PMID- 30125845 OWN - NLM STAT- MEDLINE DCOM- 20181114 LR - 20181114 IS - 1873-6424 (Electronic) IS - 0269-7491 (Linking) VI - 242 IP - Pt B DP - 2018 Nov TI - Source identification and quantification of chlorinated and brominated polycyclic aromatic hydrocarbons from cement kilns co-processing solid wastes. PG - 1346-1352 LID - S0269-7491(18)32644-7 [pii] LID - 10.1016/j.envpol.2018.08.025 [doi] AB - Chlorinated and brominated polycyclic aromatic hydrocarbons (Cl/Br-PAHs) are widespread persistent organic pollutants (POPs) in environments. Identifying the new sources of Cl/Br-PAHs is important for implementing source control and reducing environmental risk. Although co-processing of solid wastes by cement kilns increased recently, the occurrences and characteristics of Cl/Br-PAHs as emerging POPs during cement kiln co-processing solid wastes have not been investigated. This study firstly investigated the occurrences, characteristics, and variations of Cl/Br-PAHs from four cement kilns co-processing different solid wastes. The concentration ranges of Cl-PAHs and Br-PAHs in stack gas samples from the investigated cement kilns were 15.6-94.1 ng m(-3) and 1.04-4.28 ng m(-3), respectively. Emission factors of Cl-PAHs and Br-PAHs through stack gases were 29.9-275 mug t(-1) and 3.0-8.3 mug t(-1), respectively. Variations of Cl/Br-PAHs in particle samples collected from different process stages within the cement kiln system indicated that the kiln end was the major formation zone for Cl/Br-PAHs. Congener profiles of Cl/Br-PAHs varied with the co-processed solid waste types, indicating the important influence of raw material compositions. Calculations of net emissions of Cl/Br-PAHs within the cement kiln systems suggested efficient destruction (87.6%-98.8%) of Cl/Br-PAHs by the cement kilns. CI - Copyright (c) 2018 Elsevier Ltd. All rights reserved. FAU - Jin, Rong AU - Jin R AD - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, P.O. Box 2871, Beijing, 100085, China; University of Chinese Academy of Sciences, Beijing, 100049, China. FAU - Yang, Lili AU - Yang L AD - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, P.O. Box 2871, Beijing, 100085, China; University of Chinese Academy of Sciences, Beijing, 100049, China. FAU - Zheng, Minghui AU - Zheng M AD - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, P.O. Box 2871, Beijing, 100085, China; University of Chinese Academy of Sciences, Beijing, 100049, China; Institute of Environment and Health, Jianghan University, Wuhan, 430056, PR China. FAU - Xu, Yang AU - Xu Y AD - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, P.O. Box 2871, Beijing, 100085, China; University of Chinese Academy of Sciences, Beijing, 100049, China. FAU - Li, Cui AU - Li C AD - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, P.O. Box 2871, Beijing, 100085, China; University of Chinese Academy of Sciences, Beijing, 100049, China. FAU - Liu, Guorui AU - Liu G AD - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, P.O. Box 2871, Beijing, 100085, China; University of Chinese Academy of Sciences, Beijing, 100049, China. Electronic address: grliu@rcees.ac.cn. LA - eng PT - Journal Article DEP - 20180811 PL - England TA - Environ Pollut JT - Environmental pollution (Barking, Essex : 1987) JID - 8804476 RN - 0 (Environmental Pollutants) RN - 0 (Hydrocarbons, Brominated) RN - 0 (Hydrocarbons, Chlorinated) RN - 0 (Polycyclic Aromatic Hydrocarbons) RN - 0 (Solid Waste) SB - IM MH - Environmental Monitoring MH - Environmental Pollutants/*analysis MH - Halogenation MH - Hydrocarbons, Brominated/*analysis MH - Hydrocarbons, Chlorinated/*analysis MH - Incineration MH - Polycyclic Aromatic Hydrocarbons/*analysis MH - Solid Waste OTO - NOTNLM OT - Brominated PAHs OT - Cement kiln OT - Chlorinated PAHs OT - Congener profile OT - Polycyclic aromatic hydrocarbons (PAHs) OT - Solid waste EDAT- 2018/08/21 06:00 MHDA- 2018/11/15 06:00 CRDT- 2018/08/21 06:00 PHST- 2018/06/11 00:00 [received] PHST- 2018/08/07 00:00 [revised] PHST- 2018/08/07 00:00 [accepted] PHST- 2018/08/21 06:00 [pubmed] PHST- 2018/11/15 06:00 [medline] PHST- 2018/08/21 06:00 [entrez] AID - S0269-7491(18)32644-7 [pii] AID - 10.1016/j.envpol.2018.08.025 [doi] PST - ppublish SO - Environ Pollut. 2018 Nov;242(Pt B):1346-1352. doi: 10.1016/j.envpol.2018.08.025. Epub 2018 Aug 11.