PMID- 29648800 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20191120 IS - 1936-086X (Electronic) IS - 1936-0851 (Linking) VI - 12 IP - 5 DP - 2018 May 22 TI - Highly Self-Healable 3D Microsupercapacitor with MXene-Graphene Composite Aerogel. PG - 4224-4232 LID - 10.1021/acsnano.7b07528 [doi] AB - High-performance microsupercapacitors (MSCs) with three-dimensional (3D) structure provide an effective approach to improve the ability of energy storage. Because the electrodes with 3D structure are generally easily destroyed under mechanical deformation in practical applications, we fabricated a self-healable 3D MSC consisting of MXene (Ti(3)C(2)T (x))-graphene (reduced graphene oxide, rGO) composite aerogel electrode by wrapping it with a self-healing polyurethane as an outer shell. The MXene-rGO composite aerogel combining large specific surface area of rGO and high conductivity of the MXene can not only prevent the self-restacking of the lamella structure but also resist the poor oxidization of MXene to a degree. The MSC based on a 3D MXene-rGO aerogel delivers a large area specific capacitance of 34.6 mF cm(-2) at a scan rate of 1 mV s(-1) and an outstanding cycling performance with a capacitance retention up to 91% over 15 000 cycles. The 3D MSC presents an excellent self-healing ability with specific capacitance retention of 81.7% after the fifth healing. The preparation of this self-healable 3D MSC can provide a method for designing and manufacturing next-generation long-life multifunctional electronic devices further to meet the requirements of sustainable development. FAU - Yue, Yang AU - Yue Y AD - Center for Nanoscale Characterization & Devices (CNCD), School of Physics and Wuhan National Laboratory for Optoelectronics (WNLO) , Huazhong University of Science and Technology (HUST) , Luoyu Road 1037 , Wuhan 430074 , P.R. China. FAU - Liu, Nishuang AU - Liu N AUID- ORCID: 0000-0002-2507-7229 AD - Center for Nanoscale Characterization & Devices (CNCD), School of Physics and Wuhan National Laboratory for Optoelectronics (WNLO) , Huazhong University of Science and Technology (HUST) , Luoyu Road 1037 , Wuhan 430074 , P.R. China. FAU - Ma, Yanan AU - Ma Y AD - Center for Nanoscale Characterization & Devices (CNCD), School of Physics and Wuhan National Laboratory for Optoelectronics (WNLO) , Huazhong University of Science and Technology (HUST) , Luoyu Road 1037 , Wuhan 430074 , P.R. China. FAU - Wang, Siliang AU - Wang S AD - Center for Nanoscale Characterization & Devices (CNCD), School of Physics and Wuhan National Laboratory for Optoelectronics (WNLO) , Huazhong University of Science and Technology (HUST) , Luoyu Road 1037 , Wuhan 430074 , P.R. China. FAU - Liu, Weijie AU - Liu W AD - Center for Nanoscale Characterization & Devices (CNCD), School of Physics and Wuhan National Laboratory for Optoelectronics (WNLO) , Huazhong University of Science and Technology (HUST) , Luoyu Road 1037 , Wuhan 430074 , P.R. China. FAU - Luo, Cheng AU - Luo C AD - Center for Nanoscale Characterization & Devices (CNCD), School of Physics and Wuhan National Laboratory for Optoelectronics (WNLO) , Huazhong University of Science and Technology (HUST) , Luoyu Road 1037 , Wuhan 430074 , P.R. China. FAU - Zhang, Hang AU - Zhang H AD - Center for Nanoscale Characterization & Devices (CNCD), School of Physics and Wuhan National Laboratory for Optoelectronics (WNLO) , Huazhong University of Science and Technology (HUST) , Luoyu Road 1037 , Wuhan 430074 , P.R. China. FAU - Cheng, Feng AU - Cheng F AD - Center for Nanoscale Characterization & Devices (CNCD), School of Physics and Wuhan National Laboratory for Optoelectronics (WNLO) , Huazhong University of Science and Technology (HUST) , Luoyu Road 1037 , Wuhan 430074 , P.R. China. FAU - Rao, Jiangyu AU - Rao J AD - Center for Nanoscale Characterization & Devices (CNCD), School of Physics and Wuhan National Laboratory for Optoelectronics (WNLO) , Huazhong University of Science and Technology (HUST) , Luoyu Road 1037 , Wuhan 430074 , P.R. China. FAU - Hu, Xiaokang AU - Hu X AD - Center for Nanoscale Characterization & Devices (CNCD), School of Physics and Wuhan National Laboratory for Optoelectronics (WNLO) , Huazhong University of Science and Technology (HUST) , Luoyu Road 1037 , Wuhan 430074 , P.R. China. FAU - Su, Jun AU - Su J AD - Center for Nanoscale Characterization & Devices (CNCD), School of Physics and Wuhan National Laboratory for Optoelectronics (WNLO) , Huazhong University of Science and Technology (HUST) , Luoyu Road 1037 , Wuhan 430074 , P.R. China. FAU - Gao, Yihua AU - Gao Y AUID- ORCID: 0000-0003-1905-9531 AD - Center for Nanoscale Characterization & Devices (CNCD), School of Physics and Wuhan National Laboratory for Optoelectronics (WNLO) , Huazhong University of Science and Technology (HUST) , Luoyu Road 1037 , Wuhan 430074 , P.R. China. LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20180418 PL - United States TA - ACS Nano JT - ACS nano JID - 101313589 OTO - NOTNLM OT - MXene OT - aerogel OT - microsupercapacitor OT - self-healable OT - three-dimensional EDAT- 2018/04/13 06:00 MHDA- 2018/04/13 06:01 CRDT- 2018/04/13 06:00 PHST- 2018/04/13 06:00 [pubmed] PHST- 2018/04/13 06:01 [medline] PHST- 2018/04/13 06:00 [entrez] AID - 10.1021/acsnano.7b07528 [doi] PST - ppublish SO - ACS Nano. 2018 May 22;12(5):4224-4232. doi: 10.1021/acsnano.7b07528. Epub 2018 Apr 18.