PMID- 30032372 OWN - NLM STAT- MEDLINE DCOM- 20190107 LR - 20190107 IS - 1614-7499 (Electronic) IS - 0944-1344 (Linking) VI - 25 IP - 27 DP - 2018 Sep TI - Photocatalytic degradation of imidacloprid by Ag-ZnO composite. PG - 27307-27320 LID - 10.1007/s11356-018-2693-8 [doi] AB - The present study focused on exploring the potential of Ag-ZnO composites for complete mineralization of imidacloprid with the aim to sustain the pollutant free safe water supply. The composites were prepared by hydrothermal method and characterized by Scanning electron microscope (SEM), Energy dispersive X-ray crystallography (EDX), X-ray diffraction (XRD) and band gap measurements. These composites were used to study the UV irradiated degradation of imidacloprid while optimizing the process parameters such as time of UV irradiation, pH of medium, pesticide concentration and composite loading. The results of the study revealed an increase in photodegradation of imidacloprid by Ag-ZnO composites than pure ZnO. Temperature and catalyst loading had a positive effect on degradation efficiency, while an inverse relation was observed between pesticide concentration and degradation. Moreover, no harmful degradation products of imidacloprid were observed in GC-MS analyses that confirmed its complete mineralization. FAU - Kanwal, Mahwish AU - Kanwal M AD - Department of Chemistry, Syed Babar Ali School of Sciences and Engineering (SBASSE), Lahore University of Management Sciences (LUMS), Sector U, DHA, Lahore Cantt, 54792, Pakistan. FAU - Tariq, Saadia Rashid AU - Tariq SR AD - Department of Chemistry, Lahore College for Women University, Lahore, 54000, Pakistan. saadiarashid74@gmail.com. FAU - Chotana, Ghayoor Abbas AU - Chotana GA AD - Department of Chemistry, Syed Babar Ali School of Sciences and Engineering (SBASSE), Lahore University of Management Sciences (LUMS), Sector U, DHA, Lahore Cantt, 54792, Pakistan. ghayoor.abbas@lums.edu.pk. LA - eng PT - Journal Article DEP - 20180721 PL - Germany TA - Environ Sci Pollut Res Int JT - Environmental science and pollution research international JID - 9441769 RN - 0 (Neonicotinoids) RN - 0 (Nitro Compounds) RN - 3BN7M937V8 (imidacloprid) RN - 3M4G523W1G (Silver) RN - SOI2LOH54Z (Zinc Oxide) SB - IM MH - Catalysis MH - Neonicotinoids/*chemistry MH - Nitro Compounds/*chemistry MH - Photolysis MH - Silver/*chemistry MH - Ultraviolet Rays MH - X-Ray Diffraction MH - Zinc Oxide/*chemistry OTO - NOTNLM OT - Ag-ZnO composite OT - imidacloprid OT - photodegradation EDAT- 2018/07/23 06:00 MHDA- 2019/01/08 06:00 CRDT- 2018/07/23 06:00 PHST- 2017/12/07 00:00 [received] PHST- 2018/07/03 00:00 [accepted] PHST- 2018/07/23 06:00 [pubmed] PHST- 2019/01/08 06:00 [medline] PHST- 2018/07/23 06:00 [entrez] AID - 10.1007/s11356-018-2693-8 [pii] AID - 10.1007/s11356-018-2693-8 [doi] PST - ppublish SO - Environ Sci Pollut Res Int. 2018 Sep;25(27):27307-27320. doi: 10.1007/s11356-018-2693-8. Epub 2018 Jul 21.