PMID- 29705902 OWN - NLM STAT- MEDLINE DCOM- 20190422 LR - 20190422 IS - 1614-7499 (Electronic) IS - 0944-1344 (Linking) VI - 25 IP - 17 DP - 2018 Jun TI - Source characterization and risk of exposure to atmospheric polychlorinated biphenyls (PCBs) in Ghana. PG - 16316-16324 LID - 10.1007/s11356-018-2090-3 [doi] AB - With recent evidence that persistent organic pollutants (POPs) such as polychlorinated biphenyls (PCBs) are emerging in environmental media in some developing countries that otherwise have sparing production and usage history, it has become important to identify such contemporary source factors of PCBs and the risks this may pose, in line with the global consensus on POP management and elimination. The present study investigated contaminations from atmospheric PCBs in Ghana, deciphered source factors, and accessed risk of exposure to dioxin-like PCBs (DL-PCBs). Atmospheric PCBs were monitored by deployment of PUF-disk passive air samplers (PAS) at several sites across Ghana for 56 days. Atmospheric summation operator(190)PCB concentration in Ghana ranged from 0.28 ng/m(3) in Kumasi to 4.64 ng/m(3) at Agbogbloshie, a suburb in Accra noted for informal electronic waste (e-waste) recycling activities. As high as 11.10 ng/m(3) of PCB concentration was measured in plumes from uncontrolled open burning of e-wastes at Agbogbloshie. Applying statistical source characterization tools, it emerged that e-wastes were a major contributor to the environmental burden of atmospheric PCBs in Ghana. The risk of DL-PCB toxicity via inhalation in the Agbogbloshie area was 4.2 pg TEQ/day, within similar order of magnitude of an estimated risk of 3.85 pg TEQ/day faced by e-waste workers working averagely for 8 h per day. It is suggested that elimination of e-waste sites would help to significantly reduce PCB-related toxicity issues in Ghana. Graphical abstract ᅟ. FAU - Hogarh, Jonathan N AU - Hogarh JN AD - Department of Environmental Science, College of Science, Kwame Nkrumah University of Science and Technology, Kumasi, Ghana. jhogarh@gmail.com. AD - Faculty of Environment and Information Sciences, Yokohama National University, 79-7 Tokiwadai, Hodogaya-ku, Yokohama, Kanagawa, 240-8501, Japan. jhogarh@gmail.com. FAU - Seike, Nobuyasu AU - Seike N AD - Division of Hazardous Chemicals, Institute for Agro-Environmental Sciences, National Agriculture and Food Research Organization (NARO), Tsukuba, Ibaraki, 305-8604, Japan. FAU - Kobara, Yuso AU - Kobara Y AD - Division of Hazardous Chemicals, Institute for Agro-Environmental Sciences, National Agriculture and Food Research Organization (NARO), Tsukuba, Ibaraki, 305-8604, Japan. FAU - Carboo, Derick AU - Carboo D AD - Department of Chemistry, University of Ghana, P.O. Box 56, Legon, Ghana. FAU - Fobil, Julius N AU - Fobil JN AD - Department of Biological, Environmental & Occupational Health Sciences, School of Public Health, University of Ghana, Legon, Ghana. FAU - Masunaga, Shigeki AU - Masunaga S AD - Faculty of Environment and Information Sciences, Yokohama National University, 79-7 Tokiwadai, Hodogaya-ku, Yokohama, Kanagawa, 240-8501, Japan. LA - eng PT - Journal Article DEP - 20180429 PL - Germany TA - Environ Sci Pollut Res Int JT - Environmental science and pollution research international JID - 9441769 RN - 0 (Dioxins) RN - 0 (Environmental Pollutants) RN - DFC2HB4I0K (Polychlorinated Biphenyls) SB - IM MH - Dioxins/*analysis/chemistry MH - Environmental Pollutants MH - Ghana MH - Humans MH - Polychlorinated Biphenyls/*analysis/chemistry MH - Recycling MH - Risk OTO - NOTNLM OT - Agbogbloshie OT - Dioxin-like toxicity OT - E-wastes OT - Persistent organic pollutants OT - Polychlorinated biphenyls EDAT- 2018/05/01 06:00 MHDA- 2019/04/23 06:00 CRDT- 2018/04/30 06:00 PHST- 2017/12/05 00:00 [received] PHST- 2018/04/20 00:00 [accepted] PHST- 2018/05/01 06:00 [pubmed] PHST- 2019/04/23 06:00 [medline] PHST- 2018/04/30 06:00 [entrez] AID - 10.1007/s11356-018-2090-3 [pii] AID - 10.1007/s11356-018-2090-3 [doi] PST - ppublish SO - Environ Sci Pollut Res Int. 2018 Jun;25(17):16316-16324. doi: 10.1007/s11356-018-2090-3. Epub 2018 Apr 29.