PMID- 30251496
OWN - NLM
STAT- MEDLINE
DCOM- 20181018
LR  - 20181018
IS  - 1872-2059 (Electronic)
IS  - 1000-8713 (Linking)
VI  - 36
IP  - 8
DP  - 2018 Aug 8
TI  - [Determination of migration of perfluorooctanoic acid and perfluorooctane 
      sulfonic acid from food contact materials by ionic liquid-based dispersive 
      liquid-liquid microextraction and ultra-performance liquid chromatography-tandem 
      mass spectrometry].
PG  - 738-744
LID - 10.3724/SP.J.1123.2018.03039 [doi]
AB  - A new method was developed to determine the migration of perfluorooctanoic acid 
      (PFOA) and perfluorooctane sulfonic acid (PFOS) from food contact materials 
      (FCMs) using ionic liquid-based dispersive liquid-liquid microextraction 
      (IL-DLLME) coupled with ultra-performance liquid chromatography-tandem mass 
      spectrometry (UPLC-MS/MS). FCM samples were soaked in three food simulants of 
      water, 10% (v/v) aqueous ethanol solution, and 4% (v/v) acetic acid solution for 
      the migration test, and then the migration liquid was extracted and enriched 
      using the IL-DLLME. The key parameters in terms of the type and volume of 
      extractant, vortex time, NaCl concentration, and the speed and time of 
      centrifugation were investigated. The analytes were separated on a Waters ACQUITY 
      UPLC BEH Shield RP18 column (50 mmx2.1 mm, 1.7 mum), eluted by gradient with 
      acetonitrile and water, and quantified by electrospray ionization mass 
      spectrometry in negative mode using multiple reaction monitoring (MRM). The 
      experimental results showed good linearities (r(2)>0.99) in their concentration 
      ranges. The limits of detection (LODs) were 0.5 and 1 mug/L, and the limits of 
      quantitation (LOQs) were 2 and 5 mug/L for PFOA and PFOS, respectively. The 
      recoveries of PFOA and PFOS ranged from 86.4% to 116.9% at three spiked levels 
      with the relative standard deviations (RSDs) between 4.3% and 14.4% (n=6). The 
      proposed method was demonstrated as accurate, efficient, eco-friendly, and 
      suitable for the determination of the migration of PFOA and PFOS from FCMs.
FAU - Yan, Mengmeng
AU  - Yan M
AD  - Chinese Academy of Inspection and Quarantine, Beijing 100176, China.
AD  - School of Chinese Materia Medica, Beijing University of Chinese Medicine, Beijing 
      100029, China.
FAU - Chen, Meng
AU  - Chen M
AD  - Chinese Academy of Inspection and Quarantine, Beijing 100176, China.
AD  - School of Chinese Materia Medica, Beijing University of Chinese Medicine, Beijing 
      100029, China.
FAU - Meng, Xianshuang
AU  - Meng X
AD  - Chinese Academy of Inspection and Quarantine, Beijing 100176, China.
FAU - Guo, Xiangyu
AU  - Guo X
AD  - Chinese Academy of Inspection and Quarantine, Beijing 100176, China.
FAU - Bai, Hua
AU  - Bai H
AD  - Chinese Academy of Inspection and Quarantine, Beijing 100176, China.
FAU - Ma, Qiang
AU  - Ma Q
AD  - Chinese Academy of Inspection and Quarantine, Beijing 100176, China.
FAU - Wang, Penglong
AU  - Wang P
AD  - School of Chinese Materia Medica, Beijing University of Chinese Medicine, Beijing 
      100029, China.
FAU - Lei, Haimin
AU  - Lei H
AD  - School of Chinese Materia Medica, Beijing University of Chinese Medicine, Beijing 
      100029, China.
LA  - chi
PT  - Journal Article
PL  - China
TA  - Se Pu
JT  - Se pu = Chinese journal of chromatography
JID - 9424804
RN  - 0 (Alkanesulfonic Acids)
RN  - 0 (Caprylates)
RN  - 0 (Fluorocarbons)
RN  - 0 (Ionic Liquids)
RN  - 0 (Ions)
RN  - 947VD76D3L (perfluorooctanoic acid)
RN  - 9H2MAI21CL (perfluorooctane sulfonic acid)
SB  - IM
MH  - Alkanesulfonic Acids/*analysis
MH  - Caprylates/*analysis
MH  - Chromatography, High Pressure Liquid
MH  - Fluorocarbons/*analysis
MH  - Food Contamination/*analysis
MH  - *Food Packaging
MH  - Ionic Liquids
MH  - Ions
MH  - Limit of Detection
MH  - Liquid Phase Microextraction
MH  - Spectrometry, Mass, Electrospray Ionization
MH  - Tandem Mass Spectrometry
OTO - NOTNLM
OT  - dispersive liquid-liquid microextraction (DLLME)
OT  - food contact materials (FCMs)
OT  - food simulants
OT  - ionic liquid (IL)
OT  - perfluorooctane sulfonic acid (PFOS)
OT  - perfluorooctanoic acid (PFOA)
OT  - ultra-performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS)
EDAT- 2018/09/27 06:00
MHDA- 2018/10/20 06:00
CRDT- 2018/09/26 06:00
PHST- 2018/09/26 06:00 [entrez]
PHST- 2018/09/27 06:00 [pubmed]
PHST- 2018/10/20 06:00 [medline]
AID - 10.3724/SP.J.1123.2018.03039 [doi]
PST - ppublish
SO  - Se Pu. 2018 Aug 8;36(8):738-744. doi: 10.3724/SP.J.1123.2018.03039.