PMID- 29797369
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20180820
LR  - 20180820
IS  - 1521-3765 (Electronic)
IS  - 0947-6539 (Linking)
VI  - 24
IP  - 42
DP  - 2018 Jul 25
TI  - Instant Detection of Hydrogen Cyanide Gas and Cyanide Salts in Solid Matrices and 
      Water by using Cu(II) and Ni(II) Complexes of Intramolecularly Hydrogen Bonded 
      Zwitterions.
PG  - 10721-10731
LID - 10.1002/chem.201800894 [doi]
AB  - A series of intramolecularly hydrogen-bonded zwitterionic compartmental ligands 
      HL1-HL4, containing a pendent diamine arm that is monoprotonated and an aldehyde 
      functionality at two different ortho-positions of a 4-halophenoxide, is reported 
      herein. Single-crystal X-ray diffraction (SXRD) provides persuasive evidence for 
      the identification of this class of proton-transferred zwitterions at room 
      temperature. The solid-state photoluminescent nature of these zwitterions remains 
      intact in aqueous and organic solutions. Grinding of HL1 and HL2 with Cu(2+) 
      /Ni(2+) salts develop turn-on probes 1-4. Compounds 1 and 4 are dinuclear Cu(II) 
      and Ni(II) species, respectively. Compound 2 is a tetranuclear Cu(II) complex. 
      Interestingly, compound 3 is a mononuclear Ni(II) species in which both nitrogen 
      atoms in the pendant diamine arm are protonated and, therefore, not coordinated 
      to the Ni(II) center. All these probes (1-4) display an instant response to the 
      poison gas hydrogen cyanide (HCN) and cyanide salts present in both solid 
      matrices and aqueous (100 % water) solution. Selective and rapid sensing of HCN 
      gas and cyanide salts in solid/soil/water phases, without any interference, by 
      the mechanosynthesized complexes 1-4 can be perceived easily by the naked eye 
      under a hand-held UV lamp.
CI  - (c) 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
FAU - Nair, Ratish R
AU  - Nair RR
AD  - Analytical & Environmental Science Division, and Centralized Instrument Facility, 
      CSIR-CSMCRI, G. B. Marg, Bhavnagar, India), E-mails.
AD  - Academy of Scientific and Innovative Research (AcSIR), CSIR-CSMCRI, G. B. Marg, 
      Bhavnagar, India.
FAU - Raju, M
AU  - Raju M
AD  - Analytical & Environmental Science Division, and Centralized Instrument Facility, 
      CSIR-CSMCRI, G. B. Marg, Bhavnagar, India), E-mails.
AD  - Academy of Scientific and Innovative Research (AcSIR), CSIR-CSMCRI, G. B. Marg, 
      Bhavnagar, India.
FAU - Jana, Kalyanashis
AU  - Jana K
AD  - Analytical & Environmental Science Division, and Centralized Instrument Facility, 
      CSIR-CSMCRI, G. B. Marg, Bhavnagar, India), E-mails.
AD  - Academy of Scientific and Innovative Research (AcSIR), CSIR-CSMCRI, G. B. Marg, 
      Bhavnagar, India.
FAU - Mondal, Dhrubajyoti
AU  - Mondal D
AD  - Department of Inorganic Chemistry, Indian Association for the Cultivation of 
      Science, Kolkata, India.
FAU - Suresh, E
AU  - Suresh E
AD  - Analytical & Environmental Science Division, and Centralized Instrument Facility, 
      CSIR-CSMCRI, G. B. Marg, Bhavnagar, India), E-mails.
AD  - Academy of Scientific and Innovative Research (AcSIR), CSIR-CSMCRI, G. B. Marg, 
      Bhavnagar, India.
FAU - Ganguly, Bishwajit
AU  - Ganguly B
AD  - Analytical & Environmental Science Division, and Centralized Instrument Facility, 
      CSIR-CSMCRI, G. B. Marg, Bhavnagar, India), E-mails.
AD  - Academy of Scientific and Innovative Research (AcSIR), CSIR-CSMCRI, G. B. Marg, 
      Bhavnagar, India.
FAU - Chatterjee, Pabitra B
AU  - Chatterjee PB
AUID- ORCID: 0000-0003-2741-3684
AD  - Analytical & Environmental Science Division, and Centralized Instrument Facility, 
      CSIR-CSMCRI, G. B. Marg, Bhavnagar, India), E-mails.
AD  - Academy of Scientific and Innovative Research (AcSIR), CSIR-CSMCRI, G. B. Marg, 
      Bhavnagar, India.
LA  - eng
PT  - Journal Article
DEP - 20180627
PL  - Germany
TA  - Chemistry
JT  - Chemistry (Weinheim an der Bergstrasse, Germany)
JID - 9513783
OTO - NOTNLM
OT  - analytical methods
OT  - cyanides
OT  - dyes/pigments
OT  - sensors
OT  - solid-state reactions
EDAT- 2018/05/26 06:00
MHDA- 2018/05/26 06:01
CRDT- 2018/05/26 06:00
PHST- 2018/02/20 00:00 [received]
PHST- 2018/05/26 06:00 [pubmed]
PHST- 2018/05/26 06:01 [medline]
PHST- 2018/05/26 06:00 [entrez]
AID - 10.1002/chem.201800894 [doi]
PST - ppublish
SO  - Chemistry. 2018 Jul 25;24(42):10721-10731. doi: 10.1002/chem.201800894. Epub 2018 
      Jun 27.