PMID- 29732887
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20180730
LR  - 20180730
IS  - 1944-8252 (Electronic)
IS  - 1944-8244 (Linking)
VI  - 10
IP  - 21
DP  - 2018 May 30
TI  - Construction of Bimetallic ZIF-Derived Co-Ni LDHs on the Surfaces of GO or CNTs 
      with a Recyclable Method: Toward Reduced Toxicity of Gaseous Thermal 
      Decomposition Products of Unsaturated Polyester Resin.
PG  - 18359-18371
LID - 10.1021/acsami.8b04340 [doi]
AB  - This work proposed an idea of recycling in preparing Co-Ni layered double 
      hydroxide (LDH)-derived flame retardants. A novel and feasible method was 
      developed to synthesize CO-Ni LDH-decorated graphene oxide (GO) and carbon 
      nanotubes (CNTs), by sacrificing bimetal zeolitic imidazolate frameworks (ZIFs). 
      Organic ligands that departed from ZIFs were recyclable and can be reused to 
      synthesize ZIFs. ZIFs, as transitional objects, in situ synthesized on the 
      surfaces of GO or CNTs directly suppressed the re-stacking of the carbides and 
      facilitated the preparation of GO@LDHs and CNTs@LDHs. As-prepared hybrids 
      catalytically reduced toxic CO yield during the thermal decomposition of 
      unsaturated polyester resin (UPR). What is more, the release behaviors of 
      aromatic compounds were also suppressed during the pyrolysis process of UPR 
      composites. The addition of GO@LDHs and CNTs@LDHs obviously inhibited the heat 
      release and smoke emission behaviors of the UPR matrix during combustion. 
      Mechanical properties of the UPR matrix also improved by inclusion of the 
      carbides derivatives. This work paved a feasible method to prepare well-dispersed 
      carbides@Co-Ni LDH nanocomposites with a more environmentally friendly method.
FAU - Hou, Yanbei
AU  - Hou Y
AD  - State Key Laboratory of Fire Science , University of Science and Technology of 
      China , Hefei , Anhui 230026 , PR China.
FAU - Qiu, Shuilai
AU  - Qiu S
AD  - State Key Laboratory of Fire Science , University of Science and Technology of 
      China , Hefei , Anhui 230026 , PR China.
FAU - Hu, Yuan
AU  - Hu Y
AUID- ORCID: 0000-0003-0753-5430
AD  - State Key Laboratory of Fire Science , University of Science and Technology of 
      China , Hefei , Anhui 230026 , PR China.
FAU - Kundu, Chanchal Kumar
AU  - Kundu CK
AD  - State Key Laboratory of Fire Science , University of Science and Technology of 
      China , Hefei , Anhui 230026 , PR China.
FAU - Gui, Zhou
AU  - Gui Z
AD  - State Key Laboratory of Fire Science , University of Science and Technology of 
      China , Hefei , Anhui 230026 , PR China.
FAU - Hu, Weizhao
AU  - Hu W
AUID- ORCID: 0000-0002-3896-4775
AD  - State Key Laboratory of Fire Science , University of Science and Technology of 
      China , Hefei , Anhui 230026 , PR China.
LA  - eng
PT  - Journal Article
DEP - 20180516
PL  - United States
TA  - ACS Appl Mater Interfaces
JT  - ACS applied materials & interfaces
JID - 101504991
OTO - NOTNLM
OT  - Co-Ni layered double hydroxides
OT  - gaseous toxicity
OT  - graphene and carbon nanotubes
OT  - metal-organic frameworks
OT  - unsaturated polyester resin
EDAT- 2018/05/08 06:00
MHDA- 2018/05/08 06:01
CRDT- 2018/05/08 06:00
PHST- 2018/05/08 06:00 [pubmed]
PHST- 2018/05/08 06:01 [medline]
PHST- 2018/05/08 06:00 [entrez]
AID - 10.1021/acsami.8b04340 [doi]
PST - ppublish
SO  - ACS Appl Mater Interfaces. 2018 May 30;10(21):18359-18371. doi: 
      10.1021/acsami.8b04340. Epub 2018 May 16.