PMID- 30235586 OWN - NLM STAT- MEDLINE DCOM- 20190403 LR - 20190403 IS - 1879-1026 (Electronic) IS - 0048-9697 (Linking) VI - 646 DP - 2019 Jan 1 TI - Occurrence, distribution and behavior of emerging persistent organic pollutants (POPs) in a Mediterranean wetland protected area. PG - 1009-1020 LID - S0048-9697(18)32802-X [pii] LID - 10.1016/j.scitotenv.2018.07.304 [doi] AB - The analysis of perfluoroalkyl substances (PFASs) and organophosphate flame retardants (PFRs) in the different environmental compartments of a characteristic coastal wetland, the Albufera Natural Park (Valencia, Spain), is required for understanding the transport, accumulation and fate of these pollutants in an area under high anthropogenic pressure. Samples included 13 wastewater treatment plant influents, 13 effluents, 12 surface water, 19 sediment samples and 10 fish individuals from the Albufera Natural Park and the surrounding area. Tris(2-chloroisopropyl) phosphate (TCIPP) and perfluorooctane sulfonate (PFOS) were at the highest concentrations in water, 330.2 ng L(-1) and 47.8 ng L(-1), respectively. In fish and sediment PFOS was also the most detected while perfluorooctanoic acid (PFOA) was in all types of water. Higher levels of target compounds (mainly PFASs) in wastewater effluents compared to influent suggested both, formation from precursors during treatment and poor removal efficiency. Mean levels of PFOS in water and fish were higher than the environmental quality standards (EQS) established by the European Union Directive 2013/39/EU. The influence of the metropolitan area of Valencia and its surrounding industrial belt could explain the significantly higher levels reported in the northern part (influenced by the Turia River). CI - Copyright (c) 2018 Elsevier B.V. All rights reserved. FAU - Lorenzo, Maria AU - Lorenzo M AD - Food and Environmental Safety Research Group (SAMA-UV), Desertification Research Centre - CIDE (CSIC-UV-GV) and Faculty of Pharmacy, University of Valencia, Av. Vicent Andres Estelles s/n, 46100 Burjassot, Valencia, Spain. Electronic address: maria.lorenzo@uv.es. FAU - Campo, Julian AU - Campo J AD - Environmental Forensic and Landscape Chemistry Research Group, Desertification Research Centre - CIDE (CSIC-UV-GV), Carretera Moncada - Naquera km 4.5 (Campus IVIA), 46113 Moncada, Valencia, Spain. FAU - Morales Suarez-Varela, Maria AU - Morales Suarez-Varela M AD - Unit of Public Health and Environmental Care, Department of Preventive Medicine, University of Valencia, Valencia, Spain; CIBER Epidemiologia y Salud Publica (CIBERESP), Institute of Health Carlos III, Madrid, Spain. FAU - Pico, Yolanda AU - Pico Y AD - Food and Environmental Safety Research Group (SAMA-UV), Desertification Research Centre - CIDE (CSIC-UV-GV) and Faculty of Pharmacy, University of Valencia, Av. Vicent Andres Estelles s/n, 46100 Burjassot, Valencia, Spain; CIBER Epidemiologia y Salud Publica (CIBERESP), Institute of Health Carlos III, Madrid, Spain. LA - eng PT - Journal Article DEP - 20180723 PL - Netherlands TA - Sci Total Environ JT - The Science of the total environment JID - 0330500 RN - 0 (Alkanesulfonic Acids) RN - 0 (Fluorocarbons) RN - 0 (Water Pollutants, Chemical) SB - IM MH - Alkanesulfonic Acids MH - Animals MH - *Environmental Monitoring MH - Fluorocarbons/analysis MH - Rivers MH - Spain MH - Water Pollutants, Chemical/*analysis MH - *Wetlands OTO - NOTNLM OT - Environmental samples OT - Fish OT - Organophosphorus flame retardants OT - Perfluoroalkyl substances OT - Sediment OT - Wetland EDAT- 2018/09/22 06:00 MHDA- 2019/04/04 06:00 CRDT- 2018/09/22 06:00 PHST- 2018/02/07 00:00 [received] PHST- 2018/07/21 00:00 [revised] PHST- 2018/07/21 00:00 [accepted] PHST- 2018/09/22 06:00 [entrez] PHST- 2018/09/22 06:00 [pubmed] PHST- 2019/04/04 06:00 [medline] AID - S0048-9697(18)32802-X [pii] AID - 10.1016/j.scitotenv.2018.07.304 [doi] PST - ppublish SO - Sci Total Environ. 2019 Jan 1;646:1009-1020. doi: 10.1016/j.scitotenv.2018.07.304. Epub 2018 Jul 23.