PMID- 30267824 OWN - NLM STAT- MEDLINE DCOM- 20190109 LR - 20190109 IS - 1879-0003 (Electronic) IS - 0141-8130 (Linking) VI - 120 IP - Pt B DP - 2018 Dec TI - Chitosan polysaccharide as a renewable functional agent to develop antibacterial, antioxidant activity and colourful shades on wool dyed with tea extract polyphenols. PG - 1999-2006 LID - S0141-8130(18)33421-4 [pii] LID - 10.1016/j.ijbiomac.2018.09.167 [doi] AB - Chitosan is a potential renewable, versatile amino polysaccharide which has been approved by food and drug administration for use in food, cosmetics, pharmaceuticals and other industries. In order to determine if chitosan can be utilized in the development of colourful and multifunctional wool fabric without the need of toxic metal salt mordants, we have investigated the colouring, radical scavenging and antibacterial activity of wool dyed with tea extract polyphenols using chitosan as a green pre-treatment finishing agent. UV-vis analysis confirmed the optical properties of tea polyphenols, while Fourier-transform infrared spectroscopy (FT-IR), Scanning electron microscope (SEM) and Thermogravimetric analysis (TGA) spectroscopic characterizations demonstrated binding, surface morphology and thermal stability properties of chitosan coated wool. Colour spectrometry data obtained in terms of CIEL*a*b* values showed an outstanding effect of the chitosan pre-treatment. The Camellia sinensis (tea) extract dyed wool yielded interestingly elegant pale to golden yellowish colours with acceptable wash fastness properties. The chitosan gets its affinity for the wool via hydrogen bonding, electrostatic and van der Waals interactions. The results also showed that chitosan pre-treatment imparts excellent radical scavenging and antibacterial activity against E. coli and S. aureus, and thus offers new opportunities in the realm of natural dyeing. CI - Copyright (c) 2018 Elsevier B.V. All rights reserved. FAU - Shahid-Ul-Islam AU - Shahid-Ul-Islam AD - Department of Textile Technology, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110016, India. Electronic address: shads.jmi@gmail.com. FAU - Butola, B S AU - Butola BS AD - Department of Textile Technology, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110016, India. Electronic address: bsbutola@textile.iitd.ac.in. FAU - Roy, Anasuya AU - Roy A AD - Department of Textile Technology, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110016, India. LA - eng PT - Journal Article DEP - 20180926 PL - Netherlands TA - Int J Biol Macromol JT - International journal of biological macromolecules JID - 7909578 RN - 0 (Anti-Bacterial Agents) RN - 0 (Biphenyl Compounds) RN - 0 (Coloring Agents) RN - 0 (Free Radical Scavengers) RN - 0 (Picrates) RN - 0 (Polyphenols) RN - 0 (Tea) RN - 9012-76-4 (Chitosan) RN - DFD3H4VGDH (1,1-diphenyl-2-picrylhydrazyl) SB - IM MH - Animals MH - Anti-Bacterial Agents/chemistry/pharmacology MH - Biphenyl Compounds/chemistry MH - Chitosan/*chemistry/*pharmacology MH - Color MH - Coloring Agents/*chemistry MH - Escherichia coli/drug effects MH - Free Radical Scavengers/chemistry/pharmacology MH - Picrates/chemistry MH - Polyphenols/*chemistry MH - Staphylococcus aureus/drug effects MH - Tea/*chemistry MH - Wool/*chemistry OTO - NOTNLM OT - Antibacterial activity OT - Antioxidant activity OT - Chitosan polysaccharide OT - Tea polyphenols OT - Wool finishing EDAT- 2018/09/30 06:00 MHDA- 2019/01/10 06:00 CRDT- 2018/09/30 06:00 PHST- 2018/07/06 00:00 [received] PHST- 2018/09/11 00:00 [revised] PHST- 2018/09/25 00:00 [accepted] PHST- 2018/09/30 06:00 [pubmed] PHST- 2019/01/10 06:00 [medline] PHST- 2018/09/30 06:00 [entrez] AID - S0141-8130(18)33421-4 [pii] AID - 10.1016/j.ijbiomac.2018.09.167 [doi] PST - ppublish SO - Int J Biol Macromol. 2018 Dec;120(Pt B):1999-2006. doi: 10.1016/j.ijbiomac.2018.09.167. Epub 2018 Sep 26.