PMID- 29735280
OWN - NLM
STAT- MEDLINE
DCOM- 20180618
LR  - 20181202
IS  - 1873-3778 (Electronic)
IS  - 0021-9673 (Linking)
VI  - 1556
DP  - 2018 Jun 29
TI  - Hyper-crosslinked polymer nanoparticles as the solid-phase microextraction fiber 
      coating for the extraction of organochlorines.
PG  - 47-54
LID - S0021-9673(18)30546-6 [pii]
LID - 10.1016/j.chroma.2018.05.001 [doi]
AB  - A hyper-crosslinked polymer benzenedimethanol (HCP-BDM) was synthesized and 
      explored as a solid-phase microextraction (SPME) fiber coating material. To 
      prepare the HCP-BDM, 1,4-benzenedimethanol monomer was self-condensed via a 
      simple Friedel-Crafts alkylation reaction. The physical-chemical properties of 
      the HCP-BDM material were characterized by infrared spectroscopy, scanning 
      electron microscopy, thermogravimetric and analysis nitrogen 
      adsorption-desorption isotherms. The HCP-BDM coated fiber demonstrated excellent 
      adsorption performance for some organochlorine pesticides (OCPs). An effective 
      HCP-BDM fiber-based SPME method combined with gas chromatography-micro electron 
      capture detector was established for the analysis of the OCPs from various 
      vegetable samples. The linear ranges were observed from their corresponding 
      limits of quantification (LOQs) to 50 ng g(-1) for the OCPs, with correlation 
      coefficients varied from 0.9952 to 0.9992. Their limits of detection at S/N = 3 
      ranged from 0.058 to 0.14 ng g(-1). The single fiber repeatability and 
      fiber-to-fiber reproducibility, expressed as the relative standard deviations 
      (RSDs), were from 3.4% to 8.8% and from 6.7% to 9.6%, respectively. The 
      established method was finally applied to the analysis of the OCPs from cucumber, 
      Chinese cabbage and tomato samples with satisfactory recoveries and 
      repeatability.
CI  - Copyright (c) 2018 Elsevier B.V. All rights reserved.
FAU - Wang, Wenchang
AU  - Wang W
AD  - Department of Chemistry, College of Science, Hebei Agricultural University, 
      Baoding 071001, China.
FAU - Wang, Wenjin
AU  - Wang W
AD  - Department of Chemistry, College of Science, Hebei Agricultural University, 
      Baoding 071001, China.
FAU - Zhang, Shuaihua
AU  - Zhang S
AD  - Department of Chemistry, College of Science, Hebei Agricultural University, 
      Baoding 071001, China. Electronic address: zhangshuaihua@hebau.edu.cn.
FAU - Li, Zhi
AU  - Li Z
AD  - Department of Chemistry, College of Science, Hebei Agricultural University, 
      Baoding 071001, China.
FAU - Wang, Chun
AU  - Wang C
AD  - Department of Chemistry, College of Science, Hebei Agricultural University, 
      Baoding 071001, China.
FAU - Wang, Zhi
AU  - Wang Z
AD  - Department of Chemistry, College of Science, Hebei Agricultural University, 
      Baoding 071001, China. Electronic address: wangzhi@hebau.edu.cn.
LA  - eng
PT  - Journal Article
DEP - 20180502
PL  - Netherlands
TA  - J Chromatogr A
JT  - Journal of chromatography. A
JID - 9318488
RN  - 0 (Cross-Linking Reagents)
RN  - 0 (Hydrocarbons, Chlorinated)
RN  - 0 (Polymers)
RN  - 0 (Silicones)
RN  - 0 (Water Pollutants, Chemical)
RN  - N762921K75 (Nitrogen)
SB  - IM
MH  - Adsorption
MH  - Chromatography, Gas
MH  - Cross-Linking Reagents/*chemistry
MH  - Hydrocarbons, Chlorinated/*isolation & purification
MH  - Nanoparticles/*chemistry
MH  - Nitrogen/chemistry
MH  - Osmolar Concentration
MH  - Polymers/*chemistry
MH  - Reproducibility of Results
MH  - Silicones/chemistry
MH  - Solid Phase Microextraction/*methods
MH  - Spectroscopy, Fourier Transform Infrared
MH  - Temperature
MH  - Time Factors
MH  - Vegetables/chemistry
MH  - Water Pollutants, Chemical/isolation & purification
OTO - NOTNLM
OT  - Hyper-crosslinked polymer
OT  - Organochlorine pesticides
OT  - Solid-phase microextraction
OT  - Vegetable samples
EDAT- 2018/05/08 06:00
MHDA- 2018/06/19 06:00
CRDT- 2018/05/09 06:00
PHST- 2018/03/24 00:00 [received]
PHST- 2018/04/26 00:00 [revised]
PHST- 2018/05/01 00:00 [accepted]
PHST- 2018/05/08 06:00 [pubmed]
PHST- 2018/06/19 06:00 [medline]
PHST- 2018/05/09 06:00 [entrez]
AID - S0021-9673(18)30546-6 [pii]
AID - 10.1016/j.chroma.2018.05.001 [doi]
PST - ppublish
SO  - J Chromatogr A. 2018 Jun 29;1556:47-54. doi: 10.1016/j.chroma.2018.05.001. Epub 
      2018 May 2.