PMID- 29049985
OWN - NLM
STAT- MEDLINE
DCOM- 20180530
LR  - 20181202
IS  - 1873-2976 (Electronic)
IS  - 0960-8524 (Linking)
VI  - 249
DP  - 2018 Feb
TI  - Insight into the structure-function relationships of deep eutectic solvents 
      during rice straw pretreatment.
PG  - 261-267
LID - S0960-8524(17)31836-9 [pii]
LID - 10.1016/j.biortech.2017.10.019 [doi]
AB  - Rice straw pretreatment mediated by choline chloride (ChCl) or lactic acid (Lac) 
      sequences deep eutectic solvents (DESs) was investigated in this work. Hydrogen 
      bond acceptors (HBAs) and hydrogen bond donors (HBDs) proved to be both important 
      for DESs pretreatment efficiency. DESs containing lots of hydroxyl or amino 
      groups with a high intermolecular hydrogen-bond (H-bond) strength exhibited weak 
      biomass deconstruction abilities. The presence of strong electron-withdrawing 
      groups in DESs was benefit for xylan removal, thus furnishing higher cellulose 
      digestibility. The relationships between the properties of DESs, xylan removal 
      and cellulose digestibility of pretreated biomass were established. It was found 
      that xylan removal was negatively correlated with the pKa values of HBDs, and the 
      enzymatic cellulose digestibility of the residues was linearly and positively 
      related to xylan removal instead of delignification. These results provide a 
      preliminary reference for rational design of novel DESs for biomass pretreatment.
CI  - Copyright (c) 2017 Elsevier Ltd. All rights reserved.
FAU - Hou, Xue-Dan
AU  - Hou XD
AD  - School of Chemical Engineering and Light Industry, Guangdong University of 
      Technology, Guangzhou 510006, China. Electronic address: houxd@gdut.edu.cn.
FAU - Li, Ao-Lin
AU  - Li AL
AD  - School of Chemical Engineering and Light Industry, Guangdong University of 
      Technology, Guangzhou 510006, China.
FAU - Lin, Kai-Peng
AU  - Lin KP
AD  - School of Chemical Engineering and Light Industry, Guangdong University of 
      Technology, Guangzhou 510006, China.
FAU - Wang, Yuan-Yuan
AU  - Wang YY
AD  - School of Chemical Engineering and Light Industry, Guangdong University of 
      Technology, Guangzhou 510006, China.
FAU - Kuang, Zhi-Yin
AU  - Kuang ZY
AD  - School of Chemical Engineering and Light Industry, Guangdong University of 
      Technology, Guangzhou 510006, China.
FAU - Cao, Shi-Lin
AU  - Cao SL
AD  - Department of Food Science, Foshan University, Foshan 528231, China.
LA  - eng
PT  - Journal Article
DEP - 20171007
PL  - England
TA  - Bioresour Technol
JT  - Bioresource technology
JID - 9889523
RN  - 0 (Solvents)
RN  - 9004-34-6 (Cellulose)
SB  - IM
MH  - Biomass
MH  - Cellulose
MH  - *Oryza
MH  - Solvents
MH  - Structure-Activity Relationship
OTO - NOTNLM
OT  - Cellulose digestibility
OT  - Deep eutectic solvents
OT  - Rice straw pretreatment
OT  - Structure-function relationships
OT  - Xylan removal
EDAT- 2017/10/20 06:00
MHDA- 2018/05/31 06:00
CRDT- 2017/10/20 06:00
PHST- 2017/08/16 00:00 [received]
PHST- 2017/10/04 00:00 [revised]
PHST- 2017/10/05 00:00 [accepted]
PHST- 2017/10/20 06:00 [pubmed]
PHST- 2018/05/31 06:00 [medline]
PHST- 2017/10/20 06:00 [entrez]
AID - S0960-8524(17)31836-9 [pii]
AID - 10.1016/j.biortech.2017.10.019 [doi]
PST - ppublish
SO  - Bioresour Technol. 2018 Feb;249:261-267. doi: 10.1016/j.biortech.2017.10.019. 
      Epub 2017 Oct 7.