PMID- 30148344
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20180919
LR  - 20180919
IS  - 1944-8252 (Electronic)
IS  - 1944-8244 (Linking)
VI  - 10
IP  - 37
DP  - 2018 Sep 19
TI  - Multiple Linkage Modification of Lithium-Rich Layered Oxide 
      Li(1.2)Mn(0.54)Ni(0.13)Co(0.13)O(2) for Lithium Ion Battery.
PG  - 31324-31329
LID - 10.1021/acsami.8b09256 [doi]
AB  - A multiple linkage modification (MLM) method was investigated to comprehensively 
      improve the properties of lithium-rich layered oxides. MLM 
      Li(1.2)Mn(0.54)Ni(0.13)Co(0.13)O(2) was successfully synthesized via continuous 
      and appropriate heat treatment. The synthesized 
      Li(1.2)Mn(0.54)Ni(0.13)Co(0.13)O(2) particles were coated with a Li(2)ZrO(3) 
      layer and doped with Zr(4+) by using a Zr compound as the MLM reagent. The 
      Li(2)ZrO(3) coating layer could protect materials from the corrosion of hydrogen 
      fluoride, and the structure of the base materials was stabilized due to Zr(4+) 
      doping. In addition, the formation of Li(2)ZrO(3) captured inactive residual 
      lithium on the surface and absorbed lithium of host materials, thereby leading to 
      the reduction in the Li/M ratio of materials and promoting the first-cycle 
      Coulombic efficiency. The MLM material delivered the highest initial cycle 
      Coulombic efficiency ( approximately 85%), the best cycle and rate performance among bare and 
      ZrO(2)-coated particles. These results indicate that MLM is an important 
      technique for improving the performance of electrode materials.
FAU - Zheng, Jun-Chao
AU  - Zheng JC
AUID- ORCID: 0000-0002-7530-8590
AD  - School of Metallurgy and Environment , Central South University , Changsha 410083 
      , P. R. China.
FAU - Yang, Zhuo
AU  - Yang Z
AD  - School of Metallurgy and Environment , Central South University , Changsha 410083 
      , P. R. China.
FAU - Wang, Peng-Bo
AU  - Wang PB
AD  - School of Metallurgy and Environment , Central South University , Changsha 410083 
      , P. R. China.
FAU - Tang, Lin-Bo
AU  - Tang LB
AD  - School of Metallurgy and Environment , Central South University , Changsha 410083 
      , P. R. China.
FAU - An, Chang-Sheng
AU  - An CS
AD  - School of Metallurgy and Environment , Central South University , Changsha 410083 
      , P. R. China.
FAU - He, Zhen-Jiang
AU  - He ZJ
AD  - School of Metallurgy and Environment , Central South University , Changsha 410083 
      , P. R. China.
AD  - School of Environmental Science and Engineering , Donghua University , Shanghai 
      201620 , P. R. China.
LA  - eng
PT  - Journal Article
DEP - 20180907
PL  - United States
TA  - ACS Appl Mater Interfaces
JT  - ACS applied materials & interfaces
JID - 101504991
OTO - NOTNLM
OT  - cathode material
OT  - electrochemical performance
OT  - lithium ion battery
OT  - lithium-rich layered oxide
OT  - multiple linkage modification
EDAT- 2018/08/28 06:00
MHDA- 2018/08/28 06:01
CRDT- 2018/08/28 06:00
PHST- 2018/08/28 06:00 [pubmed]
PHST- 2018/08/28 06:01 [medline]
PHST- 2018/08/28 06:00 [entrez]
AID - 10.1021/acsami.8b09256 [doi]
PST - ppublish
SO  - ACS Appl Mater Interfaces. 2018 Sep 19;10(37):31324-31329. doi: 
      10.1021/acsami.8b09256. Epub 2018 Sep 7.