PMID- 29166826 OWN - NLM STAT- MEDLINE DCOM- 20181211 LR - 20220409 IS - 1477-0393 (Electronic) IS - 0748-2337 (Linking) VI - 34 IP - 1 DP - 2018 Jan TI - Polychlorinated biphenyls (PCBs) in River Niger, Nigeria: Occurrence, distribution and composition profiles. PG - 54-67 LID - 10.1177/0748233717736122 [doi] AB - Contamination of rivers with persistent organic pollutants (POPs) is an issue of current global concern. Polychlorinated biphenyls (PCBs) are POPs with origin from commercial, incineration and industrial sources. Hence, there is a need for monitoring their occurrence and distribution in the environment. This study assessed the occurrence, distribution and composition profiles of PCBs in River Niger, Nigeria. Surface and bottom water samples were collected in consecutive quarters for a period of 2 years, covering the beginning and end of the rainy seasons and the dry seasons, from five locations (Gurara, Lokoja, Onitsha, Brass and Nicolas) along River Niger. A total of 240 water samples were collected using a Van Dorn water sampler. EPA method 3510c was used with slight modifications for sample preparation and analysis. The PCBs were analysed using a Hewlett Packard GC 5890 Series 11 with electron capture detection, and confirmation was made using a Shimadzu GCMS QP2010. The higher molecular weight marker PCBs ( summation operatorCB 138, 153 and 180) were more dominant than the lighter homologues ( summation operatorCB 28, 52 and 101), while commercial sources Co-PCBs (80.8 +/- 61.7 to 288.3 +/- 102.0 ng L(-1)) were more dominant than the incineration sources (34.9 +/- 3.82 to 75.5 +/- 65.2 ng L(-1)). The POPs load in River Niger water varied in both time and space. In surface water of the River Niger, summation operatorPCBs were higher during the rainy season, as a result of storm run-off from land-based sources. In the Brass and Nicolas Rivers during the dry season, the summation operatorPCBs were higher during low tide. There was no noticeable pattern during the rainy season. It may be concluded from this study that the water of River Niger is not good for human consumption or abstraction of water from the river for drinking water treatment. FAU - Unyimadu, J P AU - Unyimadu JP AD - 1 Nigerian Institute for Oceanography and Marine Research, Victoria Island, Lagos, Nigeria. FAU - Osibanjo, O AU - Osibanjo O AD - 2 Department of Chemistry, University of Ibadan, Ibadan, Nigeria. FAU - Babayemi, J O AU - Babayemi JO AD - 3 Department of Chemical and Food Sciences, Bells University of Technology, Ota, Nigeria. LA - eng PT - Journal Article DEP - 20171122 PL - England TA - Toxicol Ind Health JT - Toxicology and industrial health JID - 8602702 RN - 0 (Water Pollutants, Chemical) RN - DFC2HB4I0K (Polychlorinated Biphenyls) SB - IM MH - Environmental Monitoring/*methods MH - Geologic Sediments/analysis MH - Niger MH - Polychlorinated Biphenyls/*analysis/chemistry MH - Rivers/*chemistry MH - Seasons MH - Water Pollutants, Chemical/*analysis OTO - NOTNLM OT - Polychlorinated biphenyls (PCBs) OT - River Niger OT - distribution and composition profiles of PCBs OT - persistent organic pollutants (POPs) OT - pollution EDAT- 2017/11/24 06:00 MHDA- 2018/12/12 06:00 CRDT- 2017/11/24 06:00 PHST- 2017/11/24 06:00 [pubmed] PHST- 2018/12/12 06:00 [medline] PHST- 2017/11/24 06:00 [entrez] AID - 10.1177/0748233717736122 [doi] PST - ppublish SO - Toxicol Ind Health. 2018 Jan;34(1):54-67. doi: 10.1177/0748233717736122. Epub 2017 Nov 22.