PMID- 29279566
OWN - NLM
STAT- MEDLINE
DCOM- 20180730
LR  - 20180730
IS  - 1880-4926 (Electronic)
IS  - 1343-4934 (Linking)
VI  - 59
IP  - 4
DP  - 2017
TI  - Trace of organic sulfur compounds detected from debonded interface between 
      transparent acrylic resin and gold alloy.
PG  - 511-517
LID - 10.2334/josnusd.16-0760 [doi]
AB  - The purpose of the current study was to evaluate the bonding performance of two 
      single-liquid primers, which contained 6-(4-vinylbenzyl-n-propyl) 
      amino-1,3,5-triazine-2,4-dithione (VTD) or 6-methacryloyloxyhexyl 2-thiouracil 
      5-carboxylate (MTU-6), used for bonding between metals and an acrylic resin. A 
      gold alloy and high-purity titanium were used as adherend materials, and a 
      transparent acrylic resin initiated with tri-n-butylborane derivative was 
      selected as the luting material. Both adherends were treated with one of the 
      primers and bonded with the luting material, after which shear bond strength was 
      determined. Fourier transform infrared spectroscopy was used to analyze debonded 
      resin specimens. Shear bond strength to gold alloy was significantly greater than 
      that to titanium for both the VTD and MTU-6 primers. A trace of thiol structure, 
      probably derived from VTD and MTU-6, was detected on resin surfaces debonded from 
      gold alloy. These results indicate that the two organic sulfur compounds, which 
      are stable in an atmospheric environment, are tautomerized into a thiol 
      structure, thus allowing adsorption onto noble metals. In addition, the adsorbed 
      thiol compounds contribute to chemical bonding between the acrylic resin and 
      noble metal alloy, as polymerizable adhesive functional monomers.
FAU - Hiraba, Haruto
AU  - Hiraba H
AD  - Division of Applied Oral Sciences, Nihon University Graduate School of Dentistry.
FAU - Koizumi, Hiroyasu
AU  - Koizumi H
AD  - Department of Fixed Prosthodontics, Nihon University School of Dentistry.
AD  - Division of Advanced Dental Treatment, Dental Research Center, Nihon University 
      School of Dentistry.
FAU - Nogawa, Hiroshi
AU  - Nogawa H
AD  - Department of Fixed Prosthodontics, Nihon University School of Dentistry.
AD  - Division of Advanced Dental Treatment, Dental Research Center, Nihon University 
      School of Dentistry.
FAU - Kodaira, Akihisa
AU  - Kodaira A
AD  - Division of Applied Oral Sciences, Nihon University Graduate School of Dentistry.
FAU - Okamura, Kentaro
AU  - Okamura K
AD  - Division of Applied Oral Sciences, Nihon University Graduate School of Dentistry.
FAU - Matsumura, Hideo
AU  - Matsumura H
AD  - Department of Fixed Prosthodontics, Nihon University School of Dentistry.
AD  - Division of Advanced Dental Treatment, Dental Research Center, Nihon University 
      School of Dentistry.
LA  - eng
PT  - Journal Article
PL  - Japan
TA  - J Oral Sci
JT  - Journal of oral science
JID - 9808942
RN  - 0 (Acrylic Resins)
RN  - 0 (Gold Alloys)
RN  - 0 (Organic Chemicals)
RN  - 70FD1KFU70 (Sulfur)
SB  - IM
MH  - Acrylic Resins/*chemistry
MH  - Gold Alloys/*chemistry
MH  - Materials Testing
MH  - Organic Chemicals/*analysis
MH  - Spectrophotometry, Infrared
MH  - Sulfur/*analysis
OTO - NOTNLM
OT  - adhesive
OT  - bonding
OT  - gold alloy
OT  - thiol
OT  - thione
EDAT- 2017/12/28 06:00
MHDA- 2018/07/31 06:00
CRDT- 2017/12/28 06:00
PHST- 2017/12/28 06:00 [entrez]
PHST- 2017/12/28 06:00 [pubmed]
PHST- 2018/07/31 06:00 [medline]
AID - 10.2334/josnusd.16-0760 [doi]
PST - ppublish
SO  - J Oral Sci. 2017;59(4):511-517. doi: 10.2334/josnusd.16-0760.