  - Copyright (c) 2017 Elsevier Ltd. All rights reserved.
FAU - Wang, Zhanghui
AU  - Wang Z
AD  - MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department 
      of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, PR 
      China.
FAU - Zhang, Peibin
AU  - Zhang P
AD  - MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department 
      of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, PR 
      China.
FAU - Hu, Fan
AU  - Hu F
AD  - MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department 
      of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, PR 
      China.
FAU - Zhao, Yifan
AU  - Zhao Y
AD  - MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department 
      of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, PR 
      China.
FAU - Zhu, Liping
AU  - Zhu L
AD  - MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department 
      of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, PR 
      China. Electronic address: lpzhu@zju.edu.cn.
LA  - eng
PT  - Journal Article
DEP - 20170819
PL  - England
TA  - Carbohydr Polym
JT  - Carbohydrate polymers
JID - 8307156
RN  - 0 (Cyclodextrins)
RN  - 0 (Organic Chemicals)
RN  - 0 (Polymers)
RN  - 0 (Water Pollutants, Chemical)
RN  - 0 (cyclodextrin polymer)
RN  - 059QF0KO0R (Water)
RN  - 9004-34-6 (Cellulose)
SB  - IM
MH  - Adsorption
MH  - Cellulose/*chemistry
MH  - Cyclodextrins/*chemistry
MH  - Organic Chemicals/*isolation & purification
MH  - Polymers
MH  - Water
MH  - Water Pollutants, Chemical/*isolation & purification
MH  - Water Purification/*methods
OTO - NOTNLM
OT  - 2,4-dichlorophenol (PubChem CID: 8449)
OT  - 2-naphthol (PubChem CID: 8663)
OT  - 4,4'-difluorodiphenylsulfone (PubChem CID: 67842)
OT  - Adsorption
OT  - Anhydrous potassium carbonate (PubChem CID: 11430)
OT  - Bis(4-hydroxyphenyl) sulfone (PubChem CID: 6626)
OT  - Bisphenol A (PubChem CID: 6623)
OT  - Dimethylacetamide (PubChem CID: 31374)
OT  - High adsorption capacity
OT  - Organic micropollutants
OT  - Propranolol hydrochloride (PubChem CID: 62882)
OT  - Rapid removal
OT  - Toluene (PubChem CID: 1140)
OT  - beta-Cyclodextrin polymer
OT  - beta-cyclodextrin (PubChem CID: 444041)
EDAT- 2017/10/01 06:00
MHDA- 2018/07/26 06:00
CRDT- 2017/10/01 06:00
PHST- 2017/07/01 00:00 [received]
PHST- 2017/08/02 00:00 [revised]
PHST- 2017/08/09 00:00 [accepted]
PHST- 2017/10/01 06:00 [entrez]
PHST- 2017/10/01 06:00 [pubmed]
PHST- 2018/07/26 06:00 [medline]
AID - S0144-8617(17)30920-7 [pii]
AID - 10.1016/j.carbpol.2017.08.059 [doi]
PST - ppublish
SO  - Carbohydr Polym. 2017 Dec 1;177:224-231. doi: 10.1016/j.carbpol.2017.08.059. Epub 
      2017 Aug 19.