PMID- 29525562 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20180424 LR - 20180424 IS - 1873-3557 (Electronic) IS - 1386-1425 (Linking) VI - 198 DP - 2018 Jun 5 TI - A hierarchical classification approach for recognition of low-density (LDPE) and high-density polyethylene (HDPE) in mixed plastic waste based on short-wave infrared (SWIR) hyperspectral imaging. PG - 115-122 LID - S1386-1425(18)30197-5 [pii] LID - 10.1016/j.saa.2018.03.006 [doi] AB - The aim of this work was to recognize different polymer flakes from mixed plastic waste through an innovative hierarchical classification strategy based on hyperspectral imaging, with particular reference to low density polyethylene (LDPE) and high-density polyethylene (HDPE). A plastic waste composition assessment, including also LDPE and HDPE identification, may help to define optimal recycling strategies for product quality control. Correct handling of plastic waste is essential for its further "sustainable" recovery, maximizing the sorting performance in particular for plastics with similar characteristics as LDPE and HDPE. Five different plastic waste samples were chosen for the investigation: polypropylene (PP), LDPE, HDPE, polystyrene (PS) and polyvinyl chloride (PVC). A calibration dataset was realized utilizing the corresponding virgin polymers. Hyperspectral imaging in the short-wave infrared range (1000-2500nm) was thus applied to evaluate the different plastic spectral attributes finalized to perform their recognition/classification. After exploring polymer spectral differences by principal component analysis (PCA), a hierarchical partial least squares discriminant analysis (PLS-DA) model was built allowing the five different polymers to be recognized. The proposed methodology, based on hierarchical classification, is very powerful and fast, allowing to recognize the five different polymers in a single step. CI - Copyright (c) 2018 Elsevier B.V. All rights reserved. FAU - Bonifazi, Giuseppe AU - Bonifazi G AD - Department of Chemical Engineering Materials & Environment (DICMA), Sapienza University of Rome, Rome, Italy. FAU - Capobianco, Giuseppe AU - Capobianco G AD - Department of Chemical Engineering Materials & Environment (DICMA), Sapienza University of Rome, Rome, Italy. FAU - Serranti, Silvia AU - Serranti S AD - Department of Chemical Engineering Materials & Environment (DICMA), Sapienza University of Rome, Rome, Italy. Electronic address: silvia.serranti@uniroma1.it. LA - eng PT - Journal Article DEP - 20180303 PL - England TA - Spectrochim Acta A Mol Biomol Spectrosc JT - Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy JID - 9602533 OTO - NOTNLM OT - Hierarchical PLS-DA OT - High density polyethylene (HDPE) OT - Hyperspectral imaging OT - Low density polyethylene (LDPE) OT - Plastic waste OT - Polymers OT - Recycling EDAT- 2018/03/12 06:00 MHDA- 2018/03/12 06:01 CRDT- 2018/03/12 06:00 PHST- 2017/09/08 00:00 [received] PHST- 2018/02/18 00:00 [revised] PHST- 2018/03/02 00:00 [accepted] PHST- 2018/03/12 06:00 [pubmed] PHST- 2018/03/12 06:01 [medline] PHST- 2018/03/12 06:00 [entrez] AID - S1386-1425(18)30197-5 [pii] AID - 10.1016/j.saa.2018.03.006 [doi] PST - ppublish SO - Spectrochim Acta A Mol Biomol Spectrosc. 2018 Jun 5;198:115-122. doi: 10.1016/j.saa.2018.03.006. Epub 2018 Mar 3.