PMID- 30314392
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20181015
LR  - 20231004
IS  - 1424-8220 (Electronic)
IS  - 1424-8220 (Linking)
VI  - 18
IP  - 10
DP  - 2018 Oct 11
TI  - Ultrafast and Energy-saving Synthesis of Nitrogen and Chlorine Co-doped Carbon 
      Nanodots via Neutralization Heat for Selective Detection of Cr(VI) in Aqueous 
      Phase.
LID - 10.3390/s18103416 [doi]
LID - 3416
AB  - In this work, it is presented for the first time that nitrogen and chlorine 
      co-doped carbon nanodots (N,Cl-CDs) were synthesized by simply mixing glucose, 
      concentrated hydrochloric acid (HCl), and 1,2-ethylenediamine (EDA). No external 
      heat was employed; the neutralization reaction served as the heat source. The 
      glucose served as the carbon source while EDA and HCl were the N and Cl dopants, 
      respectively. The fluorescence of N,Cl-CDs was adequately quenched by hexavalent 
      chromium Cr(VI) based on a combination of dynamic quenching and inner filter 
      effect (IFE). Accordingly, an efficient N,Cl-CDs-based fluorescence probe was 
      established for sensitive and selective detection of Cr(VI). The proposed 
      fluorescence sensor provides a linear recognition range for Cr(VI) determination 
      from 3 to 40 microM with a limit of detection (LOD) of 0.28 microM (14.6 microg/L). The 
      proposed fluorescence method was successfully utilized to detect Cr(VI) in 
      different water samples with satisfactory results. The spike recoveries vary from 
      97.01% to 103.89% with relative standard deviations (RSDs) of less than 0.82%. 
      This work highlights the development of a simple, ultrafast, and energy-saving 
      one-step synthetic route to fabricate N,Cl-CDs for highly selective and sensitive 
      detection of Cr(VI) in real water samples. It is anticipated that the proposed 
      fluorescence method could be further explored and widely used for Cr(VI) 
      detection in the environmental industry.
FAU - Hu, Qin
AU  - Hu Q
AUID- ORCID: 0000-0002-9989-3413
AD  - College of Food Science and Engineering, Yangzhou University, Jiangsu 225001, 
      China. qinhu1998@outlook.com.
AD  - Jiangsu Key Laboratory of Dairy Biotechnology and Safety Control, Yangzhou 
      University, Jiangsu 225001, China. qinhu1998@outlook.com.
FAU - Li, Tao
AU  - Li T
AD  - Department of Agronomy, Yangzhou University, Jiangsu 225001, China. 
      gaolu@yzu.edu.cn.
FAU - Gao, Lu
AU  - Gao L
AD  - College of Food Science and Engineering, Yangzhou University, Jiangsu 225001, 
      China. sqrao@yzu.edu.cn.
AD  - Jiangsu Key Laboratory of Dairy Biotechnology and Safety Control, Yangzhou 
      University, Jiangsu 225001, China. sqrao@yzu.edu.cn.
FAU - Gong, Xiaojuan
AU  - Gong X
AD  - Institute of Environmental Science, and School of Chemistry and Chemical 
      Engineering, Shanxi University, Taiyuan 030006, China. wmfang@yzu.edu.cn.
FAU - Rao, Shengqi
AU  - Rao S
AD  - College of Food Science and Engineering, Yangzhou University, Jiangsu 225001, 
      China. rxgu@yzu.edu.cn.
AD  - Jiangsu Key Laboratory of Dairy Biotechnology and Safety Control, Yangzhou 
      University, Jiangsu 225001, China. rxgu@yzu.edu.cn.
FAU - Fang, Weiming
AU  - Fang W
AD  - College of Food Science and Engineering, Yangzhou University, Jiangsu 225001, 
      China. taoli@yzu.edu.cn.
AD  - Jiangsu Key Laboratory of Dairy Biotechnology and Safety Control, Yangzhou 
      University, Jiangsu 225001, China. taoli@yzu.edu.cn.
FAU - Gu, Ruixia
AU  - Gu R
AD  - College of Food Science and Engineering, Yangzhou University, Jiangsu 225001, 
      China. gxj1124@sxu.edu.cn.
AD  - Jiangsu Key Laboratory of Dairy Biotechnology and Safety Control, Yangzhou 
      University, Jiangsu 225001, China. gxj1124@sxu.edu.cn.
FAU - Yang, Zhenquan
AU  - Yang Z
AD  - College of Food Science and Engineering, Yangzhou University, Jiangsu 225001, 
      China. yangzq@yzu.edu.cn.
AD  - Jiangsu Key Laboratory of Dairy Biotechnology and Safety Control, Yangzhou 
      University, Jiangsu 225001, China. yangzq@yzu.edu.cn.
LA  - eng
GR  - 31371806 and 21705101/National Natural Science Foundation of China/
GR  - CX(15)1012/China Jiangsu Innovation Fund of Agricultural Science and Technology/
GR  - 2016/Yangzhou University Science and Technology Innovation Team (2016)/
PT  - Journal Article
DEP - 20181011
PL  - Switzerland
TA  - Sensors (Basel)
JT  - Sensors (Basel, Switzerland)
JID - 101204366
PMC - PMC6210692
OTO - NOTNLM
OT  - Cr(VI) detection
OT  - carbon nanodots
OT  - fluorescent nanosensor
OT  - water samples
COIS- The authors declare no conflict of interest.
EDAT- 2018/10/14 06:00
MHDA- 2018/10/14 06:01
PMCR- 2018/10/01
CRDT- 2018/10/14 06:00
PHST- 2018/09/09 00:00 [received]
PHST- 2018/10/09 00:00 [revised]
PHST- 2018/10/09 00:00 [accepted]
PHST- 2018/10/14 06:00 [entrez]
PHST- 2018/10/14 06:00 [pubmed]
PHST- 2018/10/14 06:01 [medline]
PHST- 2018/10/01 00:00 [pmc-release]
AID - s18103416 [pii]
AID - sensors-18-03416 [pii]
AID - 10.3390/s18103416 [doi]
PST - epublish
SO  - Sensors (Basel). 2018 Oct 11;18(10):3416. doi: 10.3390/s18103416.