PMID- 29621643
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20180607
LR  - 20180607
IS  - 1095-7103 (Electronic)
IS  - 0021-9797 (Linking)
VI  - 523
DP  - 2018 Aug 1
TI  - Potential-induced reversible uptake/release of perchlorate from wastewater by 
      polypyrrole@CoNi-layered double hydroxide modified electrode with proton-ligand 
      effect.
PG  - 159-168
LID - S0021-9797(18)30354-0 [pii]
LID - 10.1016/j.jcis.2018.03.098 [doi]
AB  - In this study, CoNi-layered double hydroxide (CoNi-LDH) nanosheets coated 
      conducting polypyrrole (PPy) nanowire was controllably fabricated on Pt plate or 
      carbon cloth by using unipolar pulse electrodeposition (UPED) method and served 
      as a novel electrochemically switched ion exchange (ESIX) hybrid film with 
      proton-ligand effect for the removal of perchlorate anions (ClO(4)(-)). It is 
      expected that the space among CoNi-LDH nanosheets of the shell could act as the 
      reservoir for the anions while the PPy core serve as the potential-induced 
      element for proton-ligand. The effects of pulse potential during film deposition 
      and initial pH of the wastewater on the ClO(4)(-) removal performance of this 
      core-shell hybrid film were investigated. It is found that ClO(4)(-) adsorption 
      onto PPy@CoNi-LDH followed pseudo-second-order model, and the film fabricated 
      with -1.5 V pulse potential showed an excellent performance for the rapid removal 
      of ClO(4)(-) with a high selectivity, and the ClO(4)(-) adsorption quantity 
      reached as high as 302 mg g(-)(1). In a wide pH range (3-10), the hybrid film 
      removed ClO(4)(-) efficiently. The proton-ligand effect in PPy@CoNi-LDH was 
      proved by using XPS analysis and density functional theory. Such a PPy@CoNi-LDH 
      hybrid core-shell film should be a potential electroactive material for the 
      separation of ClO(4)(-) and other anions from wastewater.
CI  - Copyright (c) 2018 Elsevier Inc. All rights reserved.
FAU - Yang, Yanyan
AU  - Yang Y
AD  - Department of Chemical Engineering, Taiyuan University of Technology, Taiyuan 
      030024, China.
FAU - Du, Xiao
AU  - Du X
AD  - Department of Chemical Engineering, Taiyuan University of Technology, Taiyuan 
      030024, China.
FAU - An, Xiaowei
AU  - An X
AD  - Department of Chemical Engineering, Taiyuan University of Technology, Taiyuan 
      030024, China.
FAU - Ding, Shengqi
AU  - Ding S
AD  - Department of Chemical Engineering, Taiyuan University of Technology, Taiyuan 
      030024, China.
FAU - Liu, Feifan
AU  - Liu F
AD  - Department of Chemical Engineering, Taiyuan University of Technology, Taiyuan 
      030024, China.
FAU - Zhang, Zhonglin
AU  - Zhang Z
AD  - Department of Chemical Engineering, Taiyuan University of Technology, Taiyuan 
      030024, China.
FAU - Ma, Xuli
AU  - Ma X
AD  - Department of Chemical Engineering, Taiyuan University of Technology, Taiyuan 
      030024, China.
FAU - Hao, Xiaogang
AU  - Hao X
AD  - Department of Chemical Engineering, Taiyuan University of Technology, Taiyuan 
      030024, China. Electronic address: xghao@tyut.edu.cn.
FAU - Guan, Guoqing
AU  - Guan G
AD  - North Japan Research Institute for Sustainable Energy (NJRISE), Hirosaki 
      University, 2-1-3, Matsubara, Aomori 030-0813, Japan. Electronic address: 
      guan@hirosaki-u.ac.jp.
FAU - Zhang, Hui
AU  - Zhang H
AD  - Department of Chemical and Biochemical Engineering, The University of Western 
      Ontario, London, Ontario N6A 5B8, Canada.
LA  - eng
PT  - Journal Article
DEP - 20180329
PL  - United States
TA  - J Colloid Interface Sci
JT  - Journal of colloid and interface science
JID - 0043125
OTO - NOTNLM
OT  - Anions removal
OT  - Core-shell nanostructures
OT  - Electrochemically switched ion exchange
OT  - Polypyrrole@CoNi-layered double hydroxide
OT  - Potential-induced
OT  - Proton-ligand effect
EDAT- 2018/04/06 06:00
MHDA- 2018/04/06 06:01
CRDT- 2018/04/06 06:00
PHST- 2018/01/18 00:00 [received]
PHST- 2018/03/26 00:00 [revised]
PHST- 2018/03/28 00:00 [accepted]
PHST- 2018/04/06 06:00 [pubmed]
PHST- 2018/04/06 06:01 [medline]
PHST- 2018/04/06 06:00 [entrez]
AID - S0021-9797(18)30354-0 [pii]
AID - 10.1016/j.jcis.2018.03.098 [doi]
PST - ppublish
SO  - J Colloid Interface Sci. 2018 Aug 1;523:159-168. doi: 10.1016/j.jcis.2018.03.098. 
      Epub 2018 Mar 29.