PMID- 29275933
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20180330
LR  - 20180330
IS  - 1879-1026 (Electronic)
IS  - 0048-9697 (Linking)
VI  - 624
DP  - 2018 May 15
TI  - Speciation of organic fraction does matter for source apportionment. Part 1: A 
      one-year campaign in Grenoble (France).
PG  - 1598-1611
LID - S0048-9697(17)33559-3 [pii]
LID - 10.1016/j.scitotenv.2017.12.135 [doi]
AB  - PM(10) source apportionment was performed by positive matrix factorization (PMF) 
      using specific primary and secondary organic molecular markers on samples 
      collected over a one year period (2013) at an urban station in Grenoble (France). 
      The results provided a 9-factor optimum solution, including sources rarely 
      apportioned in the literature, such as two types of primary biogenic organic 
      aerosols (fungal spores and plant debris), as well as specific biogenic and 
      anthropogenic secondary organic aerosols (SOA). These sources were identified 
      thanks to the use of key organic markers, namely, polyols, odd number higher 
      alkanes, and several SOA markers related to the oxidation of isoprene, alpha-pinene, 
      toluene and polycyclic aromatic hydrocarbons (PAHs). Primary and secondary 
      biogenic contributions together accounted for at least 68% of the total organic 
      carbon (OC) in the summer, while anthropogenic primary and secondary sources 
      represented at least 71% of OC during wintertime. A very significant contribution 
      of anthropogenic SOA was estimated in the winter during an intense PM pollution 
      event (PM(10)>50mugm(-3) for several days; 18% of PM(10) and 42% of OC). Specific 
      meteorological conditions with a stagnation of pollutants over 10days and 
      possibly Fenton-like chemistry and self-amplification cycle of SOA formation 
      could explain such high anthropogenic SOA concentrations during this period. 
      Finally, PMF outputs were also used to investigate the origins of humic-like 
      substances (HuLiS), which represented 16% of OC on an annual average basis. The 
      results indicated that HuLiS were mainly associated with biomass burning (22%), 
      secondary inorganic (22%), mineral dust (15%) and biogenic SOA (14%) factors. 
      This study is probably the first to state that HuLiS are significantly associated 
      with mineral dust.
CI  - Copyright (c) 2017 Elsevier B.V. All rights reserved.
FAU - Srivastava, Deepchandra
AU  - Srivastava D
AD  - INERIS, Parc Technologique Alata, BP 2, 60550 Verneuil-en-Halatte, France; CNRS, 
      EPOC, UMR 5805 CNRS, 33405 Talence, France; Universite de Bordeaux, EPOC, UMR 
      5805 CNRS, 33405 Talence, France.
FAU - Tomaz, Sophie
AU  - Tomaz S
AD  - INERIS, Parc Technologique Alata, BP 2, 60550 Verneuil-en-Halatte, France; CNRS, 
      EPOC, UMR 5805 CNRS, 33405 Talence, France; Universite de Bordeaux, EPOC, UMR 
      5805 CNRS, 33405 Talence, France.
FAU - Favez, Olivier
AU  - Favez O
AD  - INERIS, Parc Technologique Alata, BP 2, 60550 Verneuil-en-Halatte, France. 
      Electronic address: olivier.favez@ineris.fr.
FAU - Lanzafame, Grazia Maria
AU  - Lanzafame GM
AD  - INERIS, Parc Technologique Alata, BP 2, 60550 Verneuil-en-Halatte, France.
FAU - Golly, Benjamin
AU  - Golly B
AD  - Univ. Savoie Mont Blanc, LCME, 73000 Chambery, France; Univ. Grenoble Alpes, 
      CNRS, IRD, IGE, F-38000 Grenoble, France.
FAU - Besombes, Jean-Luc
AU  - Besombes JL
AD  - Univ. Savoie Mont Blanc, LCME, 73000 Chambery, France.
FAU - Alleman, Laurent Y
AU  - Alleman LY
AD  - IMT Lille Douai, SAGE, 59000 Lille, France.
FAU - Jaffrezo, Jean-Luc
AU  - Jaffrezo JL
AD  - Univ. Grenoble Alpes, CNRS, IRD, IGE, F-38000 Grenoble, France.
FAU - Jacob, Veronique
AU  - Jacob V
AD  - Univ. Grenoble Alpes, CNRS, IRD, IGE, F-38000 Grenoble, France.
FAU - Perraudin, Emilie
AU  - Perraudin E
AD  - CNRS, EPOC, UMR 5805 CNRS, 33405 Talence, France; Universite de Bordeaux, EPOC, 
      UMR 5805 CNRS, 33405 Talence, France.
FAU - Villenave, Eric
AU  - Villenave E
AD  - CNRS, EPOC, UMR 5805 CNRS, 33405 Talence, France; Universite de Bordeaux, EPOC, 
      UMR 5805 CNRS, 33405 Talence, France.
FAU - Albinet, Alexandre
AU  - Albinet A
AD  - INERIS, Parc Technologique Alata, BP 2, 60550 Verneuil-en-Halatte, France. 
      Electronic address: alexandre.albinet@ineris.fr.
LA  - eng
PT  - Journal Article
DEP - 20171221
PL  - Netherlands
TA  - Sci Total Environ
JT  - The Science of the total environment
JID - 0330500
OTO - NOTNLM
OT  - Aerosol
OT  - HuLiS
OT  - Molecular markers
OT  - Primary biogenic organics
OT  - SOA
OT  - Source apportionment
EDAT- 2017/12/26 06:00
MHDA- 2017/12/26 06:01
CRDT- 2017/12/26 06:00
PHST- 2017/10/03 00:00 [received]
PHST- 2017/12/11 00:00 [revised]
PHST- 2017/12/12 00:00 [accepted]
PHST- 2017/12/26 06:00 [pubmed]
PHST- 2017/12/26 06:01 [medline]
PHST- 2017/12/26 06:00 [entrez]
AID - S0048-9697(17)33559-3 [pii]
AID - 10.1016/j.scitotenv.2017.12.135 [doi]
PST - ppublish
SO  - Sci Total Environ. 2018 May 15;624:1598-1611. doi: 
      10.1016/j.scitotenv.2017.12.135. Epub 2017 Dec 21.