PMID- 30058954 OWN - NLM STAT- MEDLINE DCOM- 20190909 LR - 20190909 IS - 1096-3669 (Electronic) VI - 36 IP - 10 DP - 2018 Oct TI - Removal of bisphenol A and 2,4-Di-tert-butylphenol from landfill leachate using plant- based coagulant. PG - 975-984 LID - 10.1177/0734242X18790360 [doi] AB - Landfill leachate contain persistent organic pollutants (POPs), namely, bisphenol A (BPA) and 2,4-Di-tert-butylphenol, which exceed the permissible limits. Thus, such landfill leachate must be treated before it is released into natural water courses. This article reports on investigations about the removal efficiency of POPs such as BPA and 2,4-Di-tert-butylphenol from leachate using locust bean gum (LBG) in comparison with alum. The vital experimental variables (pH, coagulant dosage and stirring speed) were optimised by applying response surface methodology equipped with the Box-Behnken design to reduce the POPs from leachate. An empirical quadratic polynomial model could accurately model the surface response with R(2) values of 0.928 and 0.954 to reduce BPA and 2,4-Di-tert-butylphenol, respectively. Fourier transform infrared (FTIR) spectroscopy and scanning electron microscopy (SEM) were performed on treated flocs for further understanding. FTIR analysis revealed that the bridging of pollutant particles could be due to the explicit adsorption and bridging via hydrogen bonding of a coagulation mechanism. SEM micrographs indicated that the flocs produced by LBG have a rough cloudy surface and numerous micro-pores compared with alum, which enabled the capture and removal of POPs from leachate. Results showed that the reduction efficiencies for BPA and 2,4-Di-tert-butylphenol at pH 7.5 were 76% and 84% at LBG dosage of 500 mg.L(-1) and 400 mg.L(-1), respectively. Coagulant dosage and pH variation have a significant effect on POPs reduction in leachate. Coagulation/flocculation using LBG could be applied for POPs reduction in leachate as a pre-treatment prior to advanced treatments. FAU - Aziz, A AU - Aziz A AD - 1 Faculty of Marine Sciences, Lasbela University of Agriculture, Water and Marine Sciences, Uthal, Balochistan, Pakistan. AD - 2 Institute of Biological Sciences, Faculty of Science, University of Malaya, 50603 Kuala Lumpur, Malaysia. AD - 3 Center for Research in Waste Management, Faculty of Science, University of Malaya, 50603 Kuala Lumpur, Malaysia. FAU - Agamuthu, P AU - Agamuthu P AD - 2 Institute of Biological Sciences, Faculty of Science, University of Malaya, 50603 Kuala Lumpur, Malaysia. AD - 3 Center for Research in Waste Management, Faculty of Science, University of Malaya, 50603 Kuala Lumpur, Malaysia. FAU - Fauziah, S H AU - Fauziah SH AD - 2 Institute of Biological Sciences, Faculty of Science, University of Malaya, 50603 Kuala Lumpur, Malaysia. AD - 3 Center for Research in Waste Management, Faculty of Science, University of Malaya, 50603 Kuala Lumpur, Malaysia. LA - eng PT - Journal Article DEP - 20180730 PL - England TA - Waste Manag Res JT - Waste management & research : the journal of the International Solid Wastes and Public Cleansing Association, ISWA JID - 9881064 RN - 0 (Benzhydryl Compounds) RN - 0 (Phenols) RN - 0 (Water Pollutants, Chemical) RN - FOB94G6HZT (2,4-di-tert-butylphenol) RN - MLT3645I99 (bisphenol A) SB - IM MH - Benzhydryl Compounds MH - Flocculation MH - Phenols MH - *Water Pollutants, Chemical OTO - NOTNLM OT - 2,4-Di-tert-butylphenol OT - Bisphenol A OT - coagulation/flocculation OT - flocs OT - locust bean gum EDAT- 2018/07/31 06:00 MHDA- 2019/09/10 06:00 CRDT- 2018/07/31 06:00 PHST- 2018/07/31 06:00 [pubmed] PHST- 2019/09/10 06:00 [medline] PHST- 2018/07/31 06:00 [entrez] AID - 10.1177/0734242X18790360 [doi] PST - ppublish SO - Waste Manag Res. 2018 Oct;36(10):975-984. doi: 10.1177/0734242X18790360. Epub 2018 Jul 30.