PMID- 30134583 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20200930 IS - 2079-4991 (Print) IS - 2079-4991 (Electronic) IS - 2079-4991 (Linking) VI - 8 IP - 9 DP - 2018 Aug 21 TI - Cement-Based Materials Containing Graphene Oxide and Polyvinyl Alcohol Fiber: Mechanical Properties, Durability, and Microstructure. LID - 10.3390/nano8090638 [doi] LID - 638 AB - The influence of graphene oxide (GO) and polyvinyl alcohol (PVA) fiber on the mechanical performance, durability, and microstructure of cement-based materials was investigated in this study. The results revealed that compared with a control sample, the mechanical strength and durability of cement-based materials were significantly improved by adding PVA fiber and GO. The compressive and flexural strength at 28 d were increased by 30.2% and 39.3%, respectively. The chloride migration coefficient at 28 d was reduced from 7.3 x 10(-12) m(2)/s to 4.3 x 10(-12) m(2)/s. Under a sulfate corrosion condition for 135 d, the compressive and flexural strength still showed a 13.9% and 12.3% gain, respectively. Furthermore, from the Mercury Intrusion Porosimetry (MIP) test, with the incorporation of GO, the cumulative porosity decreased from more than 0.13 cm(3)/g to about 0.03 cm(3)/g, and the proportion of large capillary pores reduced from around 80% to 30% and that of medium capillary pores increased from approximately 20% to 50%. Scanning electron microscope (SEM) images showed a significant amount of hydration products adhering to the surface of PVA fiber in the GO and PVA fiber modified sample. The addition of GO coupling with PVA fiber in cement-based materials could promote hydration of cement, refine the microstructure, and significantly improve mechanical strength and durability. FAU - Jiang, Wenguang AU - Jiang W AD - State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China. JWG930329@163.com. FAU - Li, Xiangguo AU - Li X AD - State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China. lixiangguo@whut.edu.cn. FAU - Lv, Yang AU - Lv Y AD - State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China. yang.lv@whut.edu.cn. FAU - Zhou, Mingkai AU - Zhou M AD - State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China. zhoumingkai@163.com. FAU - Liu, Zhuolin AU - Liu Z AD - State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China. lin7336@126.com. FAU - Ren, Zhaofeng AU - Ren Z AD - State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China. RZF15671660187@163.com. FAU - Yu, Zhuqing AU - Yu Z AD - College of Materials Science and Engineering, Nanjing Tech University, Nanjing 210000, China. zyu@njtech.edu.cn. LA - eng PT - Journal Article DEP - 20180821 PL - Switzerland TA - Nanomaterials (Basel) JT - Nanomaterials (Basel, Switzerland) JID - 101610216 PMC - PMC6163994 OTO - NOTNLM OT - PVA fiber OT - cement-based materials OT - durability OT - graphene oxide OT - mechanical strength OT - microstructure COIS- We declare that there is no conflict of interest in this work. EDAT- 2018/08/24 06:00 MHDA- 2018/08/24 06:01 PMCR- 2018/08/21 CRDT- 2018/08/24 06:00 PHST- 2018/07/18 00:00 [received] PHST- 2018/08/16 00:00 [revised] PHST- 2018/08/16 00:00 [accepted] PHST- 2018/08/24 06:00 [entrez] PHST- 2018/08/24 06:00 [pubmed] PHST- 2018/08/24 06:01 [medline] PHST- 2018/08/21 00:00 [pmc-release] AID - nano8090638 [pii] AID - nanomaterials-08-00638 [pii] AID - 10.3390/nano8090638 [doi] PST - epublish SO - Nanomaterials (Basel). 2018 Aug 21;8(9):638. doi: 10.3390/nano8090638.