PMID- 29571502
OWN - NLM
STAT- MEDLINE
DCOM- 20180924
LR  - 20190318
IS  - 1873-7072 (Electronic)
IS  - 0308-8146 (Linking)
VI  - 255
DP  - 2018 Jul 30
TI  - Application of magnetic molecularly imprinted polymers for extraction of 
      imidacloprid from eggplant and honey.
PG  - 81-88
LID - S0308-8146(18)30297-8 [pii]
LID - 10.1016/j.foodchem.2018.02.061 [doi]
AB  - A magnetic molecularly imprinted polymer (MMIP) adsorbent for imidacloprid was 
      prepared using non-covalent approach with functionalized nano Fe(3)O(4) particles 
      (magnetic cores), imidacloprid (template), acrylic acid (functional monomer), 
      ethylene glycol dimethacrylate (cross linker) and azobisisobutyronitrile 
      (initiator) and used for selective separation of imidacloprid from honey and 
      vegetable samples. The polymers were characterized using FT-IR spectroscopy, SEM 
      and TEM images. For analysis of imidacloprid LC-MS/MS equipment was used. 
      Adsorption kinetics was best explained by pseudo-second-order kinetic model. 
      Adsorption data fitted well into linearized Freundlich equation (R(2) > 0.98). 
      Scatchard plot analysis indicates the presence of two classes of binding sites in 
      the MMIPs with the C(max) of 1889.6 microg g(-1) and 65448.9 microg g(-1), respectively. 
      MMIPs demonstrated much higher affinity for imidacloprid over structurally 
      similar analogues acetamiprid (alpha = 23.59) and thiamethoxam (alpha = 17.15). About 
      87.1 +/- 5.0% and 90.6 +/- 5.6% of the added imidacloprid was recovered from MMIPs in 
      case of fortified eggplant and honey samples, respectively.
CI  - Copyright (c) 2018 Elsevier Ltd. All rights reserved.
FAU - Kumar, Niranjan
AU  - Kumar N
AD  - Division of Agricultural Chemicals, ICAR-Indian Agricultural Research Institute, 
      New Delhi 110012, India.
FAU - Narayanan, Neethu
AU  - Narayanan N
AD  - Division of Agricultural Chemicals, ICAR-Indian Agricultural Research Institute, 
      New Delhi 110012, India.
FAU - Gupta, Suman
AU  - Gupta S
AD  - Division of Agricultural Chemicals, ICAR-Indian Agricultural Research Institute, 
      New Delhi 110012, India. Electronic address: drsumangupta2002@yahoo.com.
LA  - eng
PT  - Journal Article
DEP - 20180212
PL  - England
TA  - Food Chem
JT  - Food chemistry
JID - 7702639
RN  - 0 (Methacrylates)
RN  - 0 (Neonicotinoids)
RN  - 0 (Nitriles)
RN  - 0 (Nitro Compounds)
RN  - 0 (Oxazines)
RN  - 0 (Polymers)
RN  - 0 (Thiazoles)
RN  - 3BN7M937V8 (imidacloprid)
RN  - 747IC8B487 (Thiamethoxam)
RN  - 7BK5G69305 (ethylene dimethacrylate)
RN  - FZ6PX8U5YB (azobis(isobutyronitrile))
SB  - IM
MH  - Adsorption
MH  - Food Contamination/analysis
MH  - *Honey
MH  - Magnetics
MH  - Methacrylates/chemistry
MH  - Microscopy, Electron, Scanning
MH  - Microscopy, Electron, Transmission
MH  - Molecular Imprinting/*methods
MH  - Neonicotinoids/*isolation & purification
MH  - Nitriles/chemistry
MH  - Nitro Compounds/*isolation & purification
MH  - Oxazines/isolation & purification
MH  - Polymers/chemical synthesis/*chemistry
MH  - Solanum melongena/*chemistry
MH  - Solid Phase Extraction/instrumentation/methods
MH  - Spectroscopy, Fourier Transform Infrared
MH  - Tandem Mass Spectrometry
MH  - Thiamethoxam
MH  - Thiazoles/isolation & purification
OTO - NOTNLM
OT  - Eggplant
OT  - Honey
OT  - Imidacloprid
OT  - Liquid chromatography mass spectrometry (LC-MS/MS)
OT  - Magnetic molecularly imprinted polymer (MMIP)
EDAT- 2018/03/25 06:00
MHDA- 2018/09/25 06:00
CRDT- 2018/03/25 06:00
PHST- 2017/09/20 00:00 [received]
PHST- 2018/01/18 00:00 [revised]
PHST- 2018/02/11 00:00 [accepted]
PHST- 2018/03/25 06:00 [entrez]
PHST- 2018/03/25 06:00 [pubmed]
PHST- 2018/09/25 06:00 [medline]
AID - S0308-8146(18)30297-8 [pii]
AID - 10.1016/j.foodchem.2018.02.061 [doi]
PST - ppublish
SO  - Food Chem. 2018 Jul 30;255:81-88. doi: 10.1016/j.foodchem.2018.02.061. Epub 2018 
      Feb 12.