PMID- 29351217
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20200930
IS  - 1996-1944 (Print)
IS  - 1996-1944 (Electronic)
IS  - 1996-1944 (Linking)
VI  - 11
IP  - 1
DP  - 2018 Jan 19
TI  - Nitrogen-Containing Functional Groups-Facilitated Acetone Adsorption by 
      ZIF-8-Derived Porous Carbon.
LID - 10.3390/ma11010159 [doi]
LID - 159
AB  - Nitrogen-doped porous carbon (ZC) is prepared by modification with ammonia for 
      increasing the specific surface area and surface polarity after carbonization of 
      zeolite imidazole framework-8 (ZIF-8). The structure and properties of these ZCs 
      were characterized by Transmission electron microscopy, X-ray diffraction, N(2) 
      sorption, X-ray photoelectron spectroscopy and Fourier transform infrared 
      spectroscopy. Through static adsorption tests of these carbons, the sample 
      obtained at 600  degrees C was selected as an excellent adsorbent, which exhibited an 
      excellent acetone capacity of 417.2 mg g(-1) (25  degrees C) with a very large surface 
      area and high-level nitrogen doping (13.55%). The microporosity, surface area and 
      N-containing groups of the materials, pyrrolic-N, pyridinic-N, and oxidized-N 
      groups in particular, were found to be the determining factors for acetone 
      adsorption by means of molecular simulation with density functional theory. These 
      findings indicate that N-doped microporous carbon materials are potential 
      promising adsorbents for acetone.
FAU - Li, Liqing
AU  - Li L
AD  - School of Energy Science and Engineering, Central South University, Changsha 
      410083, China. liqingli@hotmail.com.
FAU - Ma, Xiancheng
AU  - Ma X
AD  - School of Energy Science and Engineering, Central South University, Changsha 
      410083, China. maxiancheng@csu.edu.cn.
FAU - Chen, Ruofei
AU  - Chen R
AD  - School of Energy Science and Engineering, Central South University, Changsha 
      410083, China. ruofeichen@csu.edu.cn.
FAU - Wang, Chunhao
AU  - Wang C
AD  - School of Energy Science and Engineering, Central South University, Changsha 
      410083, China. wangchunhao@csu.edu.cn.
FAU - Lu, Mingming
AU  - Lu M
AD  - College of Engineering and Applied Science, University of Cincinnati, Cincinnati, 
      OH 45221, USA. mingming.lu@uc.edu.
LA  - eng
PT  - Journal Article
DEP - 20180119
PL  - Switzerland
TA  - Materials (Basel)
JT  - Materials (Basel, Switzerland)
JID - 101555929
PMC - PMC5793657
OTO - NOTNLM
OT  - ZIF-8
OT  - acetone adsorption
OT  - nitrogen-containing functional groups
OT  - porous carbon
COIS- The authors declare no conflict of interest.
EDAT- 2018/01/20 06:00
MHDA- 2018/01/20 06:01
PMCR- 2018/01/19
CRDT- 2018/01/20 06:00
PHST- 2017/12/19 00:00 [received]
PHST- 2018/01/17 00:00 [revised]
PHST- 2018/01/18 00:00 [accepted]
PHST- 2018/01/20 06:00 [entrez]
PHST- 2018/01/20 06:00 [pubmed]
PHST- 2018/01/20 06:01 [medline]
PHST- 2018/01/19 00:00 [pmc-release]
AID - ma11010159 [pii]
AID - materials-11-00159 [pii]
AID - 10.3390/ma11010159 [doi]
PST - epublish
SO  - Materials (Basel). 2018 Jan 19;11(1):159. doi: 10.3390/ma11010159.