PMID- 30075383
OWN - NLM
STAT- MEDLINE
DCOM- 20190207
LR  - 20190215
IS  - 1873-4235 (Electronic)
IS  - 0956-5663 (Linking)
VI  - 118
DP  - 2018 Oct 30
TI  - Metal-organic framework-based molecularly imprinted polymer as a high sensitive 
      and selective hybrid for the determination of dopamine in injections and human 
      serum samples.
PG  - 129-136
LID - S0956-5663(18)30549-9 [pii]
LID - 10.1016/j.bios.2018.07.047 [doi]
AB  - A highly sensitive and selective molecular imprinting polymer (MIP) sensor was 
      fabricated based on polypyrrole (PPy)/ZIF-67/Nafion hybrid modified glassy carbon 
      electrode (GCE) for the determination of dopamine (DA). The ZIF-67 material was 
      facilely prepared by using hydrothermal synthesis method; subsequently, the 
      PPy/ZIF-67/Nafion hybrid was obtained through a one-pot synthesis method. The 
      physical properties of the materials and the modified sensors were investigated 
      by using X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy 
      (FTIR), Nitrogen adsorption-desorption isothermal (BET), X-ray photoelectron 
      spectroscopy (XPS), Scanning electron microscope (SEM) and Atomic force 
      microspectroscopy (AFM) apparatus. Cyclic voltammetry (CV), differential pulse 
      voltammetry (DPV) and electrochemical impedance spectroscope (EIS) were used to 
      evaluate the electrochemical performance of the sensors. The influence factors 
      controlling the performance of the MIP sensor were studied and included scan 
      rate, pH value and scan cycles. Under optimal conditions, DPV peak was linearly 
      related to DA concentration over two concentration intervals (0.08-100 microM and 
      100-500 microM). The detection limit of PPy/ZIF-67-MIPs/Nafion/GCE sensor for DA was 
      0.0308 microM (S/N = 3) and sensitivity was equal to 1.656 microA microM cm(-2). Furthermore, 
      good reproducibility, long-term stability and favorable selectivity were obtained 
      in the experiment. Moreover, the fabricated MIP sensor was successfully applied 
      in the determination of DA concentrations in injection and human serum samples 
      with satisfactory recoveries.
CI  - Copyright (c) 2018 Elsevier B.V. All rights reserved.
FAU - Zhang, Wanqing
AU  - Zhang W
AD  - School of Chemistry and Chemical Engineering, Henan Institute of Science and 
      Technology, Xinxiang 453003, China. Electronic address: zhangwqzzu@163.com.
FAU - Duan, Dawei
AU  - Duan D
AD  - School of Chemistry and Chemical Engineering, Henan Institute of Science and 
      Technology, Xinxiang 453003, China.
FAU - Liu, Shanqin
AU  - Liu S
AD  - School of Chemistry and Chemical Engineering, Henan Institute of Science and 
      Technology, Xinxiang 453003, China.
FAU - Zhang, Yongsheng
AU  - Zhang Y
AD  - School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou 
      450001, China.
FAU - Leng, Leipeng
AU  - Leng L
AD  - School of Chemistry and Chemical Engineering, Henan Institute of Science and 
      Technology, Xinxiang 453003, China.
FAU - Li, Xinli
AU  - Li X
AD  - School of Chemistry and Chemical Engineering, Henan Institute of Science and 
      Technology, Xinxiang 453003, China.
FAU - Chen, Na
AU  - Chen N
AD  - School of Chemistry and Chemical Engineering, Henan Institute of Science and 
      Technology, Xinxiang 453003, China.
FAU - Zhang, Yuping
AU  - Zhang Y
AD  - School of Chemistry and Chemical Engineering, Henan Institute of Science and 
      Technology, Xinxiang 453003, China. Electronic address: beijing2008zyp@163.com.
LA  - eng
PT  - Journal Article
DEP - 20180725
PL  - England
TA  - Biosens Bioelectron
JT  - Biosensors & bioelectronics
JID - 9001289
RN  - 0 (Metal-Organic Frameworks)
RN  - 0 (Polymers)
RN  - VTD58H1Z2X (Dopamine)
SB  - IM
MH  - Biosensing Techniques/instrumentation/*methods
MH  - Dopamine/*analysis/*blood
MH  - Electrochemical Techniques
MH  - Electrodes
MH  - Humans
MH  - Limit of Detection
MH  - Metal-Organic Frameworks/*chemistry
MH  - Molecular Imprinting
MH  - Polymers/chemistry
MH  - Reproducibility of Results
OTO - NOTNLM
OT  - MIP sensor
OT  - PPy/ZIF-67-MIPs/Nafion hybrid
OT  - dopamine
OT  - electrochemical detection
EDAT- 2018/08/04 06:00
MHDA- 2019/02/08 06:00
CRDT- 2018/08/04 06:00
PHST- 2018/06/08 00:00 [received]
PHST- 2018/07/23 00:00 [revised]
PHST- 2018/07/24 00:00 [accepted]
PHST- 2018/08/04 06:00 [pubmed]
PHST- 2019/02/08 06:00 [medline]
PHST- 2018/08/04 06:00 [entrez]
AID - S0956-5663(18)30549-9 [pii]
AID - 10.1016/j.bios.2018.07.047 [doi]
PST - ppublish
SO  - Biosens Bioelectron. 2018 Oct 30;118:129-136. doi: 10.1016/j.bios.2018.07.047. 
      Epub 2018 Jul 25.