PMID- 29426545
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20180328
LR  - 20180328
IS  - 1873-3573 (Electronic)
IS  - 0039-9140 (Linking)
VI  - 181
DP  - 2018 May 1
TI  - An electrochemical sensor based on copper-based metal-organic frameworks-graphene 
      composites for determination of dihydroxybenzene isomers in water.
PG  - 80-86
LID - S0039-9140(18)30003-1 [pii]
LID - 10.1016/j.talanta.2018.01.002 [doi]
AB  - A highly and simply sensitive electrochemical sensor was presented for the 
      simultaneous determination of hydroquinone (HQ) and catechol (CT) in the water 
      based on copper centered metal-organic framework-graphene composites (Cu-MOF-GN) 
      [Cu-MOF = Cu(3)(BTC)(2) (BTC = 1, 3, 5-benzenetricarboxylicacid)] modified glassy 
      carbon electrode (Cu-MOF-GN/GCE). The modification procedure was carried out 
      through casting metal-organic framework-graphene oxide composites (Cu-MOF-GO) on 
      the bare glassy carbon electrode and followed by the transformation of Cu-MOF-GO 
      to Cu-MOF-GN by an electrochemical reduction. The electrochemical behavior of HQ 
      and CT at Cu-MOF-GN/GCE was investigated by cyclic voltammetry (CV), differential 
      pulse voltammetry (DPV) and electrochemical impedance spectroscopy (EIS). Under 
      the optimized conditions, the modified electrode had excellent electrocatalytic 
      activity and high selectivity toward HQ and CT. The electrochemical sensor 
      exhibited a linear response in the same range of 1.0 x 10(-6) to 1.0 x 10(-3)M 
      with the detection limits of 5.9 x 10(-7)M for HQ and 3.3 x 10(-7)M for CT (S/N = 
      3). Four samples of tap water spiked with different concentrations of HQ and CT 
      were considered. The method has been applied to the analysis of these isomers in 
      spiked tap water with recoveries from 99.0 ~ 102.9% and relative standard 
      deviations (RSDs) for 5 successive measurements less than 5% were also 
      acceptable. This method was successfully applied to detect target analytes in the 
      real samples with satisfying results. The MOFs-based sensors in the field of 
      electrochemical sensing held a great promise for routine sensing applications.
CI  - Copyright (c) 2018 Elsevier B.V. All rights reserved.
FAU - Li, Jun
AU  - Li J
AD  - College of Chemistry and Chemical Engineering, Shandong Sino-Japanese Center for 
      Collaborative Research of Carbon Nanomaterials, Collaborative Innovation Center 
      for Marine Biomass Fiber Materials and Textiles, Laboratory of Fiber Materials 
      and Modern Textile, the Growing Base for State Key Laboratory, Qingdao 
      University, Qingdao 266071, PR China.
FAU - Xia, Jianfei
AU  - Xia J
AD  - College of Chemistry and Chemical Engineering, Shandong Sino-Japanese Center for 
      Collaborative Research of Carbon Nanomaterials, Collaborative Innovation Center 
      for Marine Biomass Fiber Materials and Textiles, Laboratory of Fiber Materials 
      and Modern Textile, the Growing Base for State Key Laboratory, Qingdao 
      University, Qingdao 266071, PR China. Electronic address: xiajianfei@126.com.
FAU - Zhang, Feifei
AU  - Zhang F
AD  - College of Chemistry and Chemical Engineering, Shandong Sino-Japanese Center for 
      Collaborative Research of Carbon Nanomaterials, Collaborative Innovation Center 
      for Marine Biomass Fiber Materials and Textiles, Laboratory of Fiber Materials 
      and Modern Textile, the Growing Base for State Key Laboratory, Qingdao 
      University, Qingdao 266071, PR China.
FAU - Wang, Zonghua
AU  - Wang Z
AD  - College of Chemistry and Chemical Engineering, Shandong Sino-Japanese Center for 
      Collaborative Research of Carbon Nanomaterials, Collaborative Innovation Center 
      for Marine Biomass Fiber Materials and Textiles, Laboratory of Fiber Materials 
      and Modern Textile, the Growing Base for State Key Laboratory, Qingdao 
      University, Qingdao 266071, PR China. Electronic address: wangzonghua@qdu.edu.cn.
FAU - Liu, Qingyun
AU  - Liu Q
AD  - College of Chemistry and Environmental Engineering, Shandong University of 
      Science and Technology, Qingdao, PR China.
LA  - eng
PT  - Journal Article
DEP - 20180105
PL  - Netherlands
TA  - Talanta
JT  - Talanta
JID - 2984816R
OTO - NOTNLM
OT  - Catechol
OT  - Graphene
OT  - HKUST-1
OT  - Hydroquinone
OT  - Metal-organic framework
EDAT- 2018/02/11 06:00
MHDA- 2018/02/11 06:01
CRDT- 2018/02/11 06:00
PHST- 2017/10/07 00:00 [received]
PHST- 2017/12/24 00:00 [revised]
PHST- 2018/01/02 00:00 [accepted]
PHST- 2018/02/11 06:00 [entrez]
PHST- 2018/02/11 06:00 [pubmed]
PHST- 2018/02/11 06:01 [medline]
AID - S0039-9140(18)30003-1 [pii]
AID - 10.1016/j.talanta.2018.01.002 [doi]
PST - ppublish
SO  - Talanta. 2018 May 1;181:80-86. doi: 10.1016/j.talanta.2018.01.002. Epub 2018 Jan 
      5.