PMID- 29426488
OWN - NLM
STAT- MEDLINE
DCOM- 20180924
LR  - 20180924
IS  - 1873-3573 (Electronic)
IS  - 0039-9140 (Linking)
VI  - 181
DP  - 2018 May 1
TI  - Magnetic Cu-MOFs embedded within graphene oxide nanocomposites for enhanced 
      preconcentration of benzenoid-containing insecticides.
PG  - 112-117
LID - S0039-9140(18)30006-7 [pii]
LID - 10.1016/j.talanta.2018.01.004 [doi]
AB  - Hybrid magnetic nanocomposites based on Cu-MOFs, graphene oxide (GO), and 
      Fe(3)O(4) nanoparticles (NPs) were prepared via chemical bonding approach, which 
      GO were used as platforms to load nanostructured Cu-MOFs and Fe(3)O(4) NPs. The 
      composite features both magnetic separation characteristics and high MOFs 
      porosity, making it an excellent adsorbent for magnetic solid-phase extraction 
      (MSPE). The as-synthesized nanocomposites are characterized by XRD, TGA, SEM, 
      TEM, nitrogen adsorption-desorption analysis and FT-IR spectroscopy. The 
      composites are used in MSPE of six aromatic insecticides from various real 
      samples prior to their quantification by HPLC. Amount of adsorbent, extraction 
      times, extraction temperature, desorption times and oscillation rate are 
      optimized. Under the optimal conditions, the method has a relative standard 
      deviations (RSDs) of 1.9-2.7%, and good linearity (correlation coefficients 
      higher than 0.9931). The low LOD and LOQ for six insecticides are found to be 
      0.30-1.58mugL(-1) and 1.0-5.2mugL(-1), respectively. The RSDs of within batch 
      extraction are 1.6-9.5% and 3.9-12% for batch to batch extraction. The 
      experimental results suggest that the nanocomposites have potential application 
      for removal of hazardous pollutants from effluents.
CI  - Copyright (c) 2018 Elsevier B.V. All rights reserved.
FAU - Wang, Xuemei
AU  - Wang X
AD  - College of Chemistry and Chemical Engineering, Northwest Normal University, 
      Lanzhou 730070, China; Key Laboratory of Bioelectrochemistry & Environmental 
      Analysis of Gansu Province, Lanzhou 730070, China. Electronic address: 
      wxm98@163.com.
FAU - Ma, Xiaomin
AU  - Ma X
AD  - College of Chemistry and Chemical Engineering, Northwest Normal University, 
      Lanzhou 730070, China.
FAU - Huang, Pengfei
AU  - Huang P
AD  - College of Chemistry and Chemical Engineering, Northwest Normal University, 
      Lanzhou 730070, China.
FAU - Wang, Juan
AU  - Wang J
AD  - College of Chemistry and Chemical Engineering, Northwest Normal University, 
      Lanzhou 730070, China.
FAU - Du, Tongtong
AU  - Du T
AD  - College of Chemistry and Chemical Engineering, Northwest Normal University, 
      Lanzhou 730070, China.
FAU - Du, Xinzhen
AU  - Du X
AD  - College of Chemistry and Chemical Engineering, Northwest Normal University, 
      Lanzhou 730070, China; Key Laboratory of Bioelectrochemistry & Environmental 
      Analysis of Gansu Province, Lanzhou 730070, China.
FAU - Lu, Xiaoquan
AU  - Lu X
AD  - College of Chemistry and Chemical Engineering, Northwest Normal University, 
      Lanzhou 730070, China; Key Laboratory of Bioelectrochemistry & Environmental 
      Analysis of Gansu Province, Lanzhou 730070, China.
LA  - eng
PT  - Journal Article
DEP - 20180104
PL  - Netherlands
TA  - Talanta
JT  - Talanta
JID - 2984816R
RN  - 0 (Benzene Derivatives)
RN  - 0 (Insecticides)
RN  - 0 (Metal-Organic Frameworks)
RN  - 0 (Oxides)
RN  - 7782-42-5 (Graphite)
RN  - 789U1901C5 (Copper)
SB  - IM
MH  - Benzene Derivatives/chemistry
MH  - Chromatography, High Pressure Liquid
MH  - Copper/*chemistry
MH  - Graphite/*chemistry
MH  - Insecticides/*analysis/chemistry/isolation & purification
MH  - Magnetics
MH  - Metal-Organic Frameworks/*chemistry
MH  - Microscopy, Electron
MH  - Nanocomposites/*chemistry/ultrastructure
MH  - Oxides/*chemistry
MH  - Porosity
MH  - Reproducibility of Results
MH  - Spectroscopy, Fourier Transform Infrared
MH  - X-Ray Diffraction
OTO - NOTNLM
OT  - High performance liquid chromatography
OT  - Insecticides
OT  - Magnetic solid-phase extraction
OT  - Metal-organic frameworks
OT  - Preconcentration
EDAT- 2018/02/11 06:00
MHDA- 2018/09/25 06:00
CRDT- 2018/02/11 06:00
PHST- 2017/11/08 00:00 [received]
PHST- 2017/12/27 00:00 [revised]
PHST- 2018/01/02 00:00 [accepted]
PHST- 2018/02/11 06:00 [entrez]
PHST- 2018/02/11 06:00 [pubmed]
PHST- 2018/09/25 06:00 [medline]
AID - S0039-9140(18)30006-7 [pii]
AID - 10.1016/j.talanta.2018.01.004 [doi]
PST - ppublish
SO  - Talanta. 2018 May 1;181:112-117. doi: 10.1016/j.talanta.2018.01.004. Epub 2018 
      Jan 4.