PMID- 29119489
OWN - NLM
STAT- MEDLINE
DCOM- 20181107
LR  - 20181113
IS  - 1614-7499 (Electronic)
IS  - 0944-1344 (Linking)
VI  - 25
IP  - 3
DP  - 2018 Jan
TI  - Sulfide influence on metal behavior in a polluted southern Mediterranean lagoon: 
      implications for management.
PG  - 2248-2264
LID - 10.1007/s11356-017-0529-6 [doi]
AB  - The degree of pyritization and degree of trace metal pyritization (DTMP) were 
      investigated in sediments from Ghar El Melh Lagoon (northern Tunisia) in order to 
      study metal deposition. A sediment core and 28 samples were thus taken in summer 
      2008, and metals and sulfate were analyzed in pore water/pyrite. Acid-volatile 
      sulfide and metals were simultaneously extracted from these two fractions and the 
      role of pyrite in the metal cycling studied. To examine pyrite presence and 
      mineralogical form in sediments, X-ray diffraction of the washed and decarbonated 
      sediment was performed along with scanning electron microscopy. Results showed 
      that pyrite is present in fromboidal and euhedral forms. Thermodynamic 
      calculation highlighted the formation of metallic sulfides and the 
      co-precipitation of metals with iron sulfides. The DTMP increases with depth, 
      indicating that these metals are either sequestered as sulfides or that they 
      co-precipitate with pyrite into the deep sediment.
FAU - Oueslati, Walid
AU  - Oueslati W
AD  - Laboratoire des Ressources Minerales et Environnement, Departement de Geologie, 
      Faculte des Sciences de Tunis, Universite de Tunis El Manar, 2092, Tunis, 
      Tunisia.
FAU - Helali, Mohamed Amine
AU  - Helali MA
AD  - Laboratoire des Ressources Minerales et Environnement, Departement de Geologie, 
      Faculte des Sciences de Tunis, Universite de Tunis El Manar, 2092, Tunis, 
      Tunisia.
FAU - Zaaboub, Noureddine
AU  - Zaaboub N
AD  - Institut des Sciences et Technologies de la Mer, Salammbo, Tunis, Tunisie.
FAU - Sebei, Abdelaziz
AU  - Sebei A
AD  - Laboratoire des Ressources Minerales et Environnement, Departement de Geologie, 
      Faculte des Sciences de Tunis, Universite de Tunis El Manar, 2092, Tunis, 
      Tunisia.
FAU - Added, Ayed
AU  - Added A
AD  - Laboratoire des Ressources Minerales et Environnement, Departement de Geologie, 
      Faculte des Sciences de Tunis, Universite de Tunis El Manar, 2092, Tunis, 
      Tunisia.
FAU - Aleya, Lotfi
AU  - Aleya L
AD  - Laboratoire de Chrono-Environnement, UMR CNRS 6249, Universite de Bourgogne 
      Franche-Comte, La Bouloie, F-25030, Besancon Cedex, France. 
      lotfi.aleya@univ-fcomte.fr.
LA  - eng
GR  - CNRS/111/
PT  - Journal Article
DEP - 20171108
PL  - Germany
TA  - Environ Sci Pollut Res Int
JT  - Environmental science and pollution research international
JID - 9441769
RN  - 0 (Metals, Heavy)
RN  - 0 (Sulfides)
RN  - 0 (Water Pollutants, Chemical)
RN  - 132N09W4PR (pyrite)
RN  - E1UOL152H7 (Iron)
SB  - IM
MH  - Environmental Monitoring/*methods
MH  - Geologic Sediments/*chemistry
MH  - Iron/*analysis/chemistry
MH  - Mediterranean Sea
MH  - Metals, Heavy/*analysis/chemistry
MH  - Seawater/chemistry
MH  - Sulfides/*analysis/chemistry
MH  - Tunisia
MH  - Water Pollutants, Chemical/*analysis/chemistry
OTO - NOTNLM
OT  - Ghar El Melh Lagoon
OT  - Management
OT  - Metals
OT  - Pyrite
OT  - Pyritization
OT  - Sediment
EDAT- 2017/11/10 06:00
MHDA- 2018/11/08 06:00
CRDT- 2017/11/10 06:00
PHST- 2017/04/07 00:00 [received]
PHST- 2017/10/19 00:00 [accepted]
PHST- 2017/11/10 06:00 [pubmed]
PHST- 2018/11/08 06:00 [medline]
PHST- 2017/11/10 06:00 [entrez]
AID - 10.1007/s11356-017-0529-6 [pii]
AID - 10.1007/s11356-017-0529-6 [doi]
PST - ppublish
SO  - Environ Sci Pollut Res Int. 2018 Jan;25(3):2248-2264. doi: 
      10.1007/s11356-017-0529-6. Epub 2017 Nov 8.