PMID- 29107223
OWN - NLM
STAT- MEDLINE
DCOM- 20171204
LR  - 20171204
IS  - 1873-376X (Electronic)
IS  - 1570-0232 (Linking)
VI  - 1068-1069
DP  - 2017 Nov 15
TI  - Rapid gas chromatography with flame photometric detection of multiple 
      organophosphorus pesticides in Salvia miltiorrhizae after ultrasonication 
      assisted one-step extraction.
PG  - 233-238
LID - S1570-0232(17)31485-X [pii]
LID - 10.1016/j.jchromb.2017.10.025 [doi]
AB  - A simple and rapid gas chromatography-flame photometric detection (GC-FPD) method 
      was developed for the determination of 12 organophosphorus pesticides (OPPs) in 
      Salvia miltiorrhizae by using ultrasonication assisted one-step extraction (USAE) 
      without any clean-up steps. Some crucial parameters such as type of extraction 
      solvent were optimized to improve the method performance for trace analysis. Any 
      clean-up steps were negligent as no interferences were detected in the GC-FPD 
      chromatograms for sensitive detection. Under the optimized conditions, limits of 
      detection (LODs) and quantitation (LOQs) for all pesticides were in the range of 
      0.001-0.002mg/kg and 0.002-0.01mg/kg and 0.002-0.01mg/kg, respectively, which 
      were all below the regulatory maximum residue limits suggested. RSDs for method 
      precision (intra- and inter-day variations) were lower than 6.8% in approval with 
      international regulations. Average recovery rates for all pesticides at three 
      fortification levels (0.5, 1.0 and 5.0mg/kg) were in the range of 71.2-101.0% 
      with relative standard deviations (RSDs) <13%. The developed method was evaluated 
      for its feasibility in the simultaneous pre-concentration and determination of 12 
      OPPs in 32 batches of real S. miltiorrhizae samples. Only one pesticide 
      (dimethoate) out of the 12 targets was simultaneously detected in four samples at 
      concentrations of 0.016-0.02mg/kg. Dichlorvos and omethoate were found in the 
      same sample from Sichuan province at 0.004 and 0.027mg/kg, respectively. 
      Malathion and monocrotophos were determined in the other two samples at 0.014 and 
      0.028mg/kg, respectively. All the positive samples were confirmed by LC-MS/MS. 
      The simple, reliable and rapid USAE-GC-FPD method with many advantages over 
      traditional techniques would be preferred for trace analysis of multiple 
      pesticides in more complex matrices.
CI  - Copyright (c) 2017 Elsevier B.V. All rights reserved.
FAU - Zhang, Shanshan
AU  - Zhang S
AD  - Key Laboratory of Bioactive Substances and Resources Utilization of Chinese 
      Herbal Medicine, Ministry of Education, Institute of Medicinal Plant Development, 
      Chinese Academy of Medical Sciences & Peking Union Medical College, Beijing 
      100193, China; Pharmacy College, Jinzhou Medical University, Jinzhou 121001, 
      China.
FAU - Liu, Xiaofei
AU  - Liu X
AD  - Key Laboratory of Bioactive Substances and Resources Utilization of Chinese 
      Herbal Medicine, Ministry of Education, Institute of Medicinal Plant Development, 
      Chinese Academy of Medical Sciences & Peking Union Medical College, Beijing 
      100193, China.
FAU - Qin, Jia'an
AU  - Qin J
AD  - Pharmacy College, Jinzhou Medical University, Jinzhou 121001, China.
FAU - Yang, Meihua
AU  - Yang M
AD  - Key Laboratory of Bioactive Substances and Resources Utilization of Chinese 
      Herbal Medicine, Ministry of Education, Institute of Medicinal Plant Development, 
      Chinese Academy of Medical Sciences & Peking Union Medical College, Beijing 
      100193, China.
FAU - Zhao, Hongzheng
AU  - Zhao H
AD  - College of Traditional Chinese Medicine, Jilin Agricultural University, 
      Changchun, 130118, China.
FAU - Wang, Yong
AU  - Wang Y
AD  - Shimadzu Enterprise Management (China) Limited, Beijing, 100020, China.
FAU - Guo, Weiying
AU  - Guo W
AD  - Pharmacy College, Jinzhou Medical University, Jinzhou 121001, China.
FAU - Ma, Zhijie
AU  - Ma Z
AD  - Department of Pharmacy, Beijing Friendship Hospital, Capital Medical University, 
      Beijing 100050, China. Electronic address: 13811647091@163.com.
FAU - Kong, Weijun
AU  - Kong W
AD  - Key Laboratory of Bioactive Substances and Resources Utilization of Chinese 
      Herbal Medicine, Ministry of Education, Institute of Medicinal Plant Development, 
      Chinese Academy of Medical Sciences & Peking Union Medical College, Beijing 
      100193, China. Electronic address: kongwj302@126.com.
LA  - eng
PT  - Journal Article
DEP - 20171014
PL  - Netherlands
TA  - J Chromatogr B Analyt Technol Biomed Life Sci
JT  - Journal of chromatography. B, Analytical technologies in the biomedical and life 
      sciences
JID - 101139554
RN  - 0 (Organophosphorus Compounds)
RN  - 0 (Pesticides)
SB  - IM
MH  - Chemical Fractionation
MH  - Chromatography, Gas/*methods
MH  - Limit of Detection
MH  - Linear Models
MH  - Organophosphorus Compounds/*analysis/chemistry/isolation & purification
MH  - Pesticides/*analysis/chemistry/isolation & purification
MH  - Reproducibility of Results
MH  - Salvia miltiorrhiza/*chemistry
MH  - Sonication/*methods
OTO - NOTNLM
OT  - GC-FPD
OT  - Multi-residues determination
OT  - Organophosphorus pesticides
OT  - Salvia miltiorrhizae
OT  - Ultrasonication assisted one-step extraction
EDAT- 2017/11/07 06:00
MHDA- 2017/12/05 06:00
CRDT- 2017/11/07 06:00
PHST- 2017/08/27 00:00 [received]
PHST- 2017/10/12 00:00 [revised]
PHST- 2017/10/13 00:00 [accepted]
PHST- 2017/11/07 06:00 [pubmed]
PHST- 2017/12/05 06:00 [medline]
PHST- 2017/11/07 06:00 [entrez]
AID - S1570-0232(17)31485-X [pii]
AID - 10.1016/j.jchromb.2017.10.025 [doi]
PST - ppublish
SO  - J Chromatogr B Analyt Technol Biomed Life Sci. 2017 Nov 15;1068-1069:233-238. 
      doi: 10.1016/j.jchromb.2017.10.025. Epub 2017 Oct 14.