PMID- 29426515
OWN - NLM
STAT- MEDLINE
DCOM- 20180924
LR  - 20180924
IS  - 1873-3573 (Electronic)
IS  - 0039-9140 (Linking)
VI  - 181
DP  - 2018 May 1
TI  - Preparation of core-shell structured magnetic covalent organic framework 
      nanocomposites for magnetic solid-phase extraction of bisphenols from human serum 
      sample.
PG  - 296-304
LID - S0039-9140(18)30047-X [pii]
LID - 10.1016/j.talanta.2018.01.036 [doi]
AB  - Core-shell structured magnetic covalent organic framework (Fe(3)O(4)@COF) 
      nanocomposites were synthesized via a facile approach at room temperature and 
      explored as an absorbent for magnetic solid-phase extraction (MSPE) of bisphenols 
      (BPs) from human serum sample. The as-prepared Fe(3)O(4)@COF nanocomposites with 
      core-shell structure possessed high specific surface area (181.36m(2)/g), uniform 
      mesoporous size (~ 3.6nm), high saturation magnetization (42.7emu/g), and 
      excellent thermal and chemical stability, rendering it as an ideal adsorbent with 
      high adsorption efficiency and size selectivity. The experimental parameters 
      influencing extraction efficiency, including adsorbent dosage, extraction time, 
      pH and ion strength, desorption solvent and time, were investigated in detail. 
      Taking these advantages together, a simple, fast, effective and sensitive method 
      that MPSE followed by HPLC-MS, was proposed to detect five BPs, which exhibited 
      good linearity (r > 0.9982) within the concentration ranges of 0.1-50mug/L. 
      Moreover, the low detection limits (1.0-78.1ng/L), signal-to-noise ratio (S/N = 
      3), the high enrichment factors (56-95 fold), and good recoveries (93.0-107.8%) 
      with relative standard deviations (RSDs) less than 3.4% for inter-day and 6.9% 
      for intra-day were achieved. The developed method was also successfully applied 
      to the analysis of trace BPs in human serum sample, which demonstrated the most 
      promising potential of the Fe(3)O(4)@COF nanocomposites as good adsorbent in 
      sample pretreatment.
CI  - Copyright (c) 2018 Elsevier B.V. All rights reserved.
FAU - Chen, Lei
AU  - Chen L
AD  - Ministry of Education Key Laboratory of Analytical Science for Food Safety and 
      Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology 
      for Food Safety, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350116, 
      China.
FAU - He, Yanting
AU  - He Y
AD  - Ministry of Education Key Laboratory of Analytical Science for Food Safety and 
      Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology 
      for Food Safety, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350116, 
      China.
FAU - Lei, Zhixian
AU  - Lei Z
AD  - Ministry of Education Key Laboratory of Analytical Science for Food Safety and 
      Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology 
      for Food Safety, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350116, 
      China.
FAU - Gao, Chenling
AU  - Gao C
AD  - Ministry of Education Key Laboratory of Analytical Science for Food Safety and 
      Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology 
      for Food Safety, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350116, 
      China.
FAU - Xie, Qing
AU  - Xie Q
AD  - Fujian Vocational College of Bioengineering, Fuzhou, Fujian 350002, China.
FAU - Tong, Ping
AU  - Tong P
AD  - Ministry of Education Key Laboratory of Analytical Science for Food Safety and 
      Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology 
      for Food Safety, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350116, 
      China.
FAU - Lin, Zian
AU  - Lin Z
AD  - Ministry of Education Key Laboratory of Analytical Science for Food Safety and 
      Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology 
      for Food Safety, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350116, 
      China. Electronic address: zianlin@fzu.edu.cn.
LA  - eng
PT  - Journal Article
DEP - 20180203
PL  - Netherlands
TA  - Talanta
JT  - Talanta
JID - 2984816R
RN  - 0 (Benzhydryl Compounds)
RN  - 0 (Metal-Organic Frameworks)
RN  - 0 (Phenols)
RN  - 0 (Sulfones)
RN  - 0 (bisphenol F)
RN  - 80-09-1 (bis(4-hydroxyphenyl)sulfone)
RN  - MLT3645I99 (bisphenol A)
RN  - OH7IX8A37J (4,4'-hexafluorisopropylidene diphenol)
SB  - IM
MH  - Adsorption
MH  - Benzhydryl Compounds/blood/chemistry/*isolation & purification
MH  - Humans
MH  - Hydrogen-Ion Concentration
MH  - Magnetics
MH  - Metal-Organic Frameworks/*chemistry
MH  - Nanocomposites/*chemistry/ultrastructure
MH  - Phenols/blood/chemistry/*isolation & purification
MH  - Porosity
MH  - Reproducibility of Results
MH  - Solid Phase Extraction/*methods
MH  - Spectroscopy, Fourier Transform Infrared
MH  - Sulfones/blood/chemistry/isolation & purification
MH  - X-Ray Diffraction
OTO - NOTNLM
OT  - Bisphenols
OT  - Human serum
OT  - Liquid chromatography-tandem mass spectrometry
OT  - Magnetic covalent organic frameworks
OT  - Magnetic solid-phase extraction
EDAT- 2018/02/11 06:00
MHDA- 2018/09/25 06:00
CRDT- 2018/02/11 06:00
PHST- 2017/10/19 00:00 [received]
PHST- 2017/12/30 00:00 [revised]
PHST- 2018/01/15 00:00 [accepted]
PHST- 2018/02/11 06:00 [entrez]
PHST- 2018/02/11 06:00 [pubmed]
PHST- 2018/09/25 06:00 [medline]
AID - S0039-9140(18)30047-X [pii]
AID - 10.1016/j.talanta.2018.01.036 [doi]
PST - ppublish
SO  - Talanta. 2018 May 1;181:296-304. doi: 10.1016/j.talanta.2018.01.036. Epub 2018 
      Feb 3.