PMID- 29442304
OWN - NLM
STAT- MEDLINE
DCOM- 20181211
LR  - 20181211
IS  - 1614-7499 (Electronic)
IS  - 0944-1344 (Linking)
VI  - 25
IP  - 12
DP  - 2018 Apr
TI  - Effect of calcination temperature on the properties of Ti/SnO(2)-Sb anode and its 
      performance in Ni-EDTA electrochemical degradation.
PG  - 11683-11693
LID - 10.1007/s11356-018-1444-1 [doi]
AB  - Pd-doped Ti/SnO(2)-Sb anode was prepared at different calcination temperatures by 
      a wet-impregnation method and employed in simultaneous electrochemical catalytic 
      degradation of Ni-EDTA and recovery of nickel. The results showed that 
      Ti/SnO(2)-Sb-Pd-500 could achieve the highest electrochemical activity (87.5% of 
      Ni-EDTA removal efficiency), superior durability (50.7 h of accelerated 
      lifetime), and higher Ni recovery (19.8%) on cathode. Cyclic voltammetry (CV) and 
      linear sweep voltammetry (LSV) analysis suggested that Ni-EDTA degradation on 
      anode was mainly indirect oxidation-controlled reaction, attributing to the high 
      oxide state of MO(X + 1) and MO(X)(.OH), rather than direct oxidation. Scanning 
      electron microscope (SEM), X-ray diffraction (XRD), and X-ray photoelectron 
      spectroscopy (XPS) analyses indicated that calcination temperature could modify 
      the morphology of electrode surface and affect the incorporation and valence 
      state transformation of metal species (Sb and Pd) in SnO(2) lattice. 
      Ti/SnO(2)-Sb-Pd-500 achieved the highest electrochemical capacity with the 
      highest levels of adsorbed oxygen O(ads)/E(T) (27.11%) and lattice oxygen 
      O(lat)/E(T) (29.69%). Moreover, the operation conditions for Ni-EDTA 
      electrochemical degradation were optimized. These findings were valuable for 
      developing a high-performance electrode for Ni-EDTA electrochemical degradation.
FAU - Lei, Xin
AU  - Lei X
AD  - Ministry of Education Key Laboratory of Pollution Control and Ecological 
      Remediation for Industrial Agglomeration Area, School of Environment and Energy, 
      South China University of Technology, Guangzhou, 510006, China.
FAU - Li, Lianghao
AU  - Li L
AD  - Ministry of Education Key Laboratory of Pollution Control and Ecological 
      Remediation for Industrial Agglomeration Area, School of Environment and Energy, 
      South China University of Technology, Guangzhou, 510006, China.
FAU - Chen, Yuancai
AU  - Chen Y
AD  - Ministry of Education Key Laboratory of Pollution Control and Ecological 
      Remediation for Industrial Agglomeration Area, School of Environment and Energy, 
      South China University of Technology, Guangzhou, 510006, China. 
      chenyc@scut.edu.cn.
FAU - Hu, Yongyou
AU  - Hu Y
AD  - Ministry of Education Key Laboratory of Pollution Control and Ecological 
      Remediation for Industrial Agglomeration Area, School of Environment and Energy, 
      South China University of Technology, Guangzhou, 510006, China.
LA  - eng
GR  - 21677052/National Nature Science Foundation of China/
GR  - 201704020206/Major Science and Technology Program for the 
      Industry-Academia-Research Collaborative Innovation/
GR  - 2017-25/Guangdong Water Conservancy Science and Technology Innovation Project/
GR  - 2016B090918104, 2016B020240005, 2017A020216013/Guangdong Province Science and 
      Technology Project/
GR  - U1401235/Joint fund of Guangdong Province/
PT  - Journal Article
DEP - 20180213
PL  - Germany
TA  - Environ Sci Pollut Res Int
JT  - Environmental science and pollution research international
JID - 9441769
RN  - 0 (Tin Compounds)
RN  - 7OV03QG267 (Nickel)
RN  - 9G34HU7RV0 (Edetic Acid)
RN  - D1JT611TNE (Titanium)
RN  - KM7N50LOS6 (stannic oxide)
SB  - IM
MH  - Catalysis
MH  - Edetic Acid/chemistry/*isolation & purification
MH  - *Electrodes
MH  - Environmental Restoration and Remediation/*methods
MH  - Hot Temperature
MH  - Nickel/chemistry/*isolation & purification
MH  - Oxidation-Reduction
MH  - Tin Compounds/*chemistry
MH  - Titanium/*chemistry
OTO - NOTNLM
OT  - Calcination temperature
OT  - Electrochemical oxidation
OT  - Ni-EDTA
OT  - Ti/SnO2-Sb-Pd anode
EDAT- 2018/02/15 06:00
MHDA- 2018/12/12 06:00
CRDT- 2018/02/15 06:00
PHST- 2017/11/16 00:00 [received]
PHST- 2018/01/30 00:00 [accepted]
PHST- 2018/02/15 06:00 [pubmed]
PHST- 2018/12/12 06:00 [medline]
PHST- 2018/02/15 06:00 [entrez]
AID - 10.1007/s11356-018-1444-1 [pii]
AID - 10.1007/s11356-018-1444-1 [doi]
PST - ppublish
SO  - Environ Sci Pollut Res Int. 2018 Apr;25(12):11683-11693. doi: 
      10.1007/s11356-018-1444-1. Epub 2018 Feb 13.