PMID- 29314158
OWN - NLM
STAT- MEDLINE
DCOM- 20181126
LR  - 20181126
IS  - 1522-2683 (Electronic)
IS  - 0173-0835 (Linking)
VI  - 39
IP  - 7
DP  - 2018 Apr
TI  - Synthesis of boronate-functionalized organic-inorganic hybrid monolithic column 
      for the separation of cis-diol containing compounds at low pH.
PG  - 924-932
LID - 10.1002/elps.201700337 [doi]
AB  - In this work, an organic-inorganic hybrid boronate affinity monolithic column was 
      prepared via "one-pot" process using 4-vinylphenylboronic acid as organic monomer 
      and divinylbenzene as cross-linker. The effects of reaction temperature, solvents 
      and composition of organic monomers on the column properties (e.g. morphology, 
      permeability, and mechanical stability) were investigated. A series of test 
      compounds including small neutral molecules, aromatic amines, and cis-diol 
      compounds were used to evaluate the retention behaviors of the prepared hybrid 
      monolithic column. The results demonstrated that the prepared hybrid monolith 
      exhibited mixed-interactions including hydrophilicity, cation exchange, and 
      boronate affinity interaction. The run-to-run, day-to-day and batch-to-batch 
      reproducibilities of the prepared hybrid monolith for thiourea's retention time 
      were satisfactory with the relative standard deviations (RSDs) less than 0.09, 
      1.45 and 4.05% (n = 3), respectively, indicating the effectiveness and 
      practicability of the proposed method.
CI  - (c) 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
FAU - Zhao, Heqing
AU  - Zhao H
AUID- ORCID: 0000-0002-9354-0203
AD  - College of Materials Science and Engineering, Fuzhou University, Fuzhou, P. R. 
      China.
FAU - Lyu, Haixia
AU  - Lyu H
AD  - College of Materials Science and Engineering, Fuzhou University, Fuzhou, P. R. 
      China.
FAU - Qin, Wenfei
AU  - Qin W
AD  - College of Materials Science and Engineering, Fuzhou University, Fuzhou, P. R. 
      China.
FAU - Xie, Zenghong
AU  - Xie Z
AD  - Institute of Food Safety and Environmental Monitoring, Fuzhou University, Fuzhou, 
      P. R. China.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20180119
PL  - Germany
TA  - Electrophoresis
JT  - Electrophoresis
JID - 8204476
RN  - 0 (4-vinylphenyl boronic acid)
RN  - 0 (Alcohols)
RN  - 0 (Amines)
RN  - 0 (Boronic Acids)
RN  - 0 (Vinyl Compounds)
RN  - 7631-86-9 (Silicon Dioxide)
RN  - IZ715T4SBU (divinyl benzene)
SB  - IM
MH  - Alcohols/*chemistry/isolation & purification
MH  - Amines/chemistry
MH  - Boronic Acids/*chemistry
MH  - Capillary Electrochromatography
MH  - Chromatography, Affinity
MH  - Hydrogen-Ion Concentration
MH  - Hydrophobic and Hydrophilic Interactions
MH  - Isomerism
MH  - Molecular Structure
MH  - Polymerization
MH  - Silicon Dioxide/chemistry
MH  - Structure-Activity Relationship
MH  - Vinyl Compounds/*chemistry
OTO - NOTNLM
OT  - Boronate affinity
OT  - Divinylbenzene
OT  - Pressurized capillary electrochromatography
OT  - "One-pot"
EDAT- 2018/01/10 06:00
MHDA- 2018/11/27 06:00
CRDT- 2018/01/10 06:00
PHST- 2017/08/23 00:00 [received]
PHST- 2017/11/13 00:00 [revised]
PHST- 2017/12/28 00:00 [accepted]
PHST- 2018/01/10 06:00 [pubmed]
PHST- 2018/11/27 06:00 [medline]
PHST- 2018/01/10 06:00 [entrez]
AID - 10.1002/elps.201700337 [doi]
PST - ppublish
SO  - Electrophoresis. 2018 Apr;39(7):924-932. doi: 10.1002/elps.201700337. Epub 2018 
      Jan 19.