PMID- 29893741 OWN - NLM STAT- MEDLINE DCOM- 20180822 LR - 20181202 IS - 0273-1223 (Print) IS - 0273-1223 (Linking) VI - 77 IP - 9-10 DP - 2018 Jun TI - A novel activated carbon prepared from grapefruit peel and its application in removal of phenolic compounds. PG - 2517-2527 LID - 10.2166/wst.2018.212 [doi] AB - The most ideal conditions for preparing activated carbon from grapefruit peel (GPAC) were studied using NH(4)H(2)PO(4) as a chemical activating agent and the obtained material was characterized by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR) and Brunauer-Emmett-Teller (BET) analysis. The adsorption capacity of the resulting material has been checked using three phenolic compounds (pyrocatechol (CA), 4-chlorophenol (4-CP) and 2,4-dichlorophenol (2,4-DCP)). The adsorption characteristics of phenolic compounds from aqueous solution by GPAC have been investigated as a function of contact time, pH, initial concentration and temperature. The equilibrium experimental data fitted well with Freundlich and Koble-Corrigan isotherms. The adsorption of the three phenolic compounds on GPAC fitted well with pseudo-second-order kinetic model. Different thermodynamic parameters were also evaluated and it was found that the adsorption was spontaneous, feasible and endothermic in nature. Adsorbents were regenerated by 0.1 mol/L NaOH and GPAC could be reused in phenolic compounds removal. FAU - Liu, Xiao AU - Liu X AD - School of Chemical Engineering and Energy, Zhengzhou University, 100# of Kexue Road, Zhengzhou 450001, China. FAU - Wan, Yibei AU - Wan Y AD - School of Chemical Engineering and Energy, Zhengzhou University, 100# of Kexue Road, Zhengzhou 450001, China. FAU - Liu, Penglei AU - Liu P AD - School of Chemical Engineering and Energy, Zhengzhou University, 100# of Kexue Road, Zhengzhou 450001, China. FAU - Fu, Yanzhen AU - Fu Y AD - School of Chemical Engineering and Energy, Zhengzhou University, 100# of Kexue Road, Zhengzhou 450001, China. FAU - Zou, Weihua AU - Zou W AD - School of Chemical Engineering and Energy, Zhengzhou University, 100# of Kexue Road, Zhengzhou 450001, China. LA - eng PT - Journal Article PL - England TA - Water Sci Technol JT - Water science and technology : a journal of the International Association on Water Pollution Research JID - 9879497 RN - 0 (Phenols) RN - 0 (Water Pollutants, Chemical) RN - 16291-96-6 (Charcoal) SB - IM MH - Adsorption MH - Charcoal/*chemistry MH - Citrus paradisi/*chemistry MH - Hydrogen-Ion Concentration MH - Kinetics MH - Phenols/*chemistry MH - Spectroscopy, Fourier Transform Infrared MH - Temperature MH - Thermodynamics MH - Waste Disposal, Fluid/methods MH - Water Pollutants, Chemical/*chemistry EDAT- 2018/06/13 06:00 MHDA- 2018/08/23 06:00 CRDT- 2018/06/13 06:00 PHST- 2018/06/13 06:00 [entrez] PHST- 2018/06/13 06:00 [pubmed] PHST- 2018/08/23 06:00 [medline] AID - 10.2166/wst.2018.212 [doi] PST - ppublish SO - Water Sci Technol. 2018 Jun;77(9-10):2517-2527. doi: 10.2166/wst.2018.212.