PMID- 30273724
OWN - NLM
STAT- MEDLINE
DCOM- 20190201
LR  - 20190201
IS  - 1095-7103 (Electronic)
IS  - 0021-9797 (Linking)
VI  - 535
DP  - 2019 Feb 1
TI  - Dual and multiple stimuli-responsive platonic micelles bearing disaccharides.
PG  - 8-15
LID - S0021-9797(18)31119-6 [pii]
LID - 10.1016/j.jcis.2018.09.044 [doi]
AB  - We recently identified completely monodisperse micelles whose aggregation number 
      (N(agg)) coincides with the vertex number of regular polyhedra, named Platonic 
      micelles. The combination of both the micellar properties and controlling their 
      structures by external stimuli could be promising for producing precisely 
      controlled self-assembled structures. From this perspective, we newly synthesized 
      a calix[4]arene-based amphiphile bearing disaccharides, cellobioses. The crowded 
      and bulky structure in the hydrophilic group could provide a novel 
      stimuli-responsiveness of disaccharides in amphiphiles. The aggregation behavior 
      such as the morphologies and the aggregation number of the calix[4]arene-based 
      micelle was characterized using small angle scattering techniques and analytical 
      ultracentrifugation measurements. Owing to hydrogen bonding among the 
      disaccharide, the head volume became smaller than expected, resulting in the 
      formation of cylindrical ones. However, cleaving the hydrogen bond by controlling 
      temperature or pH induced morphological transition of the micellar structure from 
      cylindrical to spherical. The dual-stimuli (temperature and pH) generated smaller 
      micelles with N(agg) of 12. Interestingly, when the amphiphile formed spherical 
      micelles at various conditions, the N(agg) matched the Platonic number, and the 
      change of N(agg) in response to the external stimuli was non-continuous, which is 
      consistent with the concept of Platonic micelles.
CI  - Copyright (c) 2018. Published by Elsevier Inc.
FAU - Miyake, Rika
AU  - Miyake R
AD  - Department of Chemistry and Biochemistry, University of Kitakyushu, 1-1 Hibikino, 
      Kitakyushu, Fukuoka 808-0135, Japan.
FAU - Fujii, Shota
AU  - Fujii S
AD  - Department of Chemistry and Biochemistry, University of Kitakyushu, 1-1 Hibikino, 
      Kitakyushu, Fukuoka 808-0135, Japan.
FAU - Lee, Ji Ha
AU  - Lee JH
AD  - Department of Chemistry and Biochemistry, University of Kitakyushu, 1-1 Hibikino, 
      Kitakyushu, Fukuoka 808-0135, Japan.
FAU - Takahashi, Rintaro
AU  - Takahashi R
AD  - Department of Chemistry and Biochemistry, University of Kitakyushu, 1-1 Hibikino, 
      Kitakyushu, Fukuoka 808-0135, Japan.
FAU - Sakurai, Kazuo
AU  - Sakurai K
AD  - Department of Chemistry and Biochemistry, University of Kitakyushu, 1-1 Hibikino, 
      Kitakyushu, Fukuoka 808-0135, Japan. Electronic address: sakurai@kitakyu-u.ac.jp.
LA  - eng
PT  - Journal Article
DEP - 20180921
PL  - United States
TA  - J Colloid Interface Sci
JT  - Journal of colloid and interface science
JID - 0043125
RN  - 0 (Micelles)
RN  - 0 (Phenols)
RN  - 0 (Surface-Active Agents)
RN  - 0 (calix(4)arene)
RN  - 130036-26-9 (Calixarenes)
RN  - 16462-44-5 (Cellobiose)
SB  - IM
MH  - Calixarenes/*chemistry
MH  - Cellobiose/chemical synthesis/*chemistry
MH  - Hydrogen-Ion Concentration
MH  - Hydrophobic and Hydrophilic Interactions
MH  - Micelles
MH  - Particle Size
MH  - Phenols/*chemistry
MH  - Surface Properties
MH  - Surface-Active Agents/chemical synthesis/*chemistry
MH  - Temperature
OTO - NOTNLM
OT  - Dual- and multi-stimulus responsiveness
OT  - Monodisperse micelles
OT  - Platonic micelles
EDAT- 2018/10/03 06:00
MHDA- 2019/02/02 06:00
CRDT- 2018/10/02 06:00
PHST- 2018/08/01 00:00 [received]
PHST- 2018/09/12 00:00 [revised]
PHST- 2018/09/12 00:00 [accepted]
PHST- 2018/10/03 06:00 [pubmed]
PHST- 2019/02/02 06:00 [medline]
PHST- 2018/10/02 06:00 [entrez]
AID - S0021-9797(18)31119-6 [pii]
AID - 10.1016/j.jcis.2018.09.044 [doi]
PST - ppublish
SO  - J Colloid Interface Sci. 2019 Feb 1;535:8-15. doi: 10.1016/j.jcis.2018.09.044. 
      Epub 2018 Sep 21.