PMID- 29550435
OWN - NLM
STAT- MEDLINE
DCOM- 20180808
LR  - 20181202
IS  - 1090-2414 (Electronic)
IS  - 0147-6513 (Linking)
VI  - 156
DP  - 2018 Jul 30
TI  - The implications of water extractable organic matter (WEOM) on the sorption of 
      typical parent, alkyl and N/O/S-containing polycyclic aromatic hydrocarbons 
      (PAHs) by microplastics.
PG  - 176-182
LID - S0147-6513(18)30205-7 [pii]
LID - 10.1016/j.ecoenv.2018.03.021 [doi]
AB  - Microplastics sorption of persistent organic pollutants (POPs) was the core 
      processes that cause negative effects to biota, and their influencing factors and 
      related mechanisms are poorly understood. In this study, we explored the impacts 
      of water extractable organic matter (WEOM), an important source of endogenous 
      dissolved organic matter in mangrove sediment, on the sorption coefficients of 
      typical parent, alkyl and N/O/S-containing polycyclic aromatic hydrocarbons 
      (PAHs) by microplastics. The presence of L-WEOM (D) impeded the PAHs sorption as 
      the coefficients (K(f)) decreased to 10.17 (mug/kg)/(mug/L)(n) and to 
      8.39 (mug/kg)/(mug/L)(n) for fluorene (Flu) and 1-methyl-fluorene (1-M-Flu), 
      respectively. The K(f) exhibited good linear relationships with the aliphaticity 
      of L-WEOM (p < 0.05) rather than the aromatic carbon/alkyl carbon content 
      (p > 0.05). Under the presences of L-WEOM (D), (S) and (K), the lone pair 
      electrons of N/O/S-containing PAHs was the dominant factor contributing to the 
      obvious difference of the K(f) values from the other groups. Moreover, the 
      largest impact of L-WEOM (D) on the Flu sorption was in the case of PVC 
      microplastics, while almost no effect was in the case of PS microplastics. The 
      findings of our work may be helpful in improving our understanding of the role of 
      WEOM on the sorption of PAHs to microplastics in the field mangrove sediment.
CI  - Copyright (c) 2018 Elsevier Inc. All rights reserved.
FAU - Li, Ruilong
AU  - Li R
AD  - School of Marine Sciences, Guangxi University, Nanning 530004, PR China; Coral 
      Reef Research Center of China, Guangxi University, Nanning 530004, PR China; 
      Guangxi Laboratory on the Study of Coral Reefs in the South China Sea, Guangxi 
      University, Nanning 530004, PR China.
FAU - Tan, Huadong
AU  - Tan H
AD  - Environment and Plant Protection Institute, Chinese Academy of Tropical 
      Agricultural Sciences, Haikou 361102, PR China; Danzhou Scientific Observing and 
      Experimental Station of Agro-Environment, Ministry of Agriculture, Danzhou 
      571737, PR China.
FAU - Zhang, Linlin
AU  - Zhang L
AD  - School of Marine Sciences, Guangxi University, Nanning 530004, PR China; Coral 
      Reef Research Center of China, Guangxi University, Nanning 530004, PR China; 
      Guangxi Laboratory on the Study of Coral Reefs in the South China Sea, Guangxi 
      University, Nanning 530004, PR China.
FAU - Wang, Shaopeng
AU  - Wang S
AD  - School of Marine Sciences, Guangxi University, Nanning 530004, PR China; Coral 
      Reef Research Center of China, Guangxi University, Nanning 530004, PR China; 
      Guangxi Laboratory on the Study of Coral Reefs in the South China Sea, Guangxi 
      University, Nanning 530004, PR China.
FAU - Wang, Yinghui
AU  - Wang Y
AD  - School of Marine Sciences, Guangxi University, Nanning 530004, PR China; Coral 
      Reef Research Center of China, Guangxi University, Nanning 530004, PR China; 
      Guangxi Laboratory on the Study of Coral Reefs in the South China Sea, Guangxi 
      University, Nanning 530004, PR China. Electronic address: wyh@gxu.edu.cn.
FAU - Yu, Kefu
AU  - Yu K
AD  - School of Marine Sciences, Guangxi University, Nanning 530004, PR China; Coral 
      Reef Research Center of China, Guangxi University, Nanning 530004, PR China; 
      Guangxi Laboratory on the Study of Coral Reefs in the South China Sea, Guangxi 
      University, Nanning 530004, PR China. Electronic address: kefuyu@scsio.ac.cn.
LA  - eng
PT  - Journal Article
DEP - 20180320
PL  - Netherlands
TA  - Ecotoxicol Environ Saf
JT  - Ecotoxicology and environmental safety
JID - 7805381
RN  - 0 (Plastics)
RN  - 0 (Polycyclic Aromatic Hydrocarbons)
RN  - 0 (Water Pollutants, Chemical)
RN  - 059QF0KO0R (Water)
SB  - IM
MH  - Adsorption
MH  - Geologic Sediments/*chemistry
MH  - Plastics/*chemistry
MH  - Polycyclic Aromatic Hydrocarbons/analysis/*chemistry
MH  - Water/chemistry
MH  - Water Pollutants, Chemical/analysis/*chemistry
MH  - Water Pollution
MH  - Wetlands
OTO - NOTNLM
OT  - Mangrove sediment
OT  - Microplastics
OT  - Polycyclic aromatic hydrocarbons
OT  - WEOM/L-WEOM
EDAT- 2018/03/20 06:00
MHDA- 2018/08/09 06:00
CRDT- 2018/03/19 06:00
PHST- 2017/12/29 00:00 [received]
PHST- 2018/02/28 00:00 [revised]
PHST- 2018/03/06 00:00 [accepted]
PHST- 2018/03/20 06:00 [pubmed]
PHST- 2018/08/09 06:00 [medline]
PHST- 2018/03/19 06:00 [entrez]
AID - S0147-6513(18)30205-7 [pii]
AID - 10.1016/j.ecoenv.2018.03.021 [doi]
PST - ppublish
SO  - Ecotoxicol Environ Saf. 2018 Jul 30;156:176-182. doi: 
      10.1016/j.ecoenv.2018.03.021. Epub 2018 Mar 20.